Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 17 of 17
Full-Text Articles in Chemistry
Effect Of Chloride Ion On Electrochemical Behavior Of Silver Electrodeposition In Chcl-Urea Low Eutectic Solvent, Chong-Bo Zhan, Run-Jia Zhang, Xu Fu, Hai-Jing Sun, Xin Zhou, Bao-Jie Wang, Jie Sun
Effect Of Chloride Ion On Electrochemical Behavior Of Silver Electrodeposition In Chcl-Urea Low Eutectic Solvent, Chong-Bo Zhan, Run-Jia Zhang, Xu Fu, Hai-Jing Sun, Xin Zhou, Bao-Jie Wang, Jie Sun
Journal of Electrochemistry
Metallic silver coating has been widely used in the fields of microelectronics industry, catalyst, sensor and preparation of magnetoresistive materials because of its excellent corrosion resistance, good lubricity, high conductivity, excellent decoration and high catalysis. Compared with the traditional aqueous solution system, the research on metal electrodeposition in ionic liquid system is developing rapidly. In addition, additives are the key factors in the silver plating process. Adding a small amount of organic or inorganic additives to the plating solution will significantly change the coating properties, such as improving brightness, hardness and ductility. In this paper, using choline chloride urea (ChCl-Urea) …
Biofouling Behaviors Of Pure Titanium Surface Polarized At Different Potentials, Zhao-Xia Dai, Da-Jiang Zheng, Guang-Ling Song, Dan-Qing Feng, Pei Su
Biofouling Behaviors Of Pure Titanium Surface Polarized At Different Potentials, Zhao-Xia Dai, Da-Jiang Zheng, Guang-Ling Song, Dan-Qing Feng, Pei Su
Journal of Electrochemistry
Titanium (Ti) and its alloys are commonly used as engineering materials. Although they have been widely used in marine environments, they are also facing serious threats of biofouling. Therefore, it is necessary to investigate the relationship between electrochemical behavior and bioaffinity of titanium oxide film in seawater to explore effective surface treatment technology to reduce biofouling. In this work, the cathodic potential of -0.8 VSCE and the passivation potential of 0.5 VSCE were directly applied to the TA2 Ti in artificial seawater for potentionstatic polarization treatment to prepare two kinds of surface films with different states and then …
Electrochemical Voltammetric Behavior Of Sulfur Mustard On The Bare Pt Electrode, Yu-Lin Yang, Jie Sun, Tian Zhou, Ji-Gang Li, Shou-Ping Wei
Electrochemical Voltammetric Behavior Of Sulfur Mustard On The Bare Pt Electrode, Yu-Lin Yang, Jie Sun, Tian Zhou, Ji-Gang Li, Shou-Ping Wei
Journal of Electrochemistry
The sulfur mustard (bis(2-chloroethyl) sulphide, HD), one of highly toxic chemical weapon agents, can damage the alive tissue cells (such as skin, lung, respiratory mucosa and so on), and cause carcinogenic and mutagenic effects for a long time exposure, which imposes a great threat not only to the human health, but also to the sustainable development of the society. With its convenience, high sensitivity and rapid response, electrochemical technology exhibits considerable potential in the field-deployed detection toward HD, but the related reports are rare. Herein, the electrochemical behavior of HD on the bare Pt electrode was investigated by electrochemical measurements, …
An Electrochemical Investigation Of P-Sulfophenylazo Calix[4]Arene In A Buffer Solution, Yang Xing, Chen Ping
An Electrochemical Investigation Of P-Sulfophenylazo Calix[4]Arene In A Buffer Solution, Yang Xing, Chen Ping
Journal of Electrochemistry
The p-sulfophenylazo calix[4]arene was synthesized through the diazotization-coupling reaction between calix[4]arene and p-aminobenzene sulfonic acid. The UV-Vis spectroscopy, Infrared spectroscopy, and nuclear magnetic resonance (NMR) were used to characterize the as-prepared p-sulfophenylazo calix[4]arene. The electrochemical behaviors of p-sulfophenylazo calix[4]arene were investigated by cyclic voltammetry and chronoamperometry using CH3COOH-CH3COONa as a buffer solution. The result shows that the p-sulfophenylazo calix[4]arene exhibited a pair of redox peaks in a scan potential region of -0.5 ~ 1 V. The oxidation and reduction peak potentials were 0.302 V and -0.003 V, respectively, and changed with …
Electrochemical Behavior And Content Determination Of Paeonol At Poly Sudan Ⅲ Modified Electrode, Yan-Jie Zheng, Ai-Lin Liu, Yun Lei, Xin-Hua Lin
Electrochemical Behavior And Content Determination Of Paeonol At Poly Sudan Ⅲ Modified Electrode, Yan-Jie Zheng, Ai-Lin Liu, Yun Lei, Xin-Hua Lin
Journal of Electrochemistry
The poly SudanⅢ modified electrode was characterized by electrochemical impedance spectroscopy（EIS）and cyclic voltammetry (CV), while the electrochemical behavior of paeonol was studied by cyclic voltammetry (CV). The result shows that the poly Sudan Ⅲ modified electrode exhibits excellent electrocatalytic effect on the oxidation of paeonol. The peak currents of differential pulse voltammetry are linear to the paeonol concentrations over the range of 3.0*10-7 ~ 2.2*10-5 mol·L-1. The detection limit has been estimated to be 5.0*10-8 mol·L-1. This method can be used for determination of paeonol content in real sample with satisfactory results.
