Physical Sciences and Mathematics Commons^™

Spatial Variations In Ancient Meteoric Water: An Investigation Of The Rattlesnake Tuff, Julian Michael Cohen

Dissertations and Theses

Volcanic glass has been used extensively as a paleoclimate proxy. Deuterium (2H) concentrations in glass have been found to be stable over geologic timescales, making δD a reliable proxy for ancient water chemistry. However, continued work revolves around better understanding how different factors affect preserved water in ash. Here, I analyze δD in the Rattlesnake Tuff (RST), a widespread ca. 7 Ma ashflow tuff, and create an isoscape to assess variations in δD across Oregon during that time. Additionally, I examine compositional data from glass shards to explore the relationship between δD and shard composition. The RST exhibits well defined …

The Castle Rock And Ironside Mountain Calderas, Eastern Oregon, Usa: Adjacent Venting Sites Of Two Dinner Creek Tuff Units—The Most Widespread Tuffs Associated With Columbia River Flood Basalt Volcanism, Matthew Cruz, Martin J. Streck

Geology Faculty Publications and Presentations

The Dinner Creek Tuff is an important unit of mid-Miocene rhyolite volcanism contemporaneous to flood basalts of the Columbia River magmatic province. Field mapping along with analytical data of tuff samples identify two calderas, the Castle Rock and Ironside Mountain calderas, as the venting sites of two widespread ignimbrites of the Dinner Creek Tuff. Both calderas lie within the area of the proposed general storage sites of main-phase Columbia River Basalt magmas. The Castle Rock caldera formed during the eruption of the 16.16 Ma Dinner Creek Tuff unit 1. The northwestern boundary of the caldera is roughly defined by the …

Geology, Mineralogy, And Geochemistry Of The Zarloukh Bentonite -Tuff Deposit,Hemrin South Mountain, Northern Iraq: Implications For Genesis And Geotectonics, Yawooz Kettanah

Turkish Journal of Earth Sciences

The Quaternary Zarloukh Bentonite -Tuff (ZBT) deposit occurs within the Hemrin South Mountain, northern Iraq. The ZBT deposit occurs as depression-filling exposed on the erosional surface of the siliciclastic Pliocene Muqdadiya Formation and covered by an overburden of recent sediments. The thickness of the studied industrial bentonite bed is ~80-100 cm, occurring at the bottom of these depressions, covered by ~3-4 m thick bedded volcanic tuff, which also contains many 10-12 cm thick bentonite layers along its bedding planes. The volcanic ash at the bottom of lakes/swamps with shallow water content acted as basins for the deposition of falling volcanic …

Arsenic Mobilization From Silicic Volcanic Rocks In The Southern Willamette Valley, Gabriela Ribeiro De Sena Ferreira

Dissertations and Theses

Volcanic tuffs and tuffaceous sediments are frequently associated with elevated As groundwater concentrations even though their bulk As contents (~ 5 mg kg^-1; Savoie, 2013) are only marginally greater than the average crustal abundance of 4.8 mg g^-1 (Rudnick & Gao, 2003). Thus, As mobilization must be facilitated by conditions particular to these rocks. Alkaline desorption, anionic competition, reactive glass dissolution, and reductive dissolution of iron oxides are proposed processes of As release from volcanic rocks. Geogenic As contamination of groundwater in the southern Willamette Valley in western Oregon has been well-documented since the early 1960s, and …

Volcanic Evolution Of The Southern Quinn Canyon Range: Implications For Regional Correlation Of Volcanic Units, Christina Emery

UNLV Theses, Dissertations, Professional Papers, and Capstones

The southern Quinn Canyon Range lies in an area of the Great Basin subjected to large-volume Oligocene-Miocene silicic volcanism and smaller volume basaltic volcanism during the Pliocene. Three major ash-flow tuff units were correlated in the southern Quinn Canyon Range (the Pahranagat Tuff, Clifford Spring Tuff, and the Cow Canyon Tuff) with regional units by utilizing U/Pb and 40 Ar/ 39Ar geochronology, geochemical correlation, and field mapping. Isotopic analysis suggests that basalt in the southern Quinn Canyon Range is part of the Death Valley-Pancake Range Basalt Zone and is similar to Reveille Range Episode 1 and 2 basalts. Further comparison …

