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Full-Text Articles in Chemistry
Kinetic-Energy- And Angular-Resolved Fragmentation Of Co In Vibrational-Resolved C 1s Excitation, N. Saito, Franz Heiser, Oliver Hemmers, K. Wieliczek, J. Viefhaus, U. Becker
Kinetic-Energy- And Angular-Resolved Fragmentation Of Co In Vibrational-Resolved C 1s Excitation, N. Saito, Franz Heiser, Oliver Hemmers, K. Wieliczek, J. Viefhaus, U. Becker
Environmental Studies Faculty Publications
Angular distributions of C++O+ from CO were measured, following vibrationally resolved C 1s excitations into the 2pπ, 3sσ, and 3pπ orbitals as well as into higher unresolved orbitals. A time-of-flight mass spectrometer, with a multihit-type position-sensitive anode, was used for the measurements. The anisotropy parameters (β) of C++O+ approach their theoretically expected values as the released kinetic energy in the fragmentation increases. The value of the β parameters remains constant for all vibrational states within each orbital.
First Results From The High-Brightness X-Ray Spectroscopy Beamline 9.3.1 At Als, W. Ng, G. Jones, Rupert C. Perera, D. Hansen, J. Daniels, Oliver Hemmers, P. Glans, S. B. Whitfield, H. Wang, Dennis W. Lindle
First Results From The High-Brightness X-Ray Spectroscopy Beamline 9.3.1 At Als, W. Ng, G. Jones, Rupert C. Perera, D. Hansen, J. Daniels, Oliver Hemmers, P. Glans, S. B. Whitfield, H. Wang, Dennis W. Lindle
Environmental Studies Faculty Publications
Beamline 9.3.1 at the Advanced Light Source (ALS) is a windowless beamline, covering the 1–6 keV photon energy range. This beamline is designed to achieve the goal of high brightness at the sample for use in the x‐ray atomic and molecular spectroscopy (XAMS) science, surface and interface science, biology and x‐ray optical development programs at ALS. X‐ray absorption and time‐of‐flight photoemission measurements in 2–5 keV photon energy range along with the flux, resolution, spot size and stability of the beamline will be discussed. Prospects for future XAMS measurements will also be presented.
Cross Sections For The Production Of He+ (Np) 2p0 States By 50 To 150 Kev Proton Impact On Helium, Wayne C. Stolte, R. Bruch
Cross Sections For The Production Of He+ (Np) 2p0 States By 50 To 150 Kev Proton Impact On Helium, Wayne C. Stolte, R. Bruch
Chemistry and Biochemistry Faculty Research
Cross sections have been measured for the production of He+ (np) 2Po states, n=2,3,4, by proton impact on helium over a projectile velocity range of 1.42–2.45 a.u. (50 ≤E≤150 keV). Cross sections were determined by measuring the extreme ultraviolet photons emitted from excited He1 ions. The data indicate a lower energy than expected for the maximum cross section. A comparison of the present results in terms of projectile energy dependance with the cross sections for excitation to He (1snp) 1Po, ionization, and total electron capture suggests the primary mechanism …
Neutron Diffraction Structural Study Of Ce₂Fe₁₇₋ₓgaₓ, H. Luo, Z. Hu, William B. Yelon, Sanjay R. Mishra, Gary J. Long, Oran Allan Pringle, D. P. Middleton, K. H. J. Buschow
Neutron Diffraction Structural Study Of Ce₂Fe₁₇₋ₓgaₓ, H. Luo, Z. Hu, William B. Yelon, Sanjay R. Mishra, Gary J. Long, Oran Allan Pringle, D. P. Middleton, K. H. J. Buschow
Physics Faculty Research & Creative Works
Six samples of Ce2Fe17-xGax with nominal Ga content x equal to 0, 0.3, 0.5, 0.7, 1.0, 2.0 have been studied by powder neutron diffraction at room temperature. Both crystalline and magnetic refinements have been carried out. All six samples adopt the Th2Zn17-type rhombohedral structure. The only additional phase found is α-iron. Gallium atoms are found to have high affinity for the iron 18h site, and are absent from the 9d and 18f sites. The Ga substitution for Fe leads to an expansion of both the a and c axes. The Curie …