Electrochemical Behaviors Of Hydroquinone On Polypyrrole/Stab-Nammt/Gc Electrode, Rong Li, Jian Xiong, Wei-Qiong Zhu, Yuan-Yuan Han, Jin Xu, Xiao-Ying He
Electrochemical Behaviors Of Hydroquinone On Polypyrrole/Stab-Nammt/Gc Electrode, Rong Li, Jian Xiong, Wei-Qiong Zhu, Yuan-Yuan Han, Jin Xu, Xiao-Ying He
Journal of Electrochemistry
The PPy/STAB-MMT/GC electrode was made using montmorillonite modified by STAB and polypyrrole (PPy). The electrochemical behaviors of hydroquinone on the PPy/STAB-MMT/GC electrode were researched by cyclic voltammetry and square wave stripping voltammetry (SWSV). The results showed that the electrode reaction occurred on the hydroquinone electrode was controlled by diffusion in PBS (pH=6.0). The number of electron transfer was equal to the number of protons (n=m=1) with the effective area of PPy/STAB-MMT/GC electrode Aeff=0.031 cm2. Under the optimized conditions, the linear response of peak current in SWSV with the concentration of hydroquinone in a range of 8.0×10-6~8.0×10-4 mol/L was observed, and …
Effects Of Additives On The Electrochemical Behaviors Of Zn Electrode In Alkaline Solutions, Shu-Na Hong, Hai-Bin Lin, Zuo-Jian Su, He-Bing Zhou, Man Liang, Wei-Shan Li
Effects Of Additives On The Electrochemical Behaviors Of Zn Electrode In Alkaline Solutions, Shu-Na Hong, Hai-Bin Lin, Zuo-Jian Su, He-Bing Zhou, Man Liang, Wei-Shan Li
Journal of Electrochemistry
Electrochemical behaviors of Zn in 3mol•L-1 KOH solution containing the single additive( Pb(NO3)2 , SDBS )the mixed additives( Pb(NO3)2+SDBS ) were investigated. The results showed that all the additives can supress the corrosion of zinc in 3mol•L-1 KOH solution. And the inhibition effeciency of the mixed additives is higher than that of any single additive.
Electrochemical Behaviors Of Organic Coating/Matal Substrate Under Simulated Deep Sea Environment Partⅰ.Effects Of Seawater Pressure On Transportation Behavior Of Water Through Coating And Coating′S Protective Performance, Bin Liu, Zhi-Gang Fang, Tao Wang, Hong-Bin Wang
Electrochemical Behaviors Of Organic Coating/Matal Substrate Under Simulated Deep Sea Environment Partⅰ.Effects Of Seawater Pressure On Transportation Behavior Of Water Through Coating And Coating′S Protective Performance, Bin Liu, Zhi-Gang Fang, Tao Wang, Hong-Bin Wang
Journal of Electrochemistry
By means of electrochemical impedance spectroscopy(EIS),the electrochemical behaviors of organic coating/metal substrate were studied under simulated deep sea environment in the laboratory.Effects of seawater pressure on the transportation behavior of water through coating and the protective performance of coating were analyzed.The experimental results showed that,compared to normal pressured seawater,there were different impedance characteristics of coating in 3.5 MPa pressured seawater.The main observations were that high seawater pressure accelerated the process of water uptake and invalidation of coating,increased water absorption,and lowered the anti-corrosion property of coating.