Petrogenesis Of The Linked River Mountains Volcanic Section And Wilson Ridge Pluton, Denise Kelly Honn

UNLV Theses, Dissertations, Professional Papers, and Capstones

The River Mountains (RM) volcanic suite and Wilson Ridge pluton (WRP), in the northern Colorado River extensional corridor of southern Nevada and northwestern Arizona, provide an ideal opportunity to investigate one of the most fundamental questions in igneous petrology: Do volcanic rocks erupt from subjacent plutons and do plutons vent to form volcanic fields? The RM volcanic suite (14.47± 0.26 to 12.66 ± 0.54 Ma; uncertainties are 2sigma) consists of a stack of andesite and rhyolite sills beneath a stratovolcano that primarily erupted dacite with lesser volumes of basalt and rhyolite. This volcanic suite is cored by a multiphase quartz …

Removal Of Arsenic And Strontium From Aqueous Solution Using Ironoxide Coated Zeolitized Tuff, Nataliya V. Kasimtseva

UNLV Theses, Dissertations, Professional Papers, and Capstones

As world population grows so does the demand for safe drinking water. Meanwhile water resources become increasingly scarce and quality of natural water decreases due to a combination of natural and anthropogenic factors. Industry and agriculture have become a premiere source of hazardous constituents, along with natural processes such as rock weathering and volcanic eruptions. Our ability to remove hazardous constituents from water depends on chosen technology and nature of contaminant. Sorption and ion-exchange have been widely applied for water purification. Natural zeolites have been widely applied in water and waste water treatment as ion-exchangers for removal of harmful contaminants …

Influence Of Lithophysal Geometry On The Uniaxial Compression Of Tuff-Like Rock, Douglas B. Rigby, Moses Karakouzian, Amy J. Smiecinski

Publications (YM)

The purpose of this report is to summarize the work and present conclusions of Project Activity Task ORD-FY04-013 conducted under Cooperative Agreement No. DEFC28- 04RW12232 between the U.S. Department of Energy and the Nevada System of Higher Education (NSHE). This document describes results of laboratory testing on analog lithophysal tuff (Hydro-StoneTB®) conducted in the Department of Civil and Environmental Engineering of the University of Nevada at Las Vegas (UNLV) from 2004 to 2006.

Influence Of Lithophysae Geometry On Mechanical Properties Of Hydro-Stone®, Moses Karakouzian, Doug Rigby

Publications (YM)

85 percent of YM drift tunnels will be constructed in lithophysal volcanic tuff.

Rock behavior depends on porosity.

Limited experimental data exists to characterize rock porosity and dependencies on properties such as σc , E, and n.

Petrogenesis Of Pleistocene Basalts In The Norris-Mammoth Corridor, Yellowstone National Park, Kristeen Marie Bennett

UNLV Theses, Dissertations, Professional Papers, and Capstones

The basalts of the Norris-Mammoth corridor within the Yellowstone Plateau volcanic field have an outcrop erupted volume of ~94 km³. Basalt in the Yellowstone Plateau volcanic field is minor in volume compared to 3,700 km³ of felsic lavas, domes, and pyroclastic rocks. The tholeiitic eruptive products formed small Hawaiian-style shield volcanoes. A newly identified volcanic vent, called the Panther Creek vent, within the Swan Lake Flat basalt stratigraphic unit, was primarily Strombolian in its eruption style. This vent is the first recognized cinder cone in Yellowstone National Park.

All basaltic units within the Norris-Mammoth corridor, and the …

Long-Term Mechanical Behavior Of Yucca Mountain Tuff And Its Variability, Jaak J.K. Daemen, Lumin Ma, Guohua Zhao

Publications (YM)

The study of the long term mechanical behavior of Yucca Mountain tuffs is important for several reasons. Long term stability of excavations will affect accessibility (e.g. for inspection purposes), and retrievability. Long term instabilities may induce loading of drip shields and/or emplaced waste, thus affecting drip shield and/or waste package corrosion. Failure of excavations will affect airflow, may affect water flow, and may affect temperature distributions.

