Physical Sciences and Mathematics Commons^™

Spectroscopic End Point Detection With An Electron Beam Evaporator, Ryan Mcgraw

University Honors Theses

Spectroscopic end point detection is a common tool used for measuring slope changes in wavelength intensity. Using algorithms able to apply this concept, coatings will be able to be dynamically measured in real time and stopped at the appropriate level to ensure process uniformity. It is currently applied to reductive processes such as etching, where the surface will start to be eaten away, creating a plasma. When the entire amount of a material on a substrate has been eaten away, the plasma will change color as it is beginning to etch a different material. Using a spectrometer, this point where …

Impact Of Fertilizer Type, Seed Coating, And Duration Of Exposure On The Germination Of Orchardgrass Seed, Edwin L. Ritchey, Christopher D. Teutsch

IGC Proceedings (1997-2023)

Cool-season grasses such as orchardgrass, are important components of forage systems in transition zone states like Kentucky. To maintain dense and vigorous sods, improved cool-season grass varieties are sometimes overseeded into existing stands in late-winter or early-spring. In many cases seed is mixed with fertilizer and top-dressed onto pastures. Little data are available on the impact of fertilizer type or duration of exposure on the germination of raw and coated grass seed. The objective of this study was to evaluate the impact of two fertilizer types, muriate of potash and a blended fertilizer (urea, diammonium phosphate, and muriate of potash), …

Impact Of Fertilizer Type, Seeding Coating, And Duration Of Exposure On The Germination Of Red Clover Seed, C. D. Teutsch, Edwin L. Ritchey

IGC Proceedings (1997-2023)

Legumes are important components in grassland ecosystems. Red clover is one the most used legumes in the transition zones states like Kentucky. To maintain legumes in grass pastures, improved red clover varieties are often overseeded in the late-winter or early-spring. In many cases seed is mixed with fertilizer and top-dressed onto pastures. Little data are available on the impact of fertilizer type or duration of exposure on the germination of raw and coated red clover seed. The objective of this study was to evaluate the impact of two fertilizer types, muriate of potash and a blended fertilizer (urea, diammonium phosphate, …

Alkyd Resins Produced From Bio-Based Resources For More Sustainable And Environmentally Friendly Coating Applications, Cemi̇l Dizman, Eli̇f Cerrahoğlu Kaçakgi̇l

Turkish Journal of Chemistry

Recently, due to the depletion of natural resources and raising environmental and economic concerns regarding petroleum derivatives, the creation of novel ecologically friendly and sustainable materials made from bio-based and renewable resources is gaining popularity. Alkyd resins are synthetic resins in which both renewable (fatty acids, glycerol, oil, etc.) and nonrenewable (maleic anhydride, pentaerythritol, phthalic anhydride, etc.) raw materials are used in their production. Due to their superior performance (good aging, greater weather resistance and high heat resistance, outstanding gloss, etc.) over other resins, easy application, low cost, and varied use, in the coating and paint industries, they are commonly …

Functional Bottlebrush Polymer Additives For Thin Films And Coatings, Travis S. Laws

Doctoral Dissertations

Bottlebrush polymers are a class of highly branched polymers consisting of polymeric side chains that are densely grafted to a linear backbone. Their highly branched architecture results in surface enrichment across a broad range of materials. The goal of my research has been centered around the design of functional bottlebrush polymers and their use as surface active additives in blend films and coatings.

In the first chapter, we examine the segregation behavior of polystyrene bottlebrushes that are blended with linear polystyrene. We systematically vary the lengths of the bottlebrush backbone (Nb), side-chain (Nsc), and the linear matrix (Nm) in order …

An Approach For Material Model Identification Of A Composite Coating Using Micro-Indentation And Multi-Scale Simulations, Pouya Shojaei, Riccardo Scazzosi, Mohamed Trabia, Brendan O’Toole, Marco Giglio, Xing Zhang, Yiliang Liao, Andrea Manes

