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Full-Text Articles in Chemistry
Cadmium Chloride Dimensionality Changes From Ortho-Substituted Anilines, Stephanie Cernicek
Cadmium Chloride Dimensionality Changes From Ortho-Substituted Anilines, Stephanie Cernicek
Dissertations
Inorganic-organic hybrid metal halide materials have been of great interest recently due to the useful properties offered by such a combination. The inorganic portions usually consisting of MX62- subunits, (M = Pb, Sn, Cd, Cu; X = Cl, Br, I) most often form 2-D perovskite layers where the metals are bridged by corner sharing halides. The organic portion, usually consisting of primary amines or anilines provides a template for the inorganic framework and in some cases, dictates the dimensionality (2-D, 1-D, 0-D) of the network. These materials have various applications in host-guest chemistry catalysis, and gas storage, or …
Syntheses, Structures And Magnetic Properties Of Cyano-Bridged Transition Metal Compounds, Uma Prasad Mallik
Syntheses, Structures And Magnetic Properties Of Cyano-Bridged Transition Metal Compounds, Uma Prasad Mallik
Dissertations
To investigate the hypotheses, that systematically changing the electronic and relative sizes of tricyanido building blocks will tune magnetic properties of their cluster derivatives, we prepared two new tricyanido pyrazolylborate complexes, [NEt4][(Tp*Me)Fe(CN)3]·H2O and [NEt4][(Tp*Bn)FeIII(CN)3]·H2O·MeOH, and investigated their self-assembly. The new building blocks were prepared, structurally characterized, and their coordination chemistry explored to prepare small molecule-based magnetic materials.
Three bent trinuclear ferromagnetic cluster derivatives of {[(Tp*Me)FeIII(CN)3]2[NiII(L)2]}·n(solvent) [L = …