Chemistry Commons^™

Dual Crosslinked Poly(Acrylamide-Co-N-Vinylpyrrolidone) Microspheres With Re-Crosslinking Ability For Fossil Energy Recovery, Jingyang Pu, Baojun Bai, Jiaming Geng, Na Zhang, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Microspheres have been proposed to be applied in controlling wastewater production for mature oilfields and migrating leakage for gas and nuclear waste storage. However, it remains challenging for stacked microspheres to maintain strong blocking ability in micron-sized small pores or fractures. In this study, a novel microsphere was developed with comprehensive properties including high deformability and long re-crosslinking time upon tunable swelling ratio for the applications. A dual covalent and physical crosslinking strategy was used to develop novel microspheres reinforced by a hydrogen bond (H-bond, between pyrrole ring and amide group) and coordination bond (between chromium acetate (CrAc) and carboxyl …

Coreflooding Evaluation Of Fiber-Assisted Recrosslinkable Preformed Particle Gel Using An Open Fracture Model, Shuda Zhao, Ali Al Brahim, Junchen Liu, Baojun Bai, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Recrosslinkable Preformed Particle Gels (RPPGs) Have Been Used to Treat the Problem of Void Space Conduits (VSC) and repair the "Short-Circuited" Waterflood in Alaska's West Sak Field. Field Results Showed a 23% Increase in Success Rates over Typical Preformed Particle Gel (PPG) Treatments. in This Paper, We Evaluated Whether Adding Fiber into RPPGs Can Increase the RPPG Plugging Efficiency and Thus Further Improve the Success Rate. We Designed Open Fracture Models to Represent vs.C and Investigated the Effect of Swelling Ratio (SR), Fracture Size, and Fiber Concentration on Gel Injection Pressure, Water Breakthrough Pressure, and Permeability Reduction. Results Show that …

Lysine Crosslinked Polyacrylamide─A Novel Green Polymer Gel For Preferential Flow Control, Tao Song, Baojun Bai, Yugandhara Eriyagama, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Acrylamide-based polymer gels have been applied to control the preferential flow in the subsurface for decades. However, some commonly used crosslinkers, such as Cr (III) and phenol-formaldehyde, are highly toxic and are being phased out because of stringent environmental regulations. This work uses l-lysine as the green crosslinker to produce acrylamide-based polymer gels. This article systematically studied the effect of lysine and polymer concentration, salinity, pH, and temperature on gelation behavior and thermal stability. Besides, the gelation mechanism and crosslinking density were elucidated in this work. A high-permeability sandstone core was used to test the plugging efficiency of this novel …

Transport And Plugging Performance Evaluation Of A Novel Re-Crosslinkable Microgel Used For Conformance Control In Mature Oilfields With Super-Permeable Channels, Adel Alotibi, T. Song, Baojun Bai, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Preformed particle gels (PPG) have been widely applied in oilfields to control excessive water production. However, PPG has limited success in treating opening features because the particles can be flushed readily during post-water flooding. We have developed a novel micro-sized Re-crosslinkable PPG (micro-RPPG) to solve the problem. The microgel can re-crosslink to form a bulk gel, avoiding being washed out easily. This paper evaluates the novel microgels' transport and plugging performance through super-permeable channels. Micro-RPPG was synthesized and evaluated for this study. Its storage moduli after fully swelling are approximately 82 Pa. The microgel characterization, self-healing process, transportation behavior, and …

Comprehensive Evaluation Of A Novel Re-Crosslinkable Preformed Particle Gel For The Water Management Of Reservoir With Concentrated Divalent Ions, Tao Song, Mohamed Ahdaya, Zhanmiao Zhai, Thomas P. Schuman, Baojun Bai

Chemistry Faculty Research & Creative Works

As one of the most widely used technology to ameliorate the reservoir's heterogeneity, polymer gels have been applied for more than 60 years. However, how to plug fractured reservoirs with significant abnormal features, high temperature and high salinity, especially the divalent cations, is still a challenging target. This work systematically evaluated a novel salt-resistant re-crosslinkable preformed particle gel (SR-RPPG) designed for fractured reservoirs with excellent salt resistance (up to 5 % CaCl₂). We evaluated the swelling kinetics, thermal stability and plugging efficiency of this SR-RPPG. We assessed the swelling kinetic and re-crosslinking behavior of the SR-RPPG through the …

Laboratory Evaluation Of A Novel Self-Healable Polymer Gel For Co2 Leakage Remediation During Co2 Storage And Co2 Flooding, Tao Song, Zhanmiao Zhai, Junchen Liu, Yugandhara Eriyagama, Mohamed Ahdaya, Adel Alotibi, Ze Wang, Thomas P. Schuman, Baojun Bai

Chemistry Faculty Research & Creative Works

For CO₂ storage in subsurface reservoirs, one of the most crucial requirements is the ability to remediate the leakage caused by the natural fractures or newly generated fractures due to the increasing pore pressure associated with CO₂ injection. For CO₂ Enhanced Oil Recovery (EOR), high conductivity features such as fractures and void space conduits can severely restrict the CO₂ sweep efficiency. Polymer gels have been developed to plug the leakage and improve the sweep efficiency. This work evaluated a CO₂ resistant branched self-healable preformed particle gel (CO₂-BRPPG) for CO₂ plugging purpose. This …