Mechanical Engineering Faculty Research

While deposited thin film coatings can help enhance surface characteristics such as hardness and friction, their effective incorporation in product design is restricted by the limited understand-ing of their mechanical behavior. To address this, an approach combining micro-indentation and meso/micro-scale simulations was proposed. In this approach, micro-indentation testing was conducted on both the coating and the substrate. A meso-scale uniaxial compression finite element model was developed to obtain a material model of the coating. This material model was incorporated within an axisymmetric micro-scale model of the coating to simulate the indentation. The proposed approach was applied to a Ti/SiC metal …

Electrically Conductive, Hydrophobic, Uv Protective And Lightweight Cotton Spunlace Nonwoven Fabric Coated With Reduced Graphene Oxide, Beki̇r Cenkkut Gülteki̇n

Turkish Journal of Chemistry

In this study, cotton spunlace nonwoven fabrics with four different basis weights were coated with graphene oxide (GO) by conventional dip coating method which is one of the most simple and effortless process in textile industry. The graphene oxide coated cotton nonwoven fabrics were immersed in an aqueous sodium dithionite solution in order to obtain reduced graphene oxide (RGO) coated cotton spunlace nonwoven fabrics. The obtained nonwoven fabrics became electrically conductive with very low surface electrical resistivity of 5.98 × 102 W/sq for the 70 g/m2 basis weight nonwoven fabric. The color measurements and reflectance spectrophotometry were performed in order …

The Influence Of Pulse-Plasma Treatment On The Phase Composition And Hardness Of Fe-Tib2-Crb2 Coatings, A. B. Kengesbekov, B. K. Rakhadilov, Yu. N. Tyurin, N. M. Magazov, M. K. Kylyshkanov, Zh. B. Sagdoldina

Eurasian Journal of Physics and Functional Materials

This work are presented the research results of pulse plasma treatment influence on the phase composition, hardness, roughness and element composition of coatings on the bases of Fe-TiB2-CrB2. The Fe-TiB2-CrB2 coatingwas depositedby detonation method. The following pulse-plasmatreatment was used to modify the structure and properties of the surface layers of the sprayed coating. The results of mechanical experiments showed that the hardness of Fe-TiB2-CrB2 coating increased after the treatment. On the basis of the X-ray analysis, it has been established that the increase of coating hardness is connected with phase transformations in a surface layer, in particular, with formation of …

Effect Of The Detonation Spraying Mode On The Tribological Properties Of Nicr-Al2o3 Coatings, B. K. Rakhadilov, D. B. Buitkenov, E. Kabdykenova, Zh. B. Sagdoldina, L. G. Zhurerova

Eurasian Journal of Physics and Functional Materials

The article presents the study results of detonation spraying parameters on the phase composition and tribological properties of NiCr-Al 2 O 3 powder coatings. The spraying was carried out at a ratio of the acetylene oxygen mixture O 2 /C 2 H2 =1.856. The detonation barrel filling volume with an explosive gas mixture varied from 30% to 68%. It is determined that the phase composition of the NiCr-Al 2 O 3 coatings varies depending on the degree of detonation barrel filling. With an increase in the detonation barrels filling volume, the intensity of the NiCr diffraction peaks is decreased, and …

Influence Of Pulsed Plasma Treatment On Phase Composition And Hardness Of Cr3c2-Nicr Coatings, D. N. Kakimzhanov, B. K. Rakhadilov, Yu. N. Tyurin, O. V. Kolisnichenko, L. G. Zhurerova, M. K. Dautbekov

Eurasian Journal of Physics and Functional Materials

In this study, the research results of the influence of pulsed plasma treatment on phase composition, hardness, and roughness of Cr 3 C 2 -NiCr coatings are presented. The Cr 3 C2 -NiCr coating was applied to substrate 12Kh18N10T stainless steel by detonation spraying method. To change the physical and mechanical properties of sprayed coating's surface layers, subsequent pulse plasma treatment was used. The pulse plasma treatment leads to changing the roughness of Cr 3 C2 -NiCr coating. The results of mechanical tests showed that after pulsed plasma treatment, the hardness of Cr 3 C 2 -NiCr coating is increased. …

