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Missouri University of Science and Technology

Magnetization

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Full-Text Articles in Chemistry

Structural, Magnetic, And Transport Properties Of Zr-Substituted La₀.₇ Sr₀.₃ Mn O₃, Minseob Kim, Jinbo Yang, Qingsheng Cai, William Joseph James, William B. Yelon, Paul Ernest Parris, Satish K. Malik May 2007

Structural, Magnetic, And Transport Properties Of Zr-Substituted La₀.₇ Sr₀.₃ Mn O₃, Minseob Kim, Jinbo Yang, Qingsheng Cai, William Joseph James, William B. Yelon, Paul Ernest Parris, Satish K. Malik

Chemistry Faculty Research & Creative Works

Zr-substituted perovskites La0.7Sr0.3 Mn1-x Zrx O3 with 0 ≤ x ≤ 0.20 were investigated by neutron diffraction (ND), magnetization, electric resistivity, and magnetoresistance measurements. ND refinements reveal that substituted Zr4+ goes only to the Mn site. Because of its large size, this leads to a Zr-solubility limit at x ≤ 0.10. The x ≤ 0.10 samples exhibit a rhombohedral structure (R3c) from 10 K to room temperature. For the x ≤ 0.10 samples, the cell parameters a and c, and volume increase continuously with increasing Zr content. In addition, the structural distortion of …


Study Of Structural And Magnetic Properties Of Iron-Rich Mixed Rare-Earth Nddyfe (17-Y-X)Coxsiy Compounds, Kishore Kamaraju, Jinbo Yang, William B. Yelon, Oran Allan Pringle, M. S. Kim, Qingsheng Cai, William Joseph James Jan 2004

Study Of Structural And Magnetic Properties Of Iron-Rich Mixed Rare-Earth Nddyfe (17-Y-X)Coxsiy Compounds, Kishore Kamaraju, Jinbo Yang, William B. Yelon, Oran Allan Pringle, M. S. Kim, Qingsheng Cai, William Joseph James

Physics Faculty Research & Creative Works

A series of NdDyFe(17-y-x)CoxSiy solid solutions with = 2 and 3 and = 0.5 1.0 and 1.5 were prepared by induction melting stoichiometric amounts of high-purity elements. The postannealed samples consist of two phases belonging to the space groups R3 m and P63 mmc . The lattice parameters and the unit cell volumes were calculated from the refinements of the magnetic and structural unit cells using the FULLPROF version of the Rietveld program. For a fixed content of Co, the maximum Curie temperatures (305 C to 405 C) were observed in samples with = 1 and having two phases, a …