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Full-Text Articles in Chemistry
Characterization Of Ionic, Dipolar And Molecular Mobility In Polymer Systems, Zhenrong Guo
Characterization Of Ionic, Dipolar And Molecular Mobility In Polymer Systems, Zhenrong Guo
Dissertations, Theses, and Masters Projects
Changes in the ionic and dipolar molecular mobility in a polymer system are the basis for the changes in the dielectric mechanical properties of polymer materials. Frequency Dependent Dielectric Measurements (FDEMS) and Ion Time-of-Flight (ITOF) are two important techniques to investigate ionic and dipolar molecular mobility in polymer systems. The results can be related to the macro- and molecular dielectric, electrical and dynamic properties of polymeric materials. The combination of these two methods provides a full view of electric, dielectric and dynamic behavior for the systems as they undergo chemical and/or physical changes during polymerization crystallization, vitrification, and/or phase separation.;The …
Photochemical Modification Of Polyethylene Terephthalate Surface, Zhengmao Zhu
Photochemical Modification Of Polyethylene Terephthalate Surface, Zhengmao Zhu
Dissertations, Theses, and Masters Projects
The prospect of obtaining desired surface-mediated characteristics while retaining bulk-mediated physical properties and avoiding potential environmental issues with wet chemical technology lends considerable appeal to photochemical approaches to surface modification.;We undertook a combined experimental and computational approach to investigate the effect of deep UV irradiation on the polyethylene terephthalate (PET) surface. its response to 172 nm UV from a xenon examiner lamp in the absence of oxygen was characterized with X-ray Photoelectron Spectroscopy (XPS), Time of Flight/Secondary Ion Mass Spectrometry (ToF/SIMS), transmission infrared spectroscopy (IR), and Atomic Force Microscopy (AFM). The surface chemistry details suggested that the primary photochemical reactions …
Solid State Nmr Characterization Of Conductive Polyanilines, Yanina Anatolievna Goddard
Solid State Nmr Characterization Of Conductive Polyanilines, Yanina Anatolievna Goddard
Dissertations, Theses, and Masters Projects
Different forms of ring deuterated polyaniline with different conductivity have been characterized by solid state deuteron nuclear magnetic resonance.;Quadrupole echo (QE) spectra of all forms of polyaniline consist of a superposition of lineshapes for nearly rigid aromatic rings and a small fraction of rings which undergo fast 180?? flips. The intensity of the fast flipping component is temperature dependent and different for conductive emeraldine salt (ES) and non-conductive emeraldine base (EB). This is a manifestation of the different structure and morphology of these polymers.;Simultaneous measurements of QE lineshapes and the relaxation time anisotropies allowed an accurate description of motion in …
Synthesis And Characterization Of Polyimide Residuum, Friable Balloons, Microspheres And Foams, Erik Saul Weiser
Synthesis And Characterization Of Polyimide Residuum, Friable Balloons, Microspheres And Foams, Erik Saul Weiser
Dissertations, Theses, and Masters Projects
In order to meet requirements of future NASA systems for advanced polymeric cellular materials, research was undertaken to develop the next generation of polyimide foams which could be utilized as a reusable structural insulation on future Reusable Launch Vehicle (RLV) Programs. This research activity focused on developing polyimide foam and foam structures which were made using monomeric solutions or salt solutions formed from the reaction of a dianhydride and diamine dissolved in a mixture of foaming agents and alkyl alcohols. This process produced a precursor solid residuum which could then be manufactured into foams, friable balloons and microspheres. Polyimide foams …
In-Situ Frequency-Dependent Electromagnetic Sensing For Monitoring Physical And Chemical Attributes During Chemical Processing, Jeffrey David Rogozinski
In-Situ Frequency-Dependent Electromagnetic Sensing For Monitoring Physical And Chemical Attributes During Chemical Processing, Jeffrey David Rogozinski
Dissertations, Theses, and Masters Projects
The objective of this research was to develop an in-situ sensing technique that monitors the molecular-level response of ions and dipoles to an applied electric field in order to characterize the changes in state of a polymer resin during chemical processing. This technique needs to be capable of monitoring the reaction progress not only in the laboratory setting but also in-situ in the processing tool or reaction environment. Frequency Dependent Electromagnetic Sensing (FDEMS) was selected for this task.;This dissertation investigates the applicability of FDEMS to monitoring two types of processing methods: reactive and batch reactor. The reactive processing system examined …
Fabrications And Characterizations Of Boron Containing Polyimides For Radiation Shielding, Christopher Scott Pugh
Fabrications And Characterizations Of Boron Containing Polyimides For Radiation Shielding, Christopher Scott Pugh
Dissertations, Theses, and Masters Projects
No abstract provided.