Martian Spectroscopy: Laboratory Calibration Of The Perseverance Rover’S Mastcam-Z And Photometric Investigation Of Mars-Analog Ferric-Coated Sand, Kristiana Lapo

WWU Graduate School Collection

The Mars 2020 rover Perseverance will search for signs of past habitability and biosignatures after landing in Jezero Crater in February 2021. Spectroscopy is a vital tool for planetary remote sensing and Perseverance is equipped with Mastcam-Z, a stereoscopic, zoom-enabled, multispectral imager that can acquire true color images with red, green, and blue (RGB) color filters, and visible- to near-infrared images with 12 narrowband science filters between 400 and 1100 nm. Mastcam-Z will provide operational support for the rover as well as directly contribute to Perseverance’s geologic investigations. Given the integral role of Mastcam-Z in the Mars 2020 mission, calibration …

Changes In The Structure And Properties Of Zro2 Detonation Coatings During Annealing, B. K. Rakhadilov, D. N. Kakimzhanov, G. Botabaeva, D. B. Buitkenov, N. Kantai, L. B. Bayatanova

Eurasian Journal of Physics and Functional Materials

The article studied the effect of annealing on the structure and properties of zirconium dioxide coatings obtained by detonation spraying. Detonation spraying was realized on a computerized detonation spray ing complex of the new generation CCDS2000. Determined that coatings made of zirconium dioxide are characterized by high adhesive strength of adherence to the substrate. Thermal annealing of coated samples was performed at temperatures of 900-1200^◦C. It was determined that the microhardness of zir conium dioxide coatings increases by 10-25% depending on the annealing temperature after annealing. The results of nanoindentation showed that the nanohardness of the coatings after …

Effect Of Sodium Based Transparent Binders On The Optical Properties Of Gase Thin Films, Ahmad Omar

Journal of the Arab American University مجلة الجامعة العربية الامريكية للبحوث

The effect of sodium based transparent binders on the optical properties of vacuum evaporated GaSe thin films are explored by means of optical reflectivity and transmittance of the binder, GaSe and GaSe/binder interfaces in the incident light wavelength range of 300-1100 nm. The analysis of the absorption coefficient spectra for the three samples revealed a pronounced red shift in the direct allowed electron transition's energy band gap of the GaSe. In addition, the band tail states of GaSe, which was observed at ~ 0.25 eV, disappeared upon binder coating. The binder coated GaSe films screen the energy band gap of …

Obtained Of Powder Coatings By Detonation Spraying, D. B. Buitkenov, B. K. Rakhadilov, Zh. B. Sagdoldina, M. Maulet

Eurasian Journal of Physics and Functional Materials

In this work, consider the aspects of obtaining powder coatings that possessing certain working properties obtained by detonation spraying. Experimental research were carried on the effect of technological parameters of the detonation spraying process on the phase composition and properties of Ti-Si-C coatings. It is determined that when the volume of filling the detonation barrel with an explosive mixture increases to 70% in the detonation wave flow, the Ti₃SiC₂ powder partially decomposes into TiC consequently the high-speed shock interaction of heated to high temperatures. Installed that when filling the barrel with an explosive mixture of 50% and …

The Effect Of Detonation Spraying On The Phase Composition And Hardness Of Al2o3 Coatings, B. K. Rakhadilov, D. B. Buytkenov, D. Kakimzhanov, R. S. Kozhanova, G. S. Bektasova

Eurasian Journal of Physics and Functional Materials

The article were studied the e ect of detonation spraying on the structure and properties of Al 2 O 3 coatings. It was determined that reducing the delay time between shots is leading to increase the hardness and elastic module of Al 2 O 3 coatings. It was found on the basis of X-ray di raction analysis that the main reason for the increasing in hardness with a decreasing in the delay time between shots is associated with increasing in the volume fraction of α -Al 2 O 3 phase. The studies of X-ray di raction presented that the highest …

Effect Of Polymer Design And Coating Formulation On The Water Uptake And Sensitivity Of Acrylic Water-Borne Films, William Z. Thompson

