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Crystal Structure Of {N-[(6-Bromopyridin-2-Yl)- (Phenyl)Methylidene]-2,6-Dimethylaniline-Κ²N,N'}- Dichloridozinc Dichloromethane Hemisolvate, Bradley M. Wile
Crystal Structure Of {N-[(6-Bromopyridin-2-Yl)- (Phenyl)Methylidene]-2,6-Dimethylaniline-Κ²N,N'}- Dichloridozinc Dichloromethane Hemisolvate, Bradley M. Wile
Chemistry and Biochemistry Faculty Scholarship
The solvated title compound, [ZnCl2(C20H17BrN2)]·0.5CH2Cl2, comprises a bidentate iminopyridine ligand and two Cl atoms bound to a zinc2+ cation in a distorted tetrahedral arrangement. The chelate bond lengths are consistent with localized C=N double bonds and a C—C single bond, as expected for an unreduced ligand bound to a closed-shell transition metal cation. Apart from weak nonclassical C—HCl hydrogen bonds between the complex molecules and the disordered solvent molecules (occupancy = 0.5), no further significant intermolecular interactions are observed.
Modification Of A Junior-Level Capstone Course To Incorporate Scientific Writing, Bradley M. Wile
Modification Of A Junior-Level Capstone Course To Incorporate Scientific Writing, Bradley M. Wile
Chemistry and Biochemistry Faculty Scholarship
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