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Chemistry Commons

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Organic Chemistry

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William & Mary

1995

Articles 1 - 4 of 4

Full-Text Articles in Chemistry

Acid Dissociation Of Chloroguaiacols And Ph Dependent Sorption To Estuarine Sediments, Jennifer Lisa Gundersen Jan 1995

Acid Dissociation Of Chloroguaiacols And Ph Dependent Sorption To Estuarine Sediments, Jennifer Lisa Gundersen

Dissertations, Theses, and Masters Projects

Chloroguaiacols are common components of bleached kraft pulp mill effluent known to bioaccumulate in aquatic organisms, and sorb onto particulate material and sediments. Ionization properties of the chloroguaiacols must be known in order to explain their sorptive behavior in aquatic systems. to obtain this information, thermodynamic acid dissociation constants (p&K\sb{lcub}\rm a{rcub})& of guaiacol (o-methoxyphenol) and nine chloroguaiacols have been determined by spectrophotometric methods. These experimental p&K\sb{lcub}\rm a{rcub}& values have been compared with literature values, values predicted by the Hammett equation and predictions by quantum chemical calculations using MOPAC 6.0 with AM1 and MNDO Hamiltonian operators. Experimental and predicted acidities were …


The Selective Synthesis Of 3-Alkylidenetetrahydrofurans, Robin Elaine Southward Jan 1995

The Selective Synthesis Of 3-Alkylidenetetrahydrofurans, Robin Elaine Southward

Dissertations, Theses, and Masters Projects

No abstract provided.


The Synthesis Of Benzophenane 3,5-Dicarboxylic Acid For The Double Capping Of Beta-Cyclodextrin, Jaydee Dones Cabral Jan 1995

The Synthesis Of Benzophenane 3,5-Dicarboxylic Acid For The Double Capping Of Beta-Cyclodextrin, Jaydee Dones Cabral

Dissertations, Theses, and Masters Projects

No abstract provided.


Blends Of Reactive Diluents With Phenylethynyl-Terminated Arylene Ether Oligomers, Rachel Louise Knudsen Jan 1995

Blends Of Reactive Diluents With Phenylethynyl-Terminated Arylene Ether Oligomers, Rachel Louise Knudsen

Dissertations, Theses, and Masters Projects

No abstract provided.