Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 1 of 1
Full-Text Articles in Chemistry
(4-Hydroxy-2-Oxidobenzaldehyde Thiosemicarbazonato-Kappa O-3(2),N-1,S)(1, 10-Phenanthroline-Kappa N-2,N ')Zinc(Ii) Dimethyl Sulfoxide Disolvate Monohydrate, Tan Kong Wai, Ng C. H., Ng S. W., Maah M. J.
(4-Hydroxy-2-Oxidobenzaldehyde Thiosemicarbazonato-Kappa O-3(2),N-1,S)(1, 10-Phenanthroline-Kappa N-2,N ')Zinc(Ii) Dimethyl Sulfoxide Disolvate Monohydrate, Tan Kong Wai, Ng C. H., Ng S. W., Maah M. J.
Tan Kong Wai
The Zn-II atom in the title compound, [Zn(C8H7N3O2S)-(C12H8N2)]center dot 2C(2)H(6)OS center dot H2O, is N,N '-chelated by the N-heterocycle and N, O, S-chelated by the deprotonated Schiff base in a distorted square-pyramidal enviroment. Hydrogen bonds link the mononuclear molecule, the water and the dimethyl sulfoxide (DMSO) molecules into a linear chain motif. One DMSO molecule is disordered over two positions in respect of the S atom in an approximate 1:1 ratio.