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Articles 1 - 30 of 56
Full-Text Articles in Chemistry
Spectroscopic Investigation Of The Chemical And Electronic Properties Of Chalcogenide Materials For Thin-Film Optoelectronic Devices, Kimberly Horsley
Spectroscopic Investigation Of The Chemical And Electronic Properties Of Chalcogenide Materials For Thin-Film Optoelectronic Devices, Kimberly Horsley
UNLV Theses, Dissertations, Professional Papers, and Capstones
Chalcogen-based materials are at the forefront of technologies for sustainable energy production. This progress has come only from decades of research, and further investigation is needed to continue improvement of these materials.
For this dissertation, a number of chalcogenide systems were studied, which have applications in optoelectronic devices, such as LEDs and Photovoltaics. The systems studied include Cu(In,Ga)Se2 (CIGSe) and CuInSe2 (CISe) thin-film absorbers, CdTe-based photovoltaic structures, and CdTe-ZnO nanocomposite materials. For each project, a sample set was prepared through collaboration with outside institutions, and a suite of spectroscopy techniques was employed to answer specific questions about the system. These …
Catechol Oxidation By Ozone And Hydroxyl Radicals At The Air-Water Interface, Elizabeth A. Pillar, Robert C. Camm, Marcelo I. Guzman
Catechol Oxidation By Ozone And Hydroxyl Radicals At The Air-Water Interface, Elizabeth A. Pillar, Robert C. Camm, Marcelo I. Guzman
Chemistry Faculty Publications
Anthropogenic emissions of aromatic hydrocarbons promptly react with hydroxyl radicals undergoing oxidation to form phenols and polyphenols (e.g., catechol) typically identified in the complex mixture of humic-like substances (HULIS). Because further processing of polyphenols in secondary organic aerosols (SOA) can continue mediated by a mechanism of ozonolysis at interfaces, a better understanding about how these reactions proceed at the air–water interface is needed. This work shows how catechol, a molecular probe of the oxygenated aromatic hydrocarbons present in SOA, can contribute interfacial reactive species that enhance the production of HULIS under atmospheric conditions. Reactive semiquinone radicals are quickly produced upon …
Peptide Arrays For Detecting Naphthenic Acids In Oil Sands Process Affected Water, Kamaljit Kaur, Subir Bhattacharjee, Rajesh G. Pillai, Sahar Ahmed, Sarfuddin Azmi
Peptide Arrays For Detecting Naphthenic Acids In Oil Sands Process Affected Water, Kamaljit Kaur, Subir Bhattacharjee, Rajesh G. Pillai, Sahar Ahmed, Sarfuddin Azmi
Pharmacy Faculty Articles and Research
Naphthenic acids (NAs) are water-soluble components of petroleum. The characterization and quantification of NAs by analytical methods have proved quite challenging, whilst the toxic effects of these water-soluble compounds on a variety of organisms adversely affecting reproduction and steroid production is becoming apparent. In this study, we report a fluorescence-based competitive binding method for rapid sensing of the presence of NAs using cellulosic peptide array strips as sensors. The peptide array was designed from sequences derived from the estrogen receptor (ER). Several of these peptides were able to detect the presence of NAs at low micromolar (∼5 mg L−1 …
Composition Of Secondary Organic Aerosols, Ryan Caylor, Felisha Imholt, Matthew E. Wise, John Shilling
Composition Of Secondary Organic Aerosols, Ryan Caylor, Felisha Imholt, Matthew E. Wise, John Shilling
Matthew E. Wise
Interactive Comment On “Iodine Oxide In The Global Marine Boundary Layer” By C. Prados-Roman Et Al., Marcelo I. Guzman
Interactive Comment On “Iodine Oxide In The Global Marine Boundary Layer” By C. Prados-Roman Et Al., Marcelo I. Guzman
Chemistry Faculty Publications
No abstract provided.
