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Quaternary Trialkyl(Polyfluoroalkyl)Ammonium Salts Including Liquid Iodides, Om D. Gupta, Douglas Armstrong, Jean'ne M. Shreeve
Quaternary Trialkyl(Polyfluoroalkyl)Ammonium Salts Including Liquid Iodides, Om D. Gupta, Douglas Armstrong, Jean'ne M. Shreeve
Faculty Scholarship – Chemistry
New quaternary ammonium salts that contain polyfluorinated alkyl substituents were prepared by the polyfluoroalkylation of tertiary amines with polyfluorinated alkyl iodides. Metathesis reactions of the iodide salts with fluorine-containing anions resulted in new low melting salts. The iodide salts of the tri(isooctyl)polyfluoroalkyl amines are also liquids at 25°C.