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Physical Chemistry

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2007

Condenser

Articles 1 - 2 of 2

Full-Text Articles in Chemistry

Study On The Corrosion Of Chlorine Condenser By Electrochemical Method, Bin Xiang, Wen Chen, Wen-Zhang Huang, Shao-Hua Xing, Sheng-Tao Zhang Nov 2007

Study On The Corrosion Of Chlorine Condenser By Electrochemical Method, Bin Xiang, Wen Chen, Wen-Zhang Huang, Shao-Hua Xing, Sheng-Tao Zhang

Journal of Electrochemistry

Corrosion of condenser is very seriously in chlorine-alkali industry,which could lead to fatal disaster.The most commonly used material in low pressure condenser includes steel of 16MnR,10#,and welding rod of J507.Electrochemical analysis of the three materials in 29.9%(by mass) calcium chloride(CaCl2) solution was carried out.The corrosion current density icorr and impedance parameters of the three materials in 29.9% CaCl2 solution were estimated separately.The result showed that in the tripartite phase regions where the 10# seamless tube and 16MnR armor plate were jointed by welding,the weld was firstly eroded and suggested that the chlorine condenser should be examined and repaired every year.


Construction Of Three-Dimensional Finite Element Model For Complicated Cathodic Protection System, Ai-Ping Wang, Min Du, Qing-Zhang Wang, Sheng-Shan Cao, Ji-Xing Sun Nov 2007

Construction Of Three-Dimensional Finite Element Model For Complicated Cathodic Protection System, Ai-Ping Wang, Min Du, Qing-Zhang Wang, Sheng-Shan Cao, Ji-Xing Sun

Journal of Electrochemistry

When condensers with carbon steel waterbox and titanium tube structure were protected by SACP in an ocean beach power plant,while seawater were used to be cooling water,carbon steel was under-protected and Titanium was over-protected,because their protective potential are less than-0.85V(vs.SCE) and more than-0.75V(vs.SCE) separately.In order to optimize the SACP design,potential distribution of two materials must be obtained during the SACP process.In the lab,carbon steel waterbox and Titanium tube model(Q235-Ti model) were set up.A series of electrochemical techniques(steady polarization,galvanostatic charge technique)were used to obtain reasonable boundary condition and surface form of two materials during the SACP process.The experiments were carried out …