Comprehensive Review Of Polymer And Polymer Gel Treatments For Natural Gas-Related Conformance Control, Ali Al Brahim, Baojun Bai, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Conformance problems often exist in natural gas-related activities, resulting in excessive water production from natural gas production wells and/or excessive natural gas production from oil production wells. Several mechanical and chemical solutions were reported in the literature to mitigate the conformance problems. Among the chemical solutions, two classes of materials, namely polymer gels and water-soluble polymers, have been mostly reported. These systems have been mainly reviewed in several studies for their applications as water shutoff treatments for oil production wells. Natural gas production wells exhibit different characteristics and have different properties which could impact the performance of the chemical solutions. …

Systematic Evaluation Of A Novel Self-Healing Poly(Acrylamide-Co-Vinyl Acetate)/Alginate Polymer Gel For Fluid Flow Control In High Temperature And High Salinity Reservoirs, Jingyang Pu, Baojun Bai, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Preferential fluid flow often occurs when water and CO₂ is injected into mature oilfields, sig-nificantly reducing their injection efficiency. Particle gels have been evaluated and applied to control the short circulation problems. This study systematically investigated a novel poly(acrylamide-co-vinyl acetate)/alginate-based interpenetrated gel system (Alg-IPNG) which is designed to control the preferential fluid flow problems in high-temperature reservoirs. Chromium acetate was incorporated into the gel system to provide the delayed crosslinking feature of the particle gels. The alginate polymer system can also take advantage of the Ca²⁺ ions in the formation water, which exist in most reservoirs, to reinforce …

Experimental Data On Water Soluble Polymers Thermal And Hydrolytic Stability, Reactivity Ratios Of Monomers And Frr Calculation For Thermally Stable Preformed Particle Gels Therefrom, Buddhabhushan Salunkhe, Thomas P. Schuman, Ali Al Brahim, Baojun Bai

Chemistry Faculty Research & Creative Works

Experimental data on water soluble polymer thermal and hydrolytic stability in acidic, neutral and basic pH conditions in aqueous solution is presented. Thermal and hydrolytic stability of polymer aqueous solutions were monitored in variable pH medium by aging at 130 °C temperature for different aging time. Polymer viscosity measurements were performed periodically for 3 months. Furthermore, this data can serve as a basis of monomer selection for thermally stable hydrogels for applications like oil recovery, hydrogel coatings for steam sterilized medical devices and other applications. Reactivity ratios were determined for monomers associated to the most stable polymers using ¹H …

4th Annual Umr-Dnr Conference On Energy -- Entire Proceedings, University Of Missouri--Rolla

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

No abstract provided.

The Role Of Natural Gas And Lng In Supplying Our Energy Needs, D. L. Caldwell

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

The domestic natural gas industry experienced a spectacular growth during the two decades from 1950 to 1970. Demand for gas continues to rise and production has peaked at a time when the price for other energy sources is escalating. A price increase can stimulate production over the short term. Massive LNG imports can help the intermediate term supply. The long term natural gas situation is bleak and substitute natural gas sources must be employed. A conservation program and reordering of priorities for energy sources is essential for the United States as well as most industrial nations.

Oil Shale And Its Potential Utilization, G. U. Dineen

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

The large deposits of oil shale in the Green River Formation in Colorado, Utah, and Wyoming offer a potential source of significant quantities of liquid fuels. This paper discusses the location and potential of the resource; the present state of technology for producing shale oil by both aboveground and in situ processes; the characteristics of shale oil; environmental aspects of oil-shale utilization; and recent developments, particularly results of the Department of the Interior’s Prototype Oil Shale Leasing Program, that suggest inauguration of commercial oil-shale processing.

Energy Saving Projects Recently Completed At A Large Petroleum Refinery, J. A. Marshall, A. D. Kiehne

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

A significant reduction in energy consumption per barrel of crude oil processed has been effected at Shell Oil's Wood River, Illinois, Refinery during the past two years. Some of the projects which have resulted in reduced energy consumption are:

1. Improved furnace efficiency through closer surveillance and through installation of optimizing controllers on certain furnaces.

2. Lowered reflux-to-feed ratios on certain fractionating columns following reoptimization of operating conditions with current fuel values.

3. Additional heat exchangers purchased and installed on plants originally designed and optimized at lower fuel values.

This paper discusses examples of each of the above projects and …

A Technique For Improving Stability Of Petroleum Reservoir Simulation Models, M. D. Arnold, T. C. Wilson, A. Herbert Harvey

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

Computational instability may occur in the mathematical simulation of hydrocarbon reservoirs when small inaccuracies in the calculated pressures cause loss of diagonal dominance in the matrix of coefficients. The problem can be resolved by the use of a more precise technique for computation of pressures. However, this stability problem is still troublesome to users of certain types of reservoir simulators. A computational technique which has been found effective in resolving the problem is presented.

1st Umr-Mec Conference On Energy Resources -- Entire Proceedings, University Of Missouri--Rolla

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

No abstract provided.

The Role Of The Doctor Of Engineering Degree In Graduate Education, Wouter Bosch, Robert E. Carlile

Chemistry Faculty Research & Creative Works

No abstract provided.