Iron Sources And Dissolved-Particulate Interactions In The Seawater Of The Western Equatorial Pacific, Iron Isotope Perspectives, M. Labatut, F. Lacan, C. Pradoux, J. Chmeleff, A. Radic, J. W. Murray, F. Poitrasson, Anne M. Johansen, F. Thil
Iron Sources And Dissolved-Particulate Interactions In The Seawater Of The Western Equatorial Pacific, Iron Isotope Perspectives, M. Labatut, F. Lacan, C. Pradoux, J. Chmeleff, A. Radic, J. W. Murray, F. Poitrasson, Anne M. Johansen, F. Thil
All Faculty Scholarship for the College of the Sciences
This work presents iron isotope data in the western equatorial Pacific. Marine aerosols and top core margin sediments display a slightly heavy Fe isotopic composition (δ56Fe) of 0.33 ± 0.11‰ (2SD) and 0.14 ± 0.07‰, respectively. Samples reflecting the influence of Papua New Guinea runoff (Sepik River and Rabaul volcano water) are characterized by crustal values. In seawater, Fe is mainly supplied in the particulate form and is found with a δ56Fe between −0.49 and 0.34 ± 0.07‰. The particulate Fe seems to be brought mainly by runoff and transported across continental shelves and slopes. …
Carbon And Nitrogen Dynamics From Slow Pools Of Soil Organic Matter In A Temperate Forest: Pyrogenic Organic Matter And And Root Litter, Fernanda Dos Santos
Carbon And Nitrogen Dynamics From Slow Pools Of Soil Organic Matter In A Temperate Forest: Pyrogenic Organic Matter And And Root Litter, Fernanda Dos Santos
Dissertations, Theses, and Capstone Projects
Soil organic matter (SOM) is the dominant reservoir of organic carbon (OC) in terrestrial ecosystems, storing approximately three times the size of the C pool in the atmosphere. In temperate forests, a major fraction of the SOM consists of slowly decaying soil organic C (SOC) pools. While slowly cycling C pools constitute a large reservoir of stable C in soils, the dominant environmental factors controlling this C pool remain unresolved. This research investigates two significant, but poorly characterized slowly decaying C pools: fine root litter (< 2mm) and thermally altered plant biomass (pyrogenic organic matter, PyOM). Specifically, I used compound-specific stable isotope analysis (13C and 15N) as my main methodological approach to examine the (1) …
The Atmosphere Can Be A Source Of Certain Water Soluble Volatile Organic Compounds In Urban Streams, Scott J. Kenner, David A. Bender, James F. Pankow, John S. Zogorski
The Atmosphere Can Be A Source Of Certain Water Soluble Volatile Organic Compounds In Urban Streams, Scott J. Kenner, David A. Bender, James F. Pankow, John S. Zogorski
Chemistry Faculty Publications and Presentations
Surface water and air volatile organic compound (VOC) data from 10 U. S. Geological Survey monitoring sites were used to evaluate the potential for direct transport of VOCs from the atmosphere to urban streams. Analytical results of 87 VOC compounds were screened by evaluating the occurrence and detection levels in both water and air, and equilibrium concentrations in water (C-w(s)) based on the measured air concentrations. Four compounds (acetone, methyl tertiary butyl ether, toluene, and m- & p-xylene) were detected in more than 20% of water samples, in more than 10% of air samples, and more than 10% of detections …
Degradation Of Protective Glove Materials Exposed To Commercial Products: A Comparative Study Of Tensile Strength And Gravimetric Analyses, Todd B. Pelham
Degradation Of Protective Glove Materials Exposed To Commercial Products: A Comparative Study Of Tensile Strength And Gravimetric Analyses, Todd B. Pelham
Electronic Theses, Projects, and Dissertations
ABSTRACT
Current glove guides attempt to assist in recommending which type of glove is appropriate for handling chemicals; however, they include information on less than 1% of the 89 million chemical products available today.
This study offers a solution by testing five durable polymer materials against 50 chemicals, using two rapid chemical degradation assessment techniques. The first technique involves gravimetric analysis of the weight change following constant immersion against the chemical mixture. The second method uses tensile strength to assess molecular changes in the polymer structure.