Electrochemical Behavior Of Co-Ru Composite In Alkaline Solution, Su-Mei Yao, Guo-Chun Li, Xue-Ping Gao
Electrochemical Behavior Of Co-Ru Composite In Alkaline Solution, Su-Mei Yao, Guo-Chun Li, Xue-Ping Gao
Journal of Electrochemistry
The electrochemical properties of Ru doped cobalt hydroxides synthesized via homogeneous chemical co-precipitation were investigated in 6 mol·L-1 KOH solution by galvanostatic charge-discharge process and cyclic voltammetry(CV).It is demonstrated that Ru doped cobalt hydroxides exhibited good capacitive characteristic and high specific capacitance.The sample with a Co/Ru molar ratio of 8 /1 shows the optimized electrochemical performance,including capacitive property and discharge capacity.The microstructure and morphology of the obtained Ru doped hydroxides were characterized by X-ray diffraction(XRD) and scanning electron microscope(SEM).The amorphous structure of ruthenium dioxide nanoparticles and single-crystal structure of Co(OH)2 platelets were confirmed.Based on a structure analysis and electrochemical measurement,the …
The Electrochemical Behavior Of Daunorubicin Hydrochloride On Galactic Disk Electrode And Its Reaction With Bsa, Hong-Fen Cheng, Yong Zhang, Jie Liu, Yan-Mei Liu
The Electrochemical Behavior Of Daunorubicin Hydrochloride On Galactic Disk Electrode And Its Reaction With Bsa, Hong-Fen Cheng, Yong Zhang, Jie Liu, Yan-Mei Liu
Journal of Electrochemistry
This article used the linear sweep voltammetry and the circulation voltammetry to study the electrochemical behavior of daunorubicin hydrochloride on galactic disk electrode and its electrode reaction with BSA.Also it studied the interaction of daunorubicin hydrochloride with BSA.The results showed that daunorubicin hydrochloride has a sensitive reduction peak at -0.64 V(vs. SCE) in pH 6.50 Britton-Robinson buffer.The valus of reductions peak current reduced by the addition of BSA to the above mentioned solution.A new electrochemical determination method of bovine serum albumin was developed based on the interaction of daunorubicin hydrochloride with BSA.Furthermore,under the optimized condition,the decrease of the reduction peak …
The Electrochemical Behavior And Determination Of Carbendazim On Iron Montmorillonite Modified Electrode, Xiao-Li Jiang, Rong Li, Xiao-Ying He, Jiang Li, Ying Li
The Electrochemical Behavior And Determination Of Carbendazim On Iron Montmorillonite Modified Electrode, Xiao-Li Jiang, Rong Li, Xiao-Ying He, Jiang Li, Ying Li
Journal of Electrochemistry
The FeCl3 modified clay electrode was made.The electrochemical behavior of carbendazim(BCM) on the modified electrode was studied by cyclic voltammetry.The impacts of pH,scan rate and dosages of modifier were discussed and the important kinetic parameters of the electrochemical process were determined.The results indicated that the process was controlled by diffusion.The effective area of FeMM-CMC/GCE(A)=0.027 cm2,the transfer electron numbers(n)=2 and the diffusion coefficient(D)=5.115×10-6cm2/s.Under the optimized conditions,a good linearity was found between the first order derivative of peak current and concentration of BCM in the range of 2.00×10-5～8.00×10-4mol/L,with i′p=-8.045×10-7-0.0237c,correlation coefficient R=-0.9965,and the detect limitation of 2.41×10-6 mol/L.The recovery of BCM was detected …
Electrochemical Behavior Of 6-Substituted Purines And Its Interaction With Dna, Bao-Yi Lu, You-Zhi Zheng, Hong Li
Electrochemical Behavior Of 6-Substituted Purines And Its Interaction With Dna, Bao-Yi Lu, You-Zhi Zheng, Hong Li
Journal of Electrochemistry
The electrochemical behavior of 6-furfurylaminopurine(6-KT) and 6-mercaptopurine(6-MP) on a mercury electrode has been investigated using cyclic voltammetry and differential pulse voltammetry.It is found that there are two pairs of redox waves for 6-KT and 6-MP on the mercury electrode controlled by diffusion and adsorption,respectively.The anodic peak currents of the diffusion-controlled wave increase with the adding concentration of 6-substituted purines.A good linear relationship for 6-KT and 6-MP is revealed in the concentration range from 0.1 to 50.0 μmol·L-1.Based on the effects of accumulating time and pH values on the cathodic peak potentials and currents of adsorption-controlled waves,their adsorption mechanism is discussed.The …
Electrochemical Behavior Of Aluminized Steel In Seawater Environment, Cheng-Hao Liang
Electrochemical Behavior Of Aluminized Steel In Seawater Environment, Cheng-Hao Liang
