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Full-Text Articles in Chemistry
Hybridization From Guest-Host Interactions Reduces The Thermal Conductivity Of Metal-Organic Frameworks, Mallory E. Decoster, Hasan Babaei, Sangeun S. Jung, Zeinab M. Hassan, John T. Gaskins, Ashutosh Giri, Emma M. Tiernan, John A. Tomko, Helmut Baumgart, Pamela M. Norris, Alan J.H. Mcgaughey, Christopher E. Wilmer, Engelbert Redel, Gaurav Giri, Patrick E. Hopkins
Hybridization From Guest-Host Interactions Reduces The Thermal Conductivity Of Metal-Organic Frameworks, Mallory E. Decoster, Hasan Babaei, Sangeun S. Jung, Zeinab M. Hassan, John T. Gaskins, Ashutosh Giri, Emma M. Tiernan, John A. Tomko, Helmut Baumgart, Pamela M. Norris, Alan J.H. Mcgaughey, Christopher E. Wilmer, Engelbert Redel, Gaurav Giri, Patrick E. Hopkins
Electrical & Computer Engineering Faculty Publications
We experimentally and theoretically investigate the thermal conductivity and mechanical properties of polycrystalline HKUST-1 metal–organic frameworks (MOFs) infiltrated with three guest molecules: tetracyanoquinodimethane (TCNQ), 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4-TCNQ), and (cyclohexane-1,4-diylidene)dimalononitrile (H4-TCNQ). This allows for modification of the interaction strength between the guest and host, presenting an opportunity to study the fundamental atomic scale mechanisms of how guest molecules impact the thermal conductivity of large unit cell porous crystals. The thermal conductivities of the guest@MOF systems decrease significantly, by on average a factor of 4, for all infiltrated samples as compared to the uninfiltrated, pristine HKUST-1. This reduction in thermal conductivity goes in …
Predicted Properties Of Microhollow Cathode Discharges In Xenon, J. P. Boeuf, L. C. Pitchford, K. H. Schoenbach
Predicted Properties Of Microhollow Cathode Discharges In Xenon, J. P. Boeuf, L. C. Pitchford, K. H. Schoenbach
Bioelectrics Publications
A fluid model has been developed and used to help clarify the physical mechanisms occurring in microhollow cathode discharges (MHCD). Calculated current-voltage (I-V) characteristics and gas temperatures in xenon at 100 Torr are presented. Consistent with previous experimental results in similar conditions, we find a voltage maximum in the I-V characteristic. We show that this structure reflects a transition between a low-current, abnormal discharge localized inside the cylindrical hollow cathode to a higher-current, normal glow discharge sustained by electron emission from the outer surface of the cathode. This transition, due to the geometry of …
A Diamond Thin Film Flow Sensor, Sacharia Albin, John C. Hagwood, John B. Cooper, David L. Gray, Scott D. Martinson, Michael A. Scott
A Diamond Thin Film Flow Sensor, Sacharia Albin, John C. Hagwood, John B. Cooper, David L. Gray, Scott D. Martinson, Michael A. Scott
Electrical & Computer Engineering Faculty Publications
We present the results of theoretical modeling and experimental testing of a diamond thin film sensor for flow studies. It is shown that the high thermal conductivity of a diamond film can enhance the frequency response of the flow sensor. One-dimensional heat diffusion equation was solved using the finite difference method for determining the frequency response. Two different sensor structures were analyzed: a Ni film on a quartz substrate (Ni/Q) and an intermediate layer of diamond film between the Ni film and quartz substrate (Ni/D/Q). The theoretical model predicts a frequency response for the Ni/D/Q sensor higher than that of …