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Full-Text Articles in Chemistry
Exploring Heterometallic Beta-Diketonates For The Low Temperature Synthesis Of Energy-Related Oxide And Fluoride Materials, Matthew Christopher Barry
Exploring Heterometallic Beta-Diketonates For The Low Temperature Synthesis Of Energy-Related Oxide And Fluoride Materials, Matthew Christopher Barry
Legacy Theses & Dissertations (2009 - 2024)
In order to circumvent the issues associated with traditional ceramic methods such as
Mixed Ligand Approach To Design Heterometallic Single-Source Precursors For Low-Temperature Preparation Of Oxide Materials, Craig Matthew Lieberman
Mixed Ligand Approach To Design Heterometallic Single-Source Precursors For Low-Temperature Preparation Of Oxide Materials, Craig Matthew Lieberman
Legacy Theses & Dissertations (2009 - 2024)
There is a considerable interest in the use of metal oxides for development of novel high-technological materials such as gas sensors, multiferroics, and electrocatalysts. In particular, the design of complex oxides, which incorporate more than one type of metal atom, is focused on enriching chemical and physical properties of the target materials and allowing for increased functionality. In order to replace the harsh conditions associated with traditional synthetic routes that often require high temperatures and/or pressures, new soft chemistry methods for the preparation of mixed-metal oxide materials have been developed. One of the most promising directions is the emergence of …
Heterometallic Beta-Diketonates And Oxo-Diketonates As Single Source Precursors For The Synthesis Of Oxide Materials, Haitao Zhang
Heterometallic Beta-Diketonates And Oxo-Diketonates As Single Source Precursors For The Synthesis Of Oxide Materials, Haitao Zhang
Legacy Theses & Dissertations (2009 - 2024)
The focus of this investigation was to develop a simple, high-yield synthetic approach to heterometallic diketonates using the same construction principles as for their polynuclear homometallic analogs. Several low-temperature solid-state synthetic routes were suggested that appear to be general for the preparation of heterometallic diketonates incorporating a wide range of s-, p-, d-, and f-metals. Using this investigative approach, two families of bimetallic homoleptic diketonates that contain heavy main group (BiIII, PbII) and the first row divalent transition metals (Mn, Fe, Co, Ni, Cu, and Zn) have been obtained. The heterometallic molecules that are held together by strong Lewis acid-base …