Master's Theses

Water-borne latex coatings represent a safer, more user-friendly, and environmentally responsible alternative to solvent-borne coatings, and are growing in popularity each year. However, these coatings often exhibit unfavorable performance when exposed to water for extended periods of time. This prolonged exposure often results in water uptake, which may give rise to other detrimental effects such as a decrease in modulus, blushing or water-whitening, reduced serviceable life, and softening of the film. In this study, various polymer composition latex design spaces are studied to develop an understanding of how water uptake can be modulated and minimized using common synthetic approaches. Factors …

Enhanced Electrochemical Performance Of Li-Ion Battery Cathodes By Atomic Layer Deposition, Yan Gao

Doctoral Dissertations

”Li-ion battery now plays an irreplaceable role in supplying green and convenient energy. In this work, atomic layer deposition (ALD) was used to modify Li-ion battery cathode particles for performance enhancement.

An ultrathin and conductive CeO₂ ALD film was deposited on Li-rich layered cathode particles, of which the specific capacity and cyclic stability were significantly improved. On the same cathode particles, FeO_x ALD and post-annealing resulted in a stable and conductive surface spinel phase to improve the performance.

Synergetic TiN coating and Ti doping were performed on a LiFePO₄ (LFP) cathode and extended its cycle life. The …

Antibacterial Properties Of Mussel-Inspired Polydopamine Coatings Prepared By A Simple Two-Step Shaking-Assisted Method, Pegah Kord Fooroshani, Elizabeth Polega, Kevin Thomson, Mohammad Saleh Akram Bhuiyan, Rattapol Pinnaratip, Mikhail Trought, Chito E. Kendrick, Yuesheng Gao, Kahryn Perrine, Lei Pan, Bruce P. Lee

Michigan Tech Publications

A simple two-step, shaking-assisted polydopamine (PDA) coating technique was used to impart polypropylene (PP) mesh with antimicrobial properties. In this modified method, a relatively large concentration of dopamine (20 mg ml⁻¹) was first used to create a stable PDA primer layer, while the second step utilized a significantly lower concentration of dopamine (2 mg ml⁻¹) to promote the formation and deposition of large aggregates of PDA nanoparticles. Gentle shaking (70 rpm) was employed to increase the deposition of PDA nanoparticle aggregates and the formation of a thicker PDA coating with nano-scaled surface roughness (RMS = 110 …

Retrofit Of The Existing Buildings Using A Novel Developed Aerogel-Based Coating: Results From An In-Field Monitoring, Stefano Fantucci, Elisa Fenoglio, Giulia Grosso, Valentina Serra, Marco Perino, Marco Dutto, Valentina Marino

International Building Physics Conference 2018

The energy retrofit of existing buildings and more in general building rehabilitation represents an important challenge in EU countries since a large part of their building stock is old, poorly insulated and affected by pathologies, i.e. mould growth, with relevant implications on users health other than aesthetical drawbacks. Unfortunately, the energy retrofit of existing buildings and particularly when dealing with historic buildings presents several issues, i.e. the compatibility between the identified solutions and the heritage value or the reduction of the internal space if internal solutions have to be adopted. An emerging solution to address the target of the energy …

Plant Stimuli-Responsive Biodegradable Polymers For The Use In Timed Release Fertilizer Coatings, Spencer Heuchan

Electronic Thesis and Dissertation Repository

The use of nitrogen-based fertilizers continues to accelerate with human population growth and increases in global food requirements. Enhanced efficiency fertilizers (EEFs) have been developed to improve the synchronization between nutrient supply and crop nutrient demand. However, many of the current controlled release fertilizers are coated with non-degradable polymers that contribute to accumulation of microplastics within ecosystems. This thesis describes research towards the development of a new class of fertilizer coatings using a self-immolative polymer known as poly (ethyl glyoxylate) (PEtG). PEtG itself does not have suitable properties to produce a viable coating but once blended with another degradable polyester …

Optimization Of Superhydrophobic Surface Production Using Ambient-Dried Silica-Based Aerogels, Elizabeth Donlon

