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The Phase Diagram Of A Non-Ideal Mixture’S P − V − X 2-Component Gas=Liquid Representation, Including Azeotropes, Carl W. David Mar 2022

The Phase Diagram Of A Non-Ideal Mixture’S P − V − X 2-Component Gas=Liquid Representation, Including Azeotropes, Carl W. David

Chemistry Education Materials

The liquid=vapor two phase p−v−x diagram is constructed for non-ideal solutions including azeotropes.


The Van Der Waals Fluid’S Liquid Vapor Coexistence Locus, Using Maxima/Gnuplot, Carl W. David Jan 2019

The Van Der Waals Fluid’S Liquid Vapor Coexistence Locus, Using Maxima/Gnuplot, Carl W. David

Chemistry Education Materials

The Maxima/Gnuplot code for plotting the van der Waals locus of liquid and vapor molar volumes as a function of pressure and temperature (all reduced) is presented.


Is The Maxwell Construction Correct In Predicting The Van Der Waals Fluid's Vapor Pressure?, Carl W. David Apr 2016

Is The Maxwell Construction Correct In Predicting The Van Der Waals Fluid's Vapor Pressure?, Carl W. David

Chemistry Education Materials

The Maxwell construction yields a pressure value which traditionally been associated with the vapor pressure. Here, the question is answered whether or not the two phases represented by the construct are indeed in equilibrium.