The long term mechanical behavior of “hard” rocks remains an elusive topic, loaded with uncertainties. A variety of approaches have been used to improve the understanding of this complex subject, but it is doubtful …

Long-Term Mechanical Behavior Of Yucca Mountain Tuffs, And Its Variability, Jaak J.K. Daemen, George Danko, Jaime Gonzalez, Amy J. Smiecinski, Raymond E. Keeler

Publications (YM)

We propose to continue the investigation of the long term strength of Yucca Mountain tuffs, with particular emphasis on tuffs from and near the emplacement horizon. We propose to also continue and expand the investigation of the spatial variability of rock strength and stiffness. An intrinsic component of this planned rock testing is the testing of rock joints. Although the emphasis is on tests aimed at determining long term strength, as part of the testing measurements of stiffness also are collected, and will be collected, reported, and analyzed.

Influence Of Lithophysae Geometry And Distribution On Mechanical Properties Of Topopah Spring Tuff, Mohammad Shahidul Islam, Justin Fenton, Moses Karakouzian, Jaime Gonzalez, Amy J. Smiecinski, Raymond E. Keeler

Publications (YM)

The current Site Recommendation study for the proposed high level nuclear waste repository at Yucca Mountain locates the repository emplacement drifts approximately 81% within the lower lithophysal unit of the Topopah Springs Formation (Tptpll), 4% within the upper lithophysal unit of the Topopah Springs Formation (Tptpul), and roughly 15% within the middle, non-lithophysal unit (Tptpmn) of the same formation. A major geomechanical issue facing the Yucca Mountain Project is to understand the thermomechanical behavior of lithophysal tuff, which comprises roughly 85% of the repository host rock.

Experimental Investigation Of Time Dependent Behavior Of Welded Topopah Spring Tuff, Lumin Ma

Publications (YM)

Four types of laboratory tests have been performed. Specimens were attained from four lithophysal zones of the welded Topopah Spring Tuff unit at Yucca Mountain, Nevada: upper lithophysal, middle nonlithophysal, lower lithophysal and lower nonlithophysal zones. Two types of tests are conducted to study time-dependent behavior: constant strain rate and creep tests. Sixty five specimens from the middle nonlithophysal zone were tested at six strain rates: 10 , 10 , 10 , 10 , 10 , and 10 . Test durations range from 2 seconds to 7 days. Fourteen specimens from middle nonlithophysal, lower lithophysal and lower nonlithophysal zones are …

Point Load Strength Testing Of Irregular Rock Fragments Of Welded Tuff, Jaak J.K. Daemen, George Danko, Amy J. Smiecinski

Publications (YM)

Yucca Mountain is composed of a thick sequence of variably welded and nonwelded ashflow tuffs (Rautman and Engstrom, 1996). The understanding of the rock mechanical properties is useful for characterizing the mechanical stability of the potential repository and for estimating the amount of ground support needed in underground construction (Sweetkind et al, 2003). According to Brook (1993), knowledge of lump point load strength is helpful because it can help in estimating the compressive strength. Lump point load testing is one basic mechanical characterization test to support the study of long term drift stability at the potential High Level Waste repository …

Experimental Determination Of Stiffness Of Joints In Welded Tuff, Jaak J.K. Daemen, George Danko, Amy J. Smiecinski

Publications (YM)

Fourteen uniaxial joint compression tests were run to determine the normal and shear stiffnesses of type 1 fracture joints (healed joints filled with vapor-phase mineral deposits) obtained from the Yucca Mountain site. The uniaxial joint compression results show that these joints behave linearly up to over 85% of their loading history. They are stiff with strengths very close to the strength of the intact rock. Five direct shear tests were run on open, separated, joints. Results obtained from the direct shear testing show that the normal stiffness increases with increasing normal stress. Shearing through asperities gives high joint shear stiffness …

The Influence Of Lithophysal Porosity On The In-Situ Stress-Strain Properties Of Topopah Spring Tuff, Bahri B. Avar, Moses Karakouzian, Amy J. Smiecinski

