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Physics

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Missouri University of Science and Technology

Chlorine

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Full-Text Articles in Chemistry

Observation Of Stratospheric Ozone Depletion Associated With Delta Ii Rocket Emissions, Martin N. Ross, Darin W. Toohey, W. T. Rawlins, E. C. Richard, K. K. Kelly, A. F. Tuck, M. H. Proffitt, Donald E. Hagen, Alfred R. Hopkins, Philip D. Whitefield, J. R. Benbrook, W. R. Sheldon Aug 2000

Observation Of Stratospheric Ozone Depletion Associated With Delta Ii Rocket Emissions, Martin N. Ross, Darin W. Toohey, W. T. Rawlins, E. C. Richard, K. K. Kelly, A. F. Tuck, M. H. Proffitt, Donald E. Hagen, Alfred R. Hopkins, Philip D. Whitefield, J. R. Benbrook, W. R. Sheldon

Physics Faculty Research & Creative Works

Ozone, chlorine monoxide, methane, and submicron particulate concentrations were measured in the stratospheric plume wake of a Delta II rocket powered by a combination of solid (NH4ClO4/Al) and liquid (LOX/kerosene) propulsion systems. We apply a simple kinetics model describing the main features of gas-phase chlorine reactions in solid propellant exhaust plumes to derive the abundance of total reactive chlorine in the plume and estimate the associated cumulative ozone loss. Measured ozone loss during two plume encounters (12 and 39 minutes after launch) exceeded the estimate by about a factor of about two. Insofar as only the …


In Situ Measurement Of The Aerosol Size Distribution In Stratospheric Solid Rocket Motor Exhaust Plumes, Martin N. Ross, Philip D. Whitefield, Donald E. Hagen, Alfred R. Hopkins Apr 1999

In Situ Measurement Of The Aerosol Size Distribution In Stratospheric Solid Rocket Motor Exhaust Plumes, Martin N. Ross, Philip D. Whitefield, Donald E. Hagen, Alfred R. Hopkins

Chemistry Faculty Research & Creative Works

The concentration and size distribution of aerosol in the stratospheric exhaust plumes of two Space Shuttle rockets and one Titan IV rocket were measured using a two component aerosol sampling system carried aboard a WB‐57F aircraft. Aerosol size distribution in the 0.01 µm to 4 µm diameter size range was measured using a two component sampling system. The measured distributions display a trimodal form with modes near 0.005 µm, 0.09 µm, and 2.03 µm and are used to infer the relative mass fractionation among the three modes. While the smallest mode has been estimated to contain as much as 10% …