Open Access. Powered by Scholars. Published by Universities.®

Chemistry Commons

Open Access. Powered by Scholars. Published by Universities.®

Articles 1 - 3 of 3

Full-Text Articles in Chemistry

Local Structure And Dynamic Studies Of Mixed Ch4-Co2 Gas Hydrates Via Computational Simulation And Neutron Scattering, Bernadette Rita Cladek Dec 2020

Local Structure And Dynamic Studies Of Mixed Ch4-Co2 Gas Hydrates Via Computational Simulation And Neutron Scattering, Bernadette Rita Cladek

Doctoral Dissertations

Permeated throughout the ocean floor and arctic permafrost, natural gas hydrates contain an estimated 3000 trillion cubic meters, over three times that of traditional shale deposits, of CH4 that is accessible for extraction. Gas hydrates are a crystal structure in which water molecules form a cage network, the host, through hydrogen bonds while trapping a guest molecule such as CH4 in the cavities. These compounds form naturally where the appropriate low temperature and high pressure conditions occur. A promising and tested method of methane recovery is through exchange with CO2, which energetically takes place of the …


Aggregation And Coagulation Of C60 Fullerene As Affected By Natural Organic Matter And Ionic Strength, Hamid Mashayekhi Nov 2016

Aggregation And Coagulation Of C60 Fullerene As Affected By Natural Organic Matter And Ionic Strength, Hamid Mashayekhi

Doctoral Dissertations

With widespread production and use of C60 fullerene nanoparticles, their release to the environment and natural waters is inevitable. The colloidal nature of C60 fullerene in the aquatic environment significantly influences its behavior in the environment including its transport, bioavailability and toxicity to different organisms. Natural organic matter (NOM) is a ubiquitous and reactive material in aquatic environments with significant structural heterogeneity. Therefore, the effect of NOM molecules on the colloidal behavior of fullerene particles needs to be studied. A major part of NOM consists of humic acids (HA). HAs have pronounced effects on the aggregation of C …


Evidence Of Late Quaternary Fires From Charcoal And Siliceous Aggregates In Lake Sediments In The Eastern U.S.A., Joanne P. Ballard Aug 2015

Evidence Of Late Quaternary Fires From Charcoal And Siliceous Aggregates In Lake Sediments In The Eastern U.S.A., Joanne P. Ballard

Doctoral Dissertations

The late-glacial transition to the Holocene, 15,000–11,600 cal yr BP, is an enigmatic period of dynamic global changes and a major extinction event in North America. Fire is an agent of disturbance that transforms the environment physically and chemically, and affects plant community composition. To improve understanding of the linkages between fire, vegetation, and climate over the late glacial and Holocene in the eastern U.S., I analyzed lake-sediment cores for charcoal and indicators of wood ash, and compared results to existing pollen records. A new microscopic charcoal record from Anderson Pond, Tennessee revealed high fire activity from 23,000–15,000 cal yr …