Publications (YM)

Numerical analysis and a laboratory testing program were conducted in order to investigate the effect of lithophysal porosity on the elastic stress-strain properties of the lithophysae-rich tuff specimens and to find the locations of cavities in both analog and tuff specimens. In the first part of the study, a finite difference mesh containing circular holes was modeled for varying porosity ranges between 5 and 40% using commercially available software FLAG20' version 3.5. Elastic (Young's) modulus and Poisson's ratio were calculated for each setup and normalized with respect to matrix elastic modulus and Poisson's ratio. The moduli calculated through numerical analysis …

Influence Of Lithophysal Porosity On Stress-Strain Properties Of Topopah Spring Tuff - Numerical Analysis, Nick Hudyma, Moses Karakouzian, Amy J. Smiecinski

Publications (YM)

The purpose of the numerical analysis effort of Task 27 of cooperative agreement DE-FC08-98NV12081 was to investigate the effect of lithophysal porosity on the elastic stress-strain properties of the tuff rock mass. Rock mass properties without lithophysal cavities are designated matrix properties. Rock mass properties with lithophysal cavities are designated effective properties. The analysis will be performed for a 6" by 6" square cross-section with a uniform distribution of lithophysal cavities for a variety of porosities. The analyses will be performed using FLAG 2D version 3.5, a Department of Energy qualified software. The analyses will compare the matrix properties to …

Characteristics Of The Weathering Zones Developed Within The Tuffs Of The Midas Monument, Tamer Topal, Burak Sözmen

Turkish Journal of Earth Sciences

The Midas monument, an impressive cult facade located in the southern part of the Eskişehir province in central Anatolia, Turkey, was made within tuffs (white and pink), which now have deterioration problems. In this study, the depth and characteristics of the weathering zones that have developed in the white and pink tuffs have been investigated through thin-section studies, X-ray powder diffractometry, methylene blue adsorption tests, major-element analyses, and some index parameters. It has been determined that the feldspar minerals are mechanically fractured due to weathering. The tuffs contain small amounts of clay minerals. An approximately 1-cm-thick silica-rich zone has developed …

The Geochronology And Geochemistry Of The Bearhead Rhyolite, Jemez Volcanic Field, New Mexico, Leigh Justet

UNLV Theses, Dissertations, Professional Papers, and Capstones

Around 82% of mapped Bearhead Rhyolite (Main Cluster) and Peralta Tuff appears to have been derived from a relatively long-lived (~680 ka), large, shallow (Earth's surface) magma chamber that did not produce a caldera-forming eruption. Although volatile contents were great enough (~ wt.% H₂O), no large-scale explosive eruptions occurred because magma may have been tectonically vented. The lack of systematic chemical variation within the Main Cluster with time during this ~680 ka interval may imply that erupted magmas were physically separated from each other by fault-formed cupolas in the roof of the magma chamber. These results are significant …

Geology And Geochemistry Of Tertiary Volcanic Rocks In The Northern Reveille And Southern Pancake Ranges, Nye County, Nevada, Kelly Brian Rash

UNLV Theses, Dissertations, Professional Papers, and Capstones

The northern Reveille and southern Pancake Ranges, located in the south-central Great Basin, experienced a prolonged history of Tertiary volcanism. Volcanic activity in this area began with the eruption of large-volumes of ash-flow tuffs from calderas of the central Nevada caldera complex. The Reveille Range and the southernmost portion of the Pancake Range are the site of two calderas that are the sources for the tuff of Goblin Knobs and tuff of northern Reveille Range. The tuff of Goblin Knobs (70.4-75.3 wt.% SiO₂) erupted from the caldera of Goblin Knobs (25.6 Ma) and is the thickest (~1700 m) …

The Geology Of The Tuff Of Bridge Spring: Southern Nevada And Northwestern Arizona, Shirley Ann Morikawa

