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Full-Text Articles in Chemistry

Petrology And Geochemistry Of Evolved Achondrites: Planetesimal Mantles And Crusts, Zoltan Vaci Jul 2021

Petrology And Geochemistry Of Evolved Achondrites: Planetesimal Mantles And Crusts, Zoltan Vaci

Earth and Planetary Sciences ETDs

Melting and differentiation are fundamental to early solar system evolution on planetary bodies that accreted enough material to heat up radioactively or through impacts and breach their solidi. Partially and fully melted material is present in the meteorite record in the form of primitive achondrites and achondrites, which are fragments of planetesimals that underwent heating events in the first few million years of solar system history. Although the vast majority of this material is mafic or ultramafic, new evolved samples, recovered in the last few decades, are pushing the petrologic and geochemical boundaries of planetesimal melting, differentiation, and crust formation. …


Comprehensive Silica Removal With Ferric Compounds For Industrial Wastewater Reuse, Ehren D. Baca Jun 2017

Comprehensive Silica Removal With Ferric Compounds For Industrial Wastewater Reuse, Ehren D. Baca

Civil Engineering ETDs

Cooling towers, integrated circuit (IC) manufacture and reverse osmosis (RO) generate copious amounts of wastewater high in colloidal and reactive silica inhibiting on-site or synergistic reuse. Silica present in cooling water can reach solubility limits via evaporation and form impervious scale on heat transfer surfaces that decreases efficiency. When water is treated by RO operating at high rejection, silica forms difficult-to-remove scale on the membrane feed side in the form of glassy patches and communities of aggregate particles, inhibiting aspirations for zero liquid discharge. Current methods for silica scale mitigation include abundant dosing with chemical antiscalents or complex operating schemes. …