This study is focused on addressing three issues of concern. First, this study examines …
Evaluating Contaminants Of Emerging Concern In Commercial Biosolid-Based Fertilizers, John Hemmerling, Michael L. Mashtare, Linda S. Lee
Evaluating Contaminants Of Emerging Concern In Commercial Biosolid-Based Fertilizers, John Hemmerling, Michael L. Mashtare, Linda S. Lee
The Summer Undergraduate Research Fellowship (SURF) Symposium
The production and popularity of commercially available biosolid-based fertilizers are increasing because of their economic, environmental, and plant nutrition benefits, particularly in urban and suburban areas. Because biosolid-based fertilizers are derived from waste water treatment plant residuals, we hypothesized that there is the potential for micropollutants to persist in these products. Their presence would be of particular concern due to their potential impact on human and ecological health and risk of bioaccumulation. This study involves quantifying contaminants of emerging concern in three biosolid-based fertilizers, and 2 non-biosolid-based fertilizers, a composted animal manure and an organic compost. Our extraction method employed …
Laboratory Evaluation Of Black Carbon Deposition Onto Snow And Transport Via Snowmelt, Larry D. Hermanson, Joshua P. Schwarz
Laboratory Evaluation Of Black Carbon Deposition Onto Snow And Transport Via Snowmelt, Larry D. Hermanson, Joshua P. Schwarz
STAR Program Research Presentations
Black carbon (BC) is an aerosol material produced by incomplete combustion of fossil fuels and biomass. BC has been shown to be the second most important anthropogenic climate warming agent after carbon dioxide due to its ability to absorb solar radiation, influence cloud behavior, and accelerate snow melt. BC in otherwise clean snow can significantly reduce its reflectivity. In order to learn about the significance of BC contamination in snow, we explored the deposition of BC onto snow and the transport of BC in snow during snowmelt. A Single Particle Soot Photometer (SP2), was used to measure the concentration and …
Exploring Soil Moisture Protocol Alternatives For The Classroom Setting, Garrett Smith
Exploring Soil Moisture Protocol Alternatives For The Classroom Setting, Garrett Smith
STAR Program Research Presentations
Climate change poses a direct threat to future water resources but current climate models suffer from uncertainties regarding the availability of regional water. SMAP or the Soil Moisture Active Passive mission seeks to make improvements to climate models by taking highly accurate, high resolution measurements of global soil moisture. To engage students around the world in a collection of meaningful data that may support the SMAP satellite mission, the Global Learning and Observations to Benefit the Environment program or GLOBE, has forged a partnership with NASA and JPL. GLOBE brings the power of citizen science to the SMAP mission, empowering …
Speciation Behavior Of Americium Higher Oxidation States For The Separation Of Americium From Curium, Catherine Lynn Riddle
Speciation Behavior Of Americium Higher Oxidation States For The Separation Of Americium From Curium, Catherine Lynn Riddle
UNLV Theses, Dissertations, Professional Papers, and Capstones
Several countries are currently expanding the use of nuclear energy as a method for the safe generation of carbon free energy and a number are evaluating starting up a nuclear power program. Closed fuel cycle technologies may be key to waste reduction and a sustainable nuclear energy future and to support the development of more efficient fuel cycles, the investigation of the chemical properties of key actinides is at the forefront of separations research. In this work the characterization of higher oxidation states of americium (Am) has been performed using spectroscopic methods. Americium in the formal oxidation state of Am(V) …
Carbon Sequestration In Tidal Salt Marshes And Mangrove Ecosystems, Carlos Eduardo Quintana-Alcantara
Carbon Sequestration In Tidal Salt Marshes And Mangrove Ecosystems, Carlos Eduardo Quintana-Alcantara
Master's Projects and Capstones
Wetlands are dynamic systems that provide support to vital environmental functions and services. Wetlands take part in the global carbon cycle by holding organic carbon in biomass, soils and sediments. In recent years, the wetland carbon sequestration capacity has been researched worldwide due to the increase of the concentrations of greenhouse gasses implicated in global warming and climate change. Although coastal wetlands release the greenhouse gasses carbon dioxide, methane and nitrous oxide, these ecosystems maintain high performance in offsetting significant amounts of atmospheric carbon. This paper investigated the carbon sequestration capacity of coastal wetland ecosystems summarizing the environmental conditions and …
