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Full-Text Articles in Chemistry

Extraction Conductometric Determination Of Scandium And Thorium In Kaolins, Nigora Kutlimurotova, Zulayho Smanova, Habibulla Tojimuhamedov, Zuhra Yaxshiyeva, Jasur Tursunqulov Jun 2018

Extraction Conductometric Determination Of Scandium And Thorium In Kaolins, Nigora Kutlimurotova, Zulayho Smanova, Habibulla Tojimuhamedov, Zuhra Yaxshiyeva, Jasur Tursunqulov

Bulletin of National University of Uzbekistan: Mathematics and Natural Sciences

A method for extraction - conductometric determination of scandium and thorium with tributyl phosphate and trioctyl phosphine oxide in kaolin was developed. The equivalent electrical conductivity of the complex of scandium and thorium with 2,7-dinitrozo-1,8-dihydroxynaphthalene-3,6-disulfonic acid was found. A scheme for the separation and determination of kaolin content is proposed. The isotherms of scandium and thorium extraction are constructed. It was shown that at a concentration of nitric acid of 15.6 M they do not interfere with the determination of thorium and scandium.


The Dependence Of Relative Enhancement Of Sers Bands On Temperature, Ling Huang, Jian Shen, Tsing Yu, Qing-Jin Meng May 2001

The Dependence Of Relative Enhancement Of Sers Bands On Temperature, Ling Huang, Jian Shen, Tsing Yu, Qing-Jin Meng

Journal of Electrochemistry

The adsorption and binding behavior of 2,5_dimercapto_1,3,4_thiadizole(DMTD) on silver surface was studied by near_infrared Fourier Transfer surface enhanced Raman scattering(NIR FT-SERS) technique. It was found that the relative intensities of the SERS bands change regularly with the increasing of temperature, which suggests the transformation of the tautomers or the re_orientation of DMTD molecules in the surface layer.