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Full-Text Articles in Chemistry

Technical Evaluation Of Hardwood Biorefinery Using The "Near-Neutral" Hemicellulose Extraction Process, Haibo Mao Dec 2007

Technical Evaluation Of Hardwood Biorefinery Using The "Near-Neutral" Hemicellulose Extraction Process, Haibo Mao

Electronic Theses and Dissertations

A technical analysis was performed for a new process that produces ethanol and acetic acid from hardwood in addition to bleached hardwood Kraft pulp. The new process, termed the "near neutral" hemicellulose extraction process, involves the extraction of wood hemicellulose using green liquor prior to conventional Kraft pulping. This thesis assumes that the new process is located at an existing kraft pulp mill. Ancillary unit operations in the process include hydrolysis of the extracted carbohydrates using sulfuric acid, filtration of the extract to remove lignin that was extracted with the carbohydrates, liquid-liquid extraction of acetic acid and by-product furfural, liming …


Kinetics And Mechanism Of Oxygen Delignification, Yun Ji May 2007

Kinetics And Mechanism Of Oxygen Delignification, Yun Ji

Electronic Theses and Dissertations

Considerable research has been conducted into the kinetics and selectivity of the oxygen delignification process to overcome limitation in its use. However most studies were performed in a batch reactor whereby the hydroxide and dissolved oxygen concentrations are changing during the reaction time in an effort to simulate tower performance in pulp mills. This makes it difficult to determine the reaction order of the different reactants in the rate expressions. Also the lignin content and cellulose degradation of the pulp are only established at the end of the experiment when the sample is removed from the batch reactor. To overcome …


Modification Of Semi-Metal Oxide And Metal Oxide Powders By Atomic Layer Deposition Of Thin Films, Mark Q. Snyder May 2007

Modification Of Semi-Metal Oxide And Metal Oxide Powders By Atomic Layer Deposition Of Thin Films, Mark Q. Snyder

Electronic Theses and Dissertations

This work describes two methods of modifying, and the subsequent characterizing of, oxide nanopowders. The first method, atomic layer deposition, or ALD, is a series of surface-limited reactions that are repeated to deposit a thin, inorganic film on the surface of the nanopowder. Deposition of a thin film is a useful method to alter the surface properties of a material while retaining its bulk properties. Part of this thesis concerns the understanding of the growth mechanism of thin film titanium nitride (a material known for thermal and chemical stability as well as electronic conductivity) on silica through the ALD process. …