Volume 06, Kristen Gains, Amanda Willis, Holly Backer, Monika Gutierrez, Cara O'Neal, Sara Nelson, Sasha Silberman, Jessica Beardsley, Jamie Gardner, Edward Peeples, Matthew Sakach, Tess Lione, Emily Wilkins, Kelsey Holt, Jessica Page, Jamie Clift, Charles Vancampen, Gilbert Hall, Jenny Nehrt, Kasey Dye, Amanda Tharp, Jamie Leeuwrik, Ashley Mcgee, Emily Poulin, Michael Kropf, Nick Pastore, Austin Polasky, Morgan Glasco, Laura L. Kahler, Melinda L. Edwards, Brandon C. Smith, Mariah Asbell, Cabell Edmunds, Amelia D. Perry, Alyssa Hayes, Irina Boothe, Perry Bason, James Early
Volume 06, Kristen Gains, Amanda Willis, Holly Backer, Monika Gutierrez, Cara O'Neal, Sara Nelson, Sasha Silberman, Jessica Beardsley, Jamie Gardner, Edward Peeples, Matthew Sakach, Tess Lione, Emily Wilkins, Kelsey Holt, Jessica Page, Jamie Clift, Charles Vancampen, Gilbert Hall, Jenny Nehrt, Kasey Dye, Amanda Tharp, Jamie Leeuwrik, Ashley Mcgee, Emily Poulin, Michael Kropf, Nick Pastore, Austin Polasky, Morgan Glasco, Laura L. Kahler, Melinda L. Edwards, Brandon C. Smith, Mariah Asbell, Cabell Edmunds, Amelia D. Perry, Alyssa Hayes, Irina Boothe, Perry Bason, James Early
Incite: The Journal of Undergraduate Scholarship
Introduction from Dean Dr. Charles Ross
Caught Between Folklore and the Cold War: The Americanization of Russian Children's Literature by Kristen Gains
Graphic Design by Amanda Willis
Graphic Design by Holly Backer
Prejudices in Swiss German Accents by Monika Gutierrez
Photography by Cara O'Neal
Photography by Sara Nelson
Edmund Tyrone's Long Journey through Night by Sasha Silberman
Photography by Jessica Beardsley
Photography by Jamie Gardner and Edward Peeples
The Republican Razor: The Guillotine as a Symbol of Equality by Jamie Clift
Graphic Design by Matthew Sakach
Genocide: The Lasting Effects of Gender Stratification in Rwanda By Tess Lione and Emily …
A Review Of Air–Ice Chemical And Physical Interactions (Aici): Liquids, Quasi-Liquids, And Solids In Snow, T. Bartels-Rausch, H-W Jacobi, T. F. Kahan, J. L. Thomas, E. S. Thomson, J. P. D. Abbatt, M. Ammann, J. R. Blackford, H. Bluhm, Chris Boxe, F. Domine, M. M. Frey, I. Gladich, M. I. Guzmán, D. Heger, Th. Huthwelker, P. Klán, W. F. Kuhs, M. H. Kuo, S. Maus, S. G. Moussa, V. F. Mcneill, J. T. Newberg, J. B. C. Pettersson, M. Roeselová, J. R. Sodeau
A Review Of Air–Ice Chemical And Physical Interactions (Aici): Liquids, Quasi-Liquids, And Solids In Snow, T. Bartels-Rausch, H-W Jacobi, T. F. Kahan, J. L. Thomas, E. S. Thomson, J. P. D. Abbatt, M. Ammann, J. R. Blackford, H. Bluhm, Chris Boxe, F. Domine, M. M. Frey, I. Gladich, M. I. Guzmán, D. Heger, Th. Huthwelker, P. Klán, W. F. Kuhs, M. H. Kuo, S. Maus, S. G. Moussa, V. F. Mcneill, J. T. Newberg, J. B. C. Pettersson, M. Roeselová, J. R. Sodeau
Publications and Research
Snow in the environment acts as a host to rich chemistry and provides a matrix for physical exchange of contaminants within the ecosystem. The goal of this review is to summarise the current state of knowledge of physical processes and chemical reactivity in surface snow with relevance to polar regions. It focuses on a description of impurities in distinct compartments present in surface snow, such as snow crystals, grain boundaries, crystal surfaces, and liquid parts. It emphasises the microscopic description of the ice surface and its link with the environment. Distinct differences between the disordered air–ice interface, often termed quasi-liquid …
Reduction Of Uranium By Bacterial Products, Adesanya A. Akinleye, Sharon Bone, John Bargar
Reduction Of Uranium By Bacterial Products, Adesanya A. Akinleye, Sharon Bone, John Bargar
STAR Program Research Presentations
The Old Rifle Mill Processing site at Rifle, CO, contains uranium contaminated groundwater. The presence of uranium is one of the major problems at Department of Energy legacy sites. There is an initiative for attenuation of uranium by the Department of Energy. Uranium undergoes oxidation/reduction reactions with the substances at the site. Uranium’s oxidation state determines its solubility and mobility in the aquifer. The oxidation reduction pathways at this site have mineralogical, microbial and geochemical components. Understanding the oxidation/reduction pathways of these components will allow for better predictions of the changes and movement of uranium.