Structure, Dynamics, And Phase Transitions In The Fullerene Derivatives C_{60}O And C_{61}H_{2}, C. Meingast, G. Roth, L. Pintschovius, R. H. Michel, C. Stoermer, M. M. Kappes, Paul A. Heiney, Laurent Brard, Robert M. Strongin, Amos B. Smith Iii
Structure, Dynamics, And Phase Transitions In The Fullerene Derivatives C_{60}O And C_{61}H_{2}, C. Meingast, G. Roth, L. Pintschovius, R. H. Michel, C. Stoermer, M. M. Kappes, Paul A. Heiney, Laurent Brard, Robert M. Strongin, Amos B. Smith Iii
Chemistry Faculty Publications and Presentations
The effect of perturbing the icosohedral symmetry of C60 by the addition of the side groups -O and -CH2 upon orientational order-disorder and glass transitions in solid C60 has been studied by a combination of high-resolution capacitance dilatometry and single-crystal x-ray and powder inelastic neutron scattering. Both fullerene derivatives C60O (epoxide) and C61H2 (6,5-annulene) are shown to undergo a sequence of transitions similar to that found in pure C60, i.e., a first-order orientational ordering transition just below room temperature followed by an orientational glass transition at lower temperatures. Although the …
Reconnecting The Sciences, John Eggebrecht, Raymond Dagenais, Don Dosch, Norman J. Merczak, Margaret N. Park, Susan C. Styer, David Workman
Reconnecting The Sciences, John Eggebrecht, Raymond Dagenais, Don Dosch, Norman J. Merczak, Margaret N. Park, Susan C. Styer, David Workman
Faculty Publications & Research
During the last three years at the Illinois Mathematics and Science Academy, we have been working on a partial reconstruction of Whitehead's "one subject matter," a course reconnecting biology, chemistry, earth and space sciences, and physics into an Integrated Science program.
Neutron Diffraction And Magnetic Studies Of Rfe₁₂₋ₓtₓcY (R=Y,Er; T=V,Ti,Mo) Alloys, Z. Hu, William B. Yelon, X. D. Zhang, William Joseph James
Neutron Diffraction And Magnetic Studies Of Rfe₁₂₋ₓtₓcY (R=Y,Er; T=V,Ti,Mo) Alloys, Z. Hu, William B. Yelon, X. D. Zhang, William Joseph James
Physics Faculty Research & Creative Works
RFe12-xTxCy, (R=Y,Er; T=V,Ti,Mo) alloys were prepared by rf induction melting and analyzed using neutron powder diffraction and superconducting quantum interference device (SQUID) measurements. Rietveld analysis of the neutron diffraction data indicates that V, Ti, and Mo atoms all prefer the 8i sites. The refined amount of carbon atoms found in the interstitial sites from neutron diffraction data is significantly less than the nominal carbon content. All samples have the easy direction along the c axis. The Er sublattice couples to the Fe sublattice antiferromagnetically. The average Fe site moments range from 1.3 to 2.8 …
Neutron Diffraction Studies Of Ndₙfeₘ₋ₓ₋YVₓalY [(N,M)=(1,12), (2,17), (3,29)], Z. Hu, William B. Yelon, William Joseph James
Neutron Diffraction Studies Of Ndₙfeₘ₋ₓ₋YVₓalY [(N,M)=(1,12), (2,17), (3,29)], Z. Hu, William B. Yelon, William Joseph James
Physics Faculty Research & Creative Works
Several NdnFem-x-yVxAly [(n,m)=(1,12), (2,17), (3,29)] samples were prepared and analyzed using neutron powder diffraction. Rietveld analysis of the neutron diffraction data indicates that the V and Al substituents take those sites with similar environments in all three phases, as observed in our previous study of Ti-substituted compounds. It was confirmed that the diffraction data of the 3:29 compound can be better refined using the A2/m space group than using the P21/c space group. The SQUID measurements show that all samples have Curie temperatures well above room temperature. The neutron diffraction results …
Site Affinity Of Substituents In Nd₂Fe₁₇₋ₓtₓ (T=Cu,Zr,Nb,Ti,V) Alloys, William B. Yelon, Z. Hu, William Joseph James, G. K. Marasinghe
Site Affinity Of Substituents In Nd₂Fe₁₇₋ₓtₓ (T=Cu,Zr,Nb,Ti,V) Alloys, William B. Yelon, Z. Hu, William Joseph James, G. K. Marasinghe