Platinized Tin Oxide: A Low-Temperature Oxidation Catalyst, Erik Joshua Kielin
Platinized Tin Oxide: A Low-Temperature Oxidation Catalyst, Erik Joshua Kielin
Dissertations, Theses, and Masters Projects
Some combinations of noble metal and reducible metal oxide possess a synergistic level of activity for the catalytic oxidation of CO at lower temperatures and partial pressures of O2 than can be obtained by either component alone. The most promising candidates, Au on MnO2 and Pt on SnO 2, were investigated for the effects on activity of noble metal loading, of reductive pretreatment at elevated temperature, and of reaction gas mixture composition. Optimum activity was obtained at a noble metal loading of 28% Au/MnO2 and 17% Pt/SnO2. Both catalysts benefitted from reductive CO pretreatment at 125??C. Both catalysts showed enhanced …
Correlation Of Dynamic Dielectric Properties To Reaction Kinetics And Changing Mechanical Properties Of Epoxy Resins During Cure, Yunfei Wang
Dissertations, Theses, and Masters Projects
The principal objective of this paper is to describe how complex impedance, obtained from frequency dependent dielectric sensing technique, can be used as an effective diagnostic tool for in situ real-time investigation in the fabrication of thermoset structures.;Two epoxy systems (Pr500 from 3M and My720 from Ciba Geigy) with different functionality are characterized in terms of their dielectric, thermal, and rheological behavior. It is observed that there is a one to one relationship between Tg and conversion which is independent of cure temperature. The chemical kinetics of the reaction is satisfactorily described by an autocatalyzed reaction mechanism. The chemical rate …
The Synthesis Of Reflective And Electrically Conductive Polyimide Films Via An In Situ Self-Metallization Procedure Using Silver(I) Complexes, Robin Elaine Southward
The Synthesis Of Reflective And Electrically Conductive Polyimide Films Via An In Situ Self-Metallization Procedure Using Silver(I) Complexes, Robin Elaine Southward
Dissertations, Theses, and Masters Projects
Optically reflective polyimide films have been prepared by the incorporation of silver(I) acetate and a {dollar}\beta{dollar}-diketone solubilizing agent, hexafluoroacetylacetone (HFAH), into a dimethylacetamide solution of the poly(amic acid) formed from {dollar}3,3\sp\prime,4,4\sp\prime{dollar}-benzophenonetetracarboxylic acid dianhydride (BTDA) and {dollar}4,4\sp\prime{dollar}-oxydianiline {dollar}(4,4\sp\prime{dollar}-ODA). Optically reflective and conductive polyimide films have been prepared by replacing the {dollar}\beta{dollar}-diketone (HFAH), with the less substituted {dollar}\beta{dollar}-diketone, trifluoroacetylacetone (TFAH). The former system has been both cast directly from the poly(amic acid) resin and cast from the poly(amic acid) resin onto a fully imidized {dollar}\rm BTDA/4,4\sp\prime{dollar}-ODA base (forming a metallized topcoat). Thermal curing of the silver(I)-containing poly(amic acid) leads to imidization with …
Characterizing The Degradation Of Nylon-11 And Pvdf In A Flexible Oil Pipe And Cure Monitoring Of Chemflake Vinylester, John Chen Yang
Characterizing The Degradation Of Nylon-11 And Pvdf In A Flexible Oil Pipe And Cure Monitoring Of Chemflake Vinylester, John Chen Yang
Dissertations, Theses, and Masters Projects
No abstract provided.
Mechanisms Of Poly(Vinyl Chloride) Fire Retardance And Smoke Suppression Induced By Copper Additives, Jong Paul Jeng
Mechanisms Of Poly(Vinyl Chloride) Fire Retardance And Smoke Suppression Induced By Copper Additives, Jong Paul Jeng
Dissertations, Theses, and Masters Projects
The purpose of this study was to elucidate the mechanisms of PVC fire retardance and smoke suppression induced by copper additives.;The experimental approaches involved: (1) the use of activated copper (Cu{dollar}\sp0{dollar}) to study PVC model-compound reactions and the crosslinking of PVC and (2) the pyrolysis of PVC model compounds in the presence of several copper additives in order to examine all of the possible chemical reactions involved in the formation of heavy products.;The results obtained from experiments with activated copper and allylic chloride model compounds suggest that the reductive coupling mechanism is a viable process in PVC. The Cu{dollar}\sp0{dollar} that …
Metallization Of Polyimide Films To Enhance Dimensional Stability And To Achieve Reflective And Conductive Surfaces, David Scott Thompson
Metallization Of Polyimide Films To Enhance Dimensional Stability And To Achieve Reflective And Conductive Surfaces, David Scott Thompson
Dissertations, Theses, and Masters Projects
No abstract provided.
Physical And Mechanical Behavior Of Amorphous Poly(Arylene Ether-Co-Imidazole)S And Poly(Arylene Ether-Co-Imidazole) Modified Epoxies, Patricia D. Roberts-Mcdaniel
Physical And Mechanical Behavior Of Amorphous Poly(Arylene Ether-Co-Imidazole)S And Poly(Arylene Ether-Co-Imidazole) Modified Epoxies, Patricia D. Roberts-Mcdaniel
Dissertations, Theses, and Masters Projects
Due to the high crosslink density of cured epoxy resins they generally lack damage tolerance. A significant amount of research has been expended to improve the toughness of epoxies. Research into the area of thermoplastic epoxy modifiers has begun to overcome some of the limitations of early methods of epoxy toughening (i.e. lower modulus and thermal stability).;This study examines the physical and mechanical properties of random poly(arylene ether-co-imidazole) (PAE-co-Is) and the characterization of epoxies modified with poly(arylene ether-co-imidazole)s.;Poly(arylene ether-co-imidazole)s exhibited the highest solubility in N,N,N{dollar}\rm\sp\prime,N\sp\prime,{dollar}-tetraglycidyl- 4,4{dollar}\sp\prime{dollar} diaminodiphenyl methane (TGMDA) based resins. The high molecular weight polymers caused significant decreases in …
The Preparation Of And Upper Atmospheric Effects On Kevlar Films, Patricia Lynne Pate
The Preparation Of And Upper Atmospheric Effects On Kevlar Films, Patricia Lynne Pate
Dissertations, Theses, and Masters Projects
No abstract provided.
The Imidization Of Pmr-15 Aromatic Thermosetting Polyimide, Thomas Clifton Prettyman
The Imidization Of Pmr-15 Aromatic Thermosetting Polyimide, Thomas Clifton Prettyman
Dissertations, Theses, and Masters Projects
No abstract provided.