Honors Theses

Superhydrophobic surfaces exhibit particular properties that make them functional in various anti-sticking, anti-contamination, self-cleaning and drag reduction applications. Though such surfaces are found in nature - most notably the lotus leaf - they are difficult to produce. There are numerous methods and techniques for fabricating superhydrophobic surfaces. One such method is the sol-gel method, in which aerogel, a highly porous and lightweight material that can be made hydrophobic or superhydrophobic, is coated onto a surface. The purpose of this project is to devise a simple and repeatable procedure for making hydrophobic silica aerogel coatings that can be used for drag …

Electrochemical Performance Of Moo2-C Composite Coatings, Quan-Yi Li, Qi Yang, Yan-Hong Zhao

Journal of Electrochemistry

The molybdenum dioxide-carbon(MoO₂-C)composite coatings on the surface of Cu foils were prepared by simple knife coating route and followed by sintering in vacuum. The morphology, composition, structure and electrochemical performance of the MoO₂-C composite coatings were investigated. The results demonstrated that the MoO₂-C composite coatings consist of MoO₂ nano-particles with monoclinic crystal structure and amorphous carbon. Some MoO₂ nano-particles with a size range of 5-30nm were loaded on the surface of carbon matrices; while some MoO₂ nano-particles with a size of ~5nm were encapsulated inside. The composite coatings showed porous structure …

Investigating Scalable Manufacturing Of High-Conductivity Wires And Coatings From Ultra-Long Carbon Nanotubes, Pouria Khanbolouki

Mechanical Engineering ETDs

Carbon nanotubes (CNTs) are a promising candidate for next generation of electrical wirings and electromagnetic interference (EMI) shielding materials due to their exceptional mechanical and electrical properties. Wires and coatings from ultralong nanotubes that are highly crystalline, well-aligned and densely packed can achieve this goal. High-performance CNT conductors will be relatively lightweight and resistant to harsh conditions and therefore can potentially replace current conductors in many industries including aerospace, automotive, gas and oil.

This thesis investigates a new manufacturing approach, based on conventional solution coating and wire drawing methods, to fabricate high conductivity wires and coatings from ultra-long carbon nanotubes. …

Usage Of Fomblin Y To Improve Water Repellence Of Surface Coatings, Shawn Pj Kirby, Jeffrey Alston, Andrew Guenthner

STAR Program Research Presentations

Fluoro-Decyl POSS (FDP) has shown strong potential as a water repellant surface coating. Additionally, Fomblin is a solvent believed to have the ability to control the crystallization of POSS compounds on surfaces. Controlling the crystallization is key to improving water repelling abilities of surfaces. Thus, dip coating FDP and Fomblin onto surfaces is being investigated for water repulsion, mechanical stability, and deposition feasibility. First, temperature dependence of solubility of Fluoro-Decyl POSS in Fomblin was tested using Dynamic Light Scattering. Relative water repelling abilities of different coatings were determined by measuring contact angle of surfaces with water. Coatings with and without …

Cathodoluminescence Studies Of Defects In Coated Boron Nitride, Kévin Guerch, Justin Dekany, Jr Dennison, Thierry Paulmier, Sophie Guillemet-Fritsch, Pascal Lenormand

Journal Articles

Optical emission properties of Boron Nitride (BN) substrates, BN with alumina (Al2O3) coating, and thermally-annealed alumina-coated boron nitride (an-BN/Al2O3) were investigated under electron irradiation using cathodoluminescence (CL) measurements. Tests were performed temperatures ranging from ~100 K to ~300 K, with monoenergetic beams from 5 keV to 30 keV, and electron flux densities from 1 nA.cm-2 to 500 nA.cm-2. These experiments were conducted to identify the effects of coating and thermal annealing on the nature and occupation of defect states in different samples with BN substrates. Previous studies have shown that these treatments can limit the charging of BN substrates. Consequently, …

Enhancement Of Dielectric Properties With The Addition Of Bromine And Dopamine Modified Barium Titanate Particles To Silicone Rubber, Liang Jiang, David Kennedy, Stephen Jerrams, Tony Betts