Physics Faculty Research & Creative Works
In order to understand the magnetic properties of the substituted rare-earth-iron alloys, it is especially important to know the location of the substitutional atoms within the iron lattice. The site distributions of some nontransition-metal substituents in the substituted Nd2Fe17-xTx alloys have previously been reported. Here we report the site distributions of some transition-metal substituents (Cu,Zr,Nb,Ti,V) in the Nd2Fe17-xTx alloys and compare them with those of the nontransition-metal substituted compounds. Rietveld analysis of neutron powder diffraction data indicates that the nontransition-metal substituents show very similar site affinity at low substituent content. …
Auger Resonant Raman Spectroscopy Used To Study The Angular Distributions Of The Xe 4d5/2 → 6p Decay Spectrum, B. Langer, N. Berrah, A. Farhat, Oliver Hemmers, J. Bozek
Auger Resonant Raman Spectroscopy Used To Study The Angular Distributions Of The Xe 4d5/2 → 6p Decay Spectrum, B. Langer, N. Berrah, A. Farhat, Oliver Hemmers, J. Bozek
Environmental Studies Faculty Publications
The Auger resonant Raman effect can be used as a method to eliminate natural lifetime broadening in resonant Auger spectra. We have coupled this method with high-resolution photons from the Advanced Light Source to study angular distributions and decay rates of the Xe4d5/2→6p resonant Auger lines. The angular distribution parameters β of almost all possible final ionic 5p4(3P, 1D, 1S)6p states have been determined. Our data, which remove the discrepancy between previous lower-resolution experimental results, are compared to different theoretical results.
Neutron Diffraction And Mössbauer Spectral Study Of The Nd₂Fe₁₆Ticₓ Solid Solutions, Gaya Kanishka Marasinghe, Peter C. Ezekwenna, William Joseph James, Gary J. Long, Oran Allan Pringle, Zhongbo Hu, William B. Yelon, Fernande Grandjean
Neutron Diffraction And Mössbauer Spectral Study Of The Nd₂Fe₁₆Ticₓ Solid Solutions, Gaya Kanishka Marasinghe, Peter C. Ezekwenna, William Joseph James, Gary J. Long, Oran Allan Pringle, Zhongbo Hu, William B. Yelon, Fernande Grandjean
Chemistry Faculty Research & Creative Works
Three samples of , with x equal to 0.0, 0.3, and 2.8, with the Th2Zn17-type rhombohedral structure, have been studied by powder x-ray and neutron diffraction, magnetic measurements, and Mössbauer spectroscopy. Nd2Fe16Ti and Nd2Fe16TiC0.3 were synthesized by induction melting stoichiometric amounts of the constituent elements, whereas Nd2Fe16TiC2.8 was synthesized by methane-derived gas phase insertion of carbon into finely ground Nd2Fe16Ti at 600 K. The neutron diffraction determined titanium site occupancies are similar in both Nd2Fe16 …
A Magnetic Neutron Diffraction, And Mössbauer Spectral Study Of The Ce₂Fe₁₇₋ₓalₓ Solid Solutions, Sanjay R. Mishra, Gary J. Long, Oran Allan Pringle, D. P. Middleton, Zhongbo Hu, William B. Yelon, Fernande Grandjean, K. H. J. Buschow
A Magnetic Neutron Diffraction, And Mössbauer Spectral Study Of The Ce₂Fe₁₇₋ₓalₓ Solid Solutions, Sanjay R. Mishra, Gary J. Long, Oran Allan Pringle, D. P. Middleton, Zhongbo Hu, William B. Yelon, Fernande Grandjean, K. H. J. Buschow
Chemistry Faculty Research & Creative Works
The magnetic properties of a series of Ce2Fe17-xAlx solid solutions with x equal to 0.00, 0.88, 2.06, 2.81, 3.98, 5.15, 6.08, 7.21, 8.20, 9.08, 9.84, and 10.62 have been studied by magnetic measurements, neutron diffraction, and Mössbauer spectroscopy. The compounds crystallize in the rhombohedral Th2Zn17-type structure. Magnetization studies indicate that the Curie temperature increases uniformly from 238 K for Ce2Fe17 to 384 K for Ce2Fe14Al3 and then decreases at higher aluminum content. Powder neutron diffraction results, obtained at 295 K, indicate that aluminum …