Open Access. Powered by Scholars. Published by Universities.®
- Institution
Articles 1 - 8 of 8
Full-Text Articles in Chemistry
Synthesis And Characterization Of Some Dioxane Complexes, James Donald Satterlee
Synthesis And Characterization Of Some Dioxane Complexes, James Donald Satterlee
All Master's Theses
The boron trifluoride, tin (IV) fluoride and titanium (IV) fluoride complexes with 1,4-dioxane have been prepared and studied using infrared techniques. The compositions of the complexes have been determined and correspond to the 1:1 adducts in the case of the tin and titanium compounds. The boron trifluoride adduct is a 2:1 (acid:base) adduct. Infrared spectra in the region 1300 cm.-1 to 550 cm.-1 are given and the effects of coordination upon the ligand vibrations are described.
The Chemistry Of Some Unusual Carbodiimides, Donald Melvin Plautz
The Chemistry Of Some Unusual Carbodiimides, Donald Melvin Plautz
Electronic Theses and Dissertations
Several N1-alkyl-N2-(N,N-dialkylamino)carbodiimides, which were found to form dimeric species, were prepared, and the structure of the dimeric species determined. A study of the reaction chemistry of both the monomeric and dimeric carbodiimides led to the conclusion that dimerization occurred via a (π2s + π2a) ground-state, symmetry-allowed mechanism, and that thermal decomposition of the dimeric species occurred via a (π2s +-π2s) excited-state, symmetry-allowed mechanism. Although dialkylphosphoramidates have been shown to be useful intermediates in the preparation of unsaturated organic nitrogen compounds, N-acyl- and N-imino-dialkylphosphorohydrazidates were found to be too unstable, forming trialkylphosphates upon distillation, to be of …
Reactions Of Tin (Iv) Lewis Acids With -Diketones In The Presence Of Pyridine, Diana Deane Carr
Reactions Of Tin (Iv) Lewis Acids With -Diketones In The Presence Of Pyridine, Diana Deane Carr
Dissertations, Theses, and Masters Projects
No abstract provided.
Reactions Of The Tin Tetrahalides With 2,4-Pentanedione In The Presence Of Organic Amines, Kwai-Sam Wong
Reactions Of The Tin Tetrahalides With 2,4-Pentanedione In The Presence Of Organic Amines, Kwai-Sam Wong
Dissertations, Theses, and Masters Projects
No abstract provided.
The Mechanism Of Solvolysis Of Tri-Tert-Butylchloroallene, Whitney Ann Boynton
The Mechanism Of Solvolysis Of Tri-Tert-Butylchloroallene, Whitney Ann Boynton
Dissertations, Theses, and Masters Projects
No abstract provided.
Potential Five-Coordinate Titanium-Diketonate Complexes, Pamela Bowen Barrett
Potential Five-Coordinate Titanium-Diketonate Complexes, Pamela Bowen Barrett
Dissertations, Theses, and Masters Projects
No abstract provided.
Studies In The Preparation Of Metal Enolates Of 3,3,5,5-Tetramethylcyclohexanone And Their Reactions With Lead(Iv) And Mercury(Ii) Acetates, Donald Robert Paveska
Studies In The Preparation Of Metal Enolates Of 3,3,5,5-Tetramethylcyclohexanone And Their Reactions With Lead(Iv) And Mercury(Ii) Acetates, Donald Robert Paveska
Masters Theses
No abstract provided.
The Solvolysis Of Triaryhaloallenes, Henry Wayne Moran
The Solvolysis Of Triaryhaloallenes, Henry Wayne Moran
Dissertations, Theses, and Masters Projects
No abstract provided.