Articles

Dual-coated barium titanate (BT) particles were prepared using dopamine (DP) in conjunction with bromine (Br) in order to enhance the dielectric constant of silicone rubber (SR) composites containing evenly distributed BT particles. The results showed that both DP and Br were deposited on the BT particles. The dielectric constant of the SR/BT composite was significantly increased from 3.6 to 4.7 at 1 kHz with the addition of BT modified with dopamine (DP–BT). Moreover, the dielectric constant further rose to 4.9 at 1 kHz when the DP–BT particle was grafted with bromine (Br–DP–BT).

Photocontrolled Degradation Of Stimuli-Responsive Poly(Ethyl Glyoxylate): Differentiating Features And Traceless Ambient Depolymerization, Bo Fan, John Trant, Rebecca Yardley, Andrew Pickering, Francois Lagugne-Labarthet, Elizabeth Gillies

Chemistry Publications

The depolymerization of coatings prepared from a 6-nitroveratryl carbonate end-capped poly(ethyl glyoxylate) (PEtG) self-immolative polymer was studied. This polymer undergoes end-to-end depolymerization following cleavage of the end-cap by UV light. Several important fundamental diff erences between this class of polymers and conventional degradable polymers were revealed. For example, polymer backbone cleavage and depolymerization exhibited different dependencies on pH, emphasizing the decoupling of these processes. Probing of the coating erosion mechanism illustrated an interesting combination of features from surface erosion and bulk degradation mechanisms that arise from the end-to-end depolymerization mechanism and further differentiate these polymers from convention degradable polymers. It …

Heating Power Of Coated Fecov Magnetic Nanoparticles, Hanaa Ali Alshammari

Browse all Theses and Dissertations

The effect of coatings on the heating curves of magnetic nanoparticles was studied in this Thesis. Iron cobalt vanadium (FeCoV) nanoparticles with oxide (CoOFe2O3) and graphite (C) coating to prevent oxidation, were synthesized through thermal plasma processing method. The magnetic nanoparticles had an average diameter of 30 nm. In the case of FeCoV with oxide coating, the initial diameter of the pure FeCoV nanoparticles on average was 30 nm but after oxidation 5 nm thick oxide layer was created. As a result of this oxidation, the magnetic core of FeCoV nanoparticles was shrunk from 30 nm to 20 nm in …

Electrical Properties Of Annealed And Coated Boron Nitride Under Electron Beam Irradiation, Kevin Guerch, Theirry Paulmier, Jr Dennison, Justin Dekany, Pascal Lenormand, Sophie Guillemet-Fritsch

Journal Articles

The charging and relaxation kinetics of pyrolytic boron nitride (BN) substrates, BN with an aluminium oxide (BN/Al₂O₃) coating, and thermally-annealed alumina-coated boron nitride (an-BN/Al₂O₃) were investigated under low power electron irradiation (5 < E₀ < 20 keV, J_i = 10 nA.cm^-2 at room temperature) in the CEDRE facility at ONERA (Toulouse, France). Surface potentials of each ceramics configuration were measured over time using the Kelvin probe method. The influence of coating and annealing treatments to limit charging is discussed in this paper. A thorough study of a an–BN/Al₂O₃ sample was carried out …

Application Of Colloidal Unimolecular Polymer (Cup) Particles In Coatings, Sagar Vijay Gade

Doctoral Dissertations

"Colloidal unimolecular polymer (CUP) particles were prepared by the process of water reduction on copolymers containing hydrophobic and hydrophilic monomers at definite ratio using free radical polymerization. The CUPs are formed by the effect of hydrophilic /hydrophobic interactions of the polymer with a change in the solvent environment around them. Once formed these colloidal particles are thermodynamically stable with collapsed hydrophobic groups forming a spheroidal core and hydrophilic charges on the surface stabilizing the particle by the charge repulsion. CUPs contain only the charged CUP particles, water and counterions with all the functionality on the surface for further chemistry. CUP …