Journal of Electrochemistry
The electrochemical behavior of aluminized steel in seawater has been studied by immersion test and electrochemical technology. The results indicate that compared with 20# steel, the aluminized steel has lower corrosion potential and stronger anodic activity in seawater. Its anodic solution will occur at low potential. The immersion test shows that the corrosion rates of aluminized steel and 20# steel are 5.80 mg/dm~2 dand 3.36 mg/dm~2 d, respectively. Through the X-ray diffraction patternanalysis, it was found that chloride ions exit in the corrosion products of aluminized steel. It proves the participation of chloride ions in the process of corrosion, which …
Anodic Dissolution Of Aluminum In Koh-Ethanol Solutions, Hai-Bo Shao, Jian-Ming Wang, Xiao-Yan Wang, Yi Zheng, Jian-Qing Zhang
Anodic Dissolution Of Aluminum In Koh-Ethanol Solutions, Hai-Bo Shao, Jian-Ming Wang, Xiao-Yan Wang, Yi Zheng, Jian-Qing Zhang
Journal of Electrochemistry
The feasibility of employing aluminum in KOH ethanol solution as a battery anode system was discussed. Weight loss measurement showed that the corrosion rate of Al is low enough to be used in sealed batteries. Through the measurements done by anodic polarization, EIS and galvanostatic discharge, it was found that A1 is electrochemical active in a wide potential range in this system, and its discharge mechanism is similar to that of A1 in aqueous solution. The discharge potential increased rapidly after a period of time, which might be caused by the discharge products depositing on the electrode surface.
The Effect Of Calcium On The Properties Of Molybdenum Nitride Electrode, Yun-Gui Zhu, Xue-Liang Li, Dao-Rong Lu, Jian-Bo He, Ji-Huai Xia
The Effect Of Calcium On The Properties Of Molybdenum Nitride Electrode, Yun-Gui Zhu, Xue-Liang Li, Dao-Rong Lu, Jian-Bo He, Ji-Huai Xia
Journal of Electrochemistry
The effect of calcium on the properties of molybdenum nitride film electrode was studied by using XRD, SEM and cyclic voltammetry. The results show that the specific electric capacity and the voltage operating range of electrode vary with the concentration of additive in the dipping solution. At the optimum concentration of additive in the dipping solution, the specific electric capacity of the electrode is 2.1 times as large as that of the electrode prepared in the dipping solution without additive, and the voltage operating range of electrode is increased by 0.11 V. The active mechanism of calcium on the properties …
Study On The Electrochemical Behavior Of Glycyrrhizic Acid, Chunming Wang, Yanrong Zhang, Hulin Li
Study On The Electrochemical Behavior Of Glycyrrhizic Acid, Chunming Wang, Yanrong Zhang, Hulin Li
Journal of Electrochemistry
The electrochemical response characteristics of glycyrrhizic acid (GA) on the mercury electrode are described. In Britton Robinson buffer, the cyclic voltammograms exhibit two reduction peaks at a potential range of -0.80～-1.60 V.The peak potentials and currents change significantly when solution pH changes. By means of ultraviolet abosrption method, it is proved that the reduction position of GA molecular is ketenes radical. The peak potentials move positively with increasing pH demonstrate that the primary electrode reaction is accompanied by a coupled chemical reaction.The electrode reaction process is a typical example of ECE mechanism. Some effects of various parameters on adsorptive stripping …
Electrochemical Behaviors Of The Loaded Stainless Steel In Dilute Thiosulphate Solution, Changjian Lin, Zude Feng, Fuling Lin, Fayang Wang, Jianguang Tang, Yuanhui Wang
Electrochemical Behaviors Of The Loaded Stainless Steel In Dilute Thiosulphate Solution, Changjian Lin, Zude Feng, Fuling Lin, Fayang Wang, Jianguang Tang, Yuanhui Wang
Journal of Electrochemistry
The electrochemical behavior of l8/8 stainless steel in dilute thiosulphate solutionduring strained loading was studied by various electrochemical techniques and scanning electronmicroscope.It is evidenced that the corrosion activity of stainless steel increased with strained loading.The dynamic process of repassivation ,which may datermine the initiation ,the cease and developmentof the stress corrosion cracking for stainless steel ,was strongly influenced by both electrochemical andloading conditions. Pitting corrosion may locate preferentially on the sites which was suffered mostloading.The propagation of pitting corrosion of stainless steel may induce stress corrosion crakingunder certain conditions.