Sulfide [S2- ] and …
A Review Of The Hyporheic Zone, Stream Restoration, And Means To Enhance Denitrification, Leanne Merill, David J. Tonjes
A Review Of The Hyporheic Zone, Stream Restoration, And Means To Enhance Denitrification, Leanne Merill, David J. Tonjes
Technology & Society Faculty Publications
The hyporheic zone is the subsurface area below and adjacent to a stream where groundwater mixes with stream water, through vertical, lateral, and longitudinal flows. The hyporheic zone connects the stream to uplands and other terrestrial environments. It is a zone of distinct faunal communities, high biological diversity and ecological complexity, and is the site of chemical processing and transformations of ground- and stream waters. The hyporheic zone is important to the overall ecosystem ecology of the stream, and it can influence stream water chemistry. Flows, reactions, and biota in the hyporheic zone are heterogeneous and patchy, making it difficult …
Soil And Biosolid Nano- And Macro-Colloid Properties And Contaminant Transport Behavior, Jessique L. Ghezzi
Soil And Biosolid Nano- And Macro-Colloid Properties And Contaminant Transport Behavior, Jessique L. Ghezzi
Theses and Dissertations--Plant and Soil Sciences
Despite indications that they are potential contaminant transport systems and threats to groundwater quality, very little effort has been invested in comparing contaminant transport behavior of natural environmental nanocolloids and their corresponding macrocolloid fractions in the presence of As, Se, Pb, and Cu contaminants. This study involved physico-chemical, mineralogical, stability and contaminant-transport characterizations of nano- (< 100 nm) and macro-colloids (100-2000 nm) fractionated from three Kentucky soils and one biosolid waste. Particle size was investigated with SEM/TEM and dynamic light scattering. Surface reactivity was estimated using CEC and zeta potential. Mineralogical composition was determined by XRD, FTIR, and thermogravimetric analyses. Sorption isotherms assessed affinities for Cu2+, Pb2+, AsO3-, and SeO4-2 contaminants, while settling kinetics experiments of suspensions at 0, 2 and 10 mg/L contaminants determined stability and transportability potential. Undisturbed 18x30 cm KY Ashton Loam soil monoliths were also used for …
How Environmental Conditions Affect Cattle Diets, Kalynne R. Ewerks
How Environmental Conditions Affect Cattle Diets, Kalynne R. Ewerks
Natural Sciences Student Research Presentations
This poster presented at the Natural Sciences Poster Session at Parkland College, outlines a study that shows that protein content in animal feed is decreased by increased temperatures and briefly identifies measures that might be taken to counteract an impact on food supply.
Termodynamika Procesowa I Techniczna Lab., Wojciech M. Budzianowski
Termodynamika Procesowa I Techniczna Lab., Wojciech M. Budzianowski
Wojciech Budzianowski
No abstract provided.
Tematyka Prac Dyplomowych Dla Studentów Wydziału Mechaniczno-Energetycznego Pwr., Wojciech M. Budzianowski
Tematyka Prac Dyplomowych Dla Studentów Wydziału Mechaniczno-Energetycznego Pwr., Wojciech M. Budzianowski
Wojciech Budzianowski
No abstract provided.
Tematyka Prac Dyplomowych Dla Studentów Wydziału Chemicznego Pwr., Wojciech M. Budzianowski
Tematyka Prac Dyplomowych Dla Studentów Wydziału Chemicznego Pwr., Wojciech M. Budzianowski
Wojciech Budzianowski
No abstract provided.
Mechanika Płynów Lab., Wojciech M. Budzianowski
Mechanika Płynów Lab., Wojciech M. Budzianowski
Wojciech Budzianowski
No abstract provided.
02. Animal Science, University Of Central Oklahoma
02. Animal Science, University Of Central Oklahoma
Oklahoma Research Day Abstracts
No abstract provided.
06. Computer Science, University Of Central Oklahoma
06. Computer Science, University Of Central Oklahoma
Oklahoma Research Day Abstracts
No abstract provided.
04. Botany, University Of Central Oklahoma
04. Botany, University Of Central Oklahoma
Oklahoma Research Day Abstracts
No abstract provided.
07. Criminal Justice, University Of Central Oklahoma
07. Criminal Justice, University Of Central Oklahoma
Oklahoma Research Day Abstracts
No abstract provided.
09. Environmental Science, University Of Central Oklahoma
09. Environmental Science, University Of Central Oklahoma
Oklahoma Research Day Abstracts
No abstract provided.
11. Genetics, University Of Central Oklahoma
11. Genetics, University Of Central Oklahoma
Oklahoma Research Day Abstracts
No abstract provided.