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An Effective Method For The Preparation Of High Temperature Stable Anatase Tio2 Photocatalysts, Rachel Fagan, Declan Mccormack, Suresh Pillai, Damian Synnott
An Effective Method For The Preparation Of High Temperature Stable Anatase Tio2 Photocatalysts, Rachel Fagan, Declan Mccormack, Suresh Pillai, Damian Synnott
Articles
An efficient, rapid and straightforward method for the preparation of nitrogen and fluorine (N, F) codoped high temperature stable anatase using a microwave pre-treatment is reported. Using a single source, ammonium fluoride (NH4F) for both nitrogen and fluorine, effective doping of the precursor titanium isopropoxide (TTIP) was possible. These samples were characterised for their structural and optical properties using X-ray diffraction (XRD), Fourier transform IR (FTIR), Raman spectroscopy and UV-vis spectroscopy. In terms of the anatase to rutile transition enhancement using a novel microwave assisted technique, the sample prepared in a composition of 1:8 TiO2: NH …
Improved High Temperature Stability Of Anatase Tio2 Photocatalysts By N, F, P Co-Doping, Rachel Fagan, Declan Mccormack, Steven Hinder, Suresh Pillai
Improved High Temperature Stability Of Anatase Tio2 Photocatalysts By N, F, P Co-Doping, Rachel Fagan, Declan Mccormack, Steven Hinder, Suresh Pillai
Articles
Among the three commonly occurring phases (anatase, rutile, and brookite) of TiO2, the anatase form is reported to be the best photocatalyst due to the improved charge-carrier mobility and the greater number of surface hydroxyl groups. The anatase to rutile transition in titania photocatalysts usually occurs at a temperature between 500 °C to 700 °C. Development of a high temperature stable (above 1000 °C) anatase phase is important for various environmental applications (e.g. self-cleaning ceramic tiles, anti-microbial sanitary wares, etc.). In this study, the use of ammonium hexafluorophosphate as a single source dopant (method A) and urea, trifluoroacetic acid and …