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Physical Chemistry

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2001

Hydrogen diffusion coefficient

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Full-Text Articles in Chemistry

Study Of Hydrogen Diffusion Behavior In Hydrogen Storage Alloy Mlni_(3.75)Co_(0.65) Mn_(0.4) Al_(0.2) With Potential Step Method, Xian Xia Yuan, Nai Xin Xu Nov 2001

Study Of Hydrogen Diffusion Behavior In Hydrogen Storage Alloy Mlni_(3.75)Co_(0.65) Mn_(0.4) Al_(0.2) With Potential Step Method, Xian Xia Yuan, Nai Xin Xu

Journal of Electrochemistry

Potential step method was employed to study the hydrogen diffusion behavior in hydrogen storage alloy MlNi 3.75 Co 0.65 Mn 0.4 Al 0.2 with various depth of discharge(DOD) at ambient temperature and with 50%DOD at various temperatures. It was found that hydrogen diffusion cofficient in the hydrogen storage alloy increaes with the increase in DOD at ambient temperature. and for the alloy with 50%DOD,the hydrogen diffusion coefficient increases with the increase in temperature and the activation energy for hydrogen diffusion in the alloy is 19.87 kJ/mol.


Determination Of Hydrogen Diffusion Coefficient In Metal Hydride Electrode With Electrochemical Impedance Spectroscopy, Xian Xia Yuan, Nai Xin Xu Aug 2001

Determination Of Hydrogen Diffusion Coefficient In Metal Hydride Electrode With Electrochemical Impedance Spectroscopy, Xian Xia Yuan, Nai Xin Xu

Journal of Electrochemistry

Electrochemical impedance spectroscopy was employed to determine the hydrogen diffusion coefficient in MlNi 3.75 Co 0.65 Mn 0.4 Al 0.2 metal hydride electrode with various states of charge(SOC) at room temperature and with 50% SOC at various temperatures. It was found that hydrogen diffusion coefficient in this electrode decreases with the increase in SOC at ambient temperature, and for the electrode with 50%SOC, hydrogen diffusion coefficient increases with the increase of temperature and the activation energy for hydrogen diffusion in it is 35 kJ/mol.