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Tuff of Bridge Spring (TBS) is a regionally-widespread, andesite to rhyolite (59.50 to 74.91 wt. %) ash-flow tuff of mid-Miocene age (ca. 15.2 Ma) that is exposed in the northern Colorado River extensional corridor of southern Nevada and northwestern Arizona. Determination of the areal distribution, geochronology, lithology, geochemistry, and internal stratigraphy of the TBS is important for its establishment as a reliable stratigraphic reference horizon for tectonic reconstructions of the extensional corridor during the middle Miocene. Based on reoccurring patterns of major and trace element variation, the TBS is divided into constant Cr/variable SiO₂ and variable Cr/variable SiO …

The Sloan Sag: A Mid-Miocene Volcanotectonic Depression, North-Central Mccullough Mountains, Southern Nevada, Hayden L. Bridwell

UNLV Theses, Dissertations, Professional Papers, and Capstones

In the Hidden Valley area of the north-central McCullough Mountains, southern Nevada, mid-Miocene andesite and dacite domes, flows and pyroclastic units (the Sloan volcanics) partially fill a sag in the underlying Hidden Valley volcanics. The 13.5 km diameter sag formed during and/or after the eruption of the Sloan volcanics. Sagging was accommodated by a combination of movement on the McCullough Wash fault system, and subsidence into evacuated chambers.

Major, trace and rare-earth element geochemistry suggests that the rocks of the Sloan volcanics belong to four groups, each of which were produced by partial melting of chemically distinct sources. With the …

Eruption Dynamics And Petrology Of The Most Recent Eruptions Of Nevado Del Ruiz Volcano, Colombia, South America, Richard Henry Young

LSU Historical Dissertations and Theses

Field measurements and petrographic analyses of pumices from the most recent tephra deposits of Nevado del Ruiz volcano provide a context in which to view the disastrous eruption of 13 November, 1985 (R0). The pumices are all crystal-rich, two-pyroxene andesites to dacites with whole rock SiO₂ contents of 62 - 66 wt.%, and magma water contents estimated to be between 1 - 4 wt.%. The 1985 tephra has greater petrologic diversity than earlier deposits which may be related to an input of a hotter, more basic magma into the Ruiz system, as suggested by xenocrystic olivine which is most …

Geology, Volcanology, And Petrology Of Cerro Bravo, A Young, Dactic, Stratovolcano In West-Central Colombia, David Tondl Lescinsky

LSU Historical Dissertations and Theses

The northernmost active Andean volcano, Cerro Bravo is a small, young, and very explosive stratovolcano. Cerro Bravo has produced voluminous tephra deposits, that are found> 30 km away, as well as, pumice flow deposits, block and ash flow deposits, and high-aspect lava flows, which are found proximally to the volcano. There have been eight episodes of activity during the past 6250±110 years (Herd, 1982), with the most recent <200 years ago and the present being a period of quiescence with no visible activity or thermal manifestations. Stratigraphic relationships suggest the occurrence of an initial explosive phase and a concluding effusive phase of activity during individual episodes. The products of volcanic activity at Cerro Bravo are a chemically and mineralogically monotonous suite of medium-K dacite and high-silica andesite (59.2- 67.5% SiO₂ pumices and lavas. The dominant phenocrysts present are plagioclase and hornblende (oxyhomblende in lavas) with lesser quantities of orthopyroxene, titanomagnetite, and rare augite and biotite also present. Petrology and eruption dynamics …

The Precambrian Volcanic Stratigraphy And Petrology Of The Des Arc Ne 7 1/2 Minute Quadrangle, South Central St. Francois Mountains, Missouri, Vernon Max Brown

Doctoral Dissertations

"The Precambrian volcanics in the Des Arc NE 7½ minute quadrangle are composed predominantly of rhyolitic ash-flow tuffs with minor rhyolitic, trachytic, and andesitic lavas, and basaltic dikes. Thirty-seven volcanic units were identified, mapped, and informally named. A minimum of 1,000 meters of volcanic section is present. The rhyolites consist of phenocrysts of albitized alkali feldspar, albitic plagioclase, quartz, opaques, and ferromagnesium relicts set in a devitrified and locally recrystallized felsitic matrix. Pumice and lithophysal structures are common in the ash flows.

Chemically, the rhyolites are quite similar. The potassium to sodium ratio in individual units, however, tends to vary …