Physical Sciences and Mathematics Commons^™

Thermochronology And Exhumation Dynamics Of Metamorphic Units In The Salmon River Suture Zone, Jonathan J. Cone

MSU Graduate Theses

The Salmon River suture zone in western Idaho records the Jurassic-Cretaceous (160-90 Ma) accretion of amalgamated volcanic arc terranes onto the North American continent. Rocks exposed at the surface record burial to depths of more than 20 kilometers, with unclear drivers for uplift and exhumation. Two competing hypotheses have been proposed to explain the transport of deep crustal rocks to the surface: (1) delamination of a dense lithospheric root resulted in rapid isostatic uplift of the crust and (2) exhumation of crustal blocks along thrust faults. To test these models, I present temperature-time (T-t) paths for mid-crustal metamorphic rocks constructed …

Geochemistry Of Zircon And Apatite In Rhyolites From The Central Snake River Plain: Genetic Implications, Chesley Philip Gale

Theses and Dissertations

Whole-rock and mineral compositions of three eruptive deposits from the Twin Falls caldera, associated with the Yellowstone hotspot, provide a window into melt generation and evolution for hot, dry, A-type rhyolites. Three rhyolitic units were sampled via the Kimberly drill-core as a part of project HOTSPOT, a study focused on mantle plume and continental lithosphere interaction. Previous work has been done to collect high resolution U-Pb zircon ages, and Hf- and O-isotopic compositions. This study examined the geochemistry of apatite and zircon along with host rock compositions in the context of this previous work. The Kimberly core sampled the Shoshone …

Apatite Reference Materials For Sims Microanalysis Of Isotopes And Trace Elements, James L. Crowley, Mark Schmitz

Geosciences Faculty Publications and Presentations

Twelve apatite samples have been tested as secondary ion mass spectrometry (SIMS) reference materials. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) analysis shows that the SLAP, NUAN and GR40 apatite gems are internally homogeneous, with most trace element mass fractions having 2 standard deviations (2s) ≤ 2.0%. BR2, BR5, OL2, AFG2 and AFB1, which have U > 63 μg g^-1, ²⁰⁶Pb/²⁰⁴Pb > 283, and homogeneous SIMS U-Pb data, have respective isotope dilution thermal ionisation mass spectrometry (ID-TIMS) ages of 2053.83 ± 0.21 Ma, 2040.34 ± 0.09 Ma, 868.87 ± 0.25 Ma, 478.71 ± 0.22 Ma and …

In-Situ Weathering Of Calcium Bearing Minerals In Forested Ecosystems, Victoria Treto

Graduate College Dissertations and Theses

Timber harvests in the northeastern United States are integral to its economy but shifts in land management, biotic stresses, and nutrient limitations are diminishing forest productivity levels. The effects of harvesting severity and repeated harvests result in net losses of base cation nutrients which decreases woody biomass, potentially as much as 20%. Calcium (Ca) serves to regulate critical processes linked to tree growth and ecosystem health, but it is the quickest depleting base cation from northeastern forest soils. As a result, the quantification of nutrient-bearing minerals in forest soils is fundamental in predicting long-term sustainability of wood production. Further, the …

U-Pb Apatite Chronometry Of Intrusions In An Accretionary Metamorphic Belt In Western Idaho, Usa, Colleen Grace Rankin

MSU Graduate Theses

The Salmon River suture zone in west-central Idaho, USA records the tectonic processes where island arcs, similar to modern-day Japan, were accreted to the North American continent in the Jurassic and Cretaceous periods (160-90 million years ago). This suture zone contains metamorphic rocks that were buried deep within the crust at depths of 20 kilometers or more and have subsequently been brought to the surface. The exhuming processes responsible for the metamorphic rocks in the Salmon River suture zone remains unclear. Two competing hypotheses have been proposed to explain the transport of the rocks from the Salmon River suture zone …

An Early Triassic Small Shelly Fossil-Style Assemblage From The Virgin Limestone Member, Moenkopi Formation, Western United States, Vivienne Maxwell, Ben Thuy, Sara B. Pruss

Geosciences: Faculty Publications

Small shelly fossils (SSFs) are minute fossils moulded or replaced by apatite, and less commonly, other minerals like glauconite and iron oxides. This taphonomic mode is best known from Cambrian deposits, though some occurrences occur across geological time. Instances of small shelly-style preservation were found in insoluble residues from the Lower Triassic Virgin Limestone Member exposed in southern Nevada, the western United States, a second such occurrence known from this unit. Fossil steinkerns of tiny brachiopods, echinoid spines and ophiuroids are fluorapatite, with scarce phosphatic internal moulds of bivalves and two replaced ostracods. In contrast, the crinoid ossicles, almost all …

New Iodine-Apatites: Synthesis And Crystal Structure, Evgeny Bulanov, Sergey Petrov, Alexander Knyazev

Turkish Journal of Chemistry

The paper describes methods for the preparation of compounds with an apatite structure containing only iodine atoms in the "halogen" position. The crystal structure of the compounds was refined by the Rietveld method. The resulting apatites have a structure with a space group P63/m and have the following unit cell parameters: Ba4f 1.78(2) Ba6h 2.75(2)(PO4)3I0.04(2) (a = 10.18609(34) Å, c = 7.71113(30) Å, V = 692.889(54) Å3, R = 5.448%), Pb4f 1.82(2)Pb6h 2.75(2)(PO4)3I0.13(2) (a = 9.87882(18) Å, c = 7.43222(16) Å, V = 628.144(26) Å3, R = 8.533 %), Pb4f 1.90(2)Pb6h 2.68(2)(PO4)3I0.16(2) a = 9.87058(48) Å, c = 7.41255(46) Å, …

Microstructural And Microchemical Studies Of Fluid–Chondrule Interactions In A Pristine Cr Carbonaceous Chondrite And Apatite In Martian Nakhlites, Marina Martínez

Earth and Planetary Sciences ETDs

PROJECT 1: Chondrites are the most primitive objects in the solar system, aggregates of the material that formed in the solar protoplanetary disk during the first 1-5 million years of its formation. However, petrographic observations indicate that most chondrites have been modified by secondary processes, including aqueous alteration, thermal metamorphism, and shock. Fortunately, a few chondrites largely escaped these processes and are considered pristine, such as the CR carbonaceous chondrite Queen Alexandra Range (QUE) 99177. QUE 99177 is an excellent sample for deciphering information about the reactions that took place between unaltered anhydrous solar nebular components and water under highly …

Spatially Variable Syn- And Post-Orogenic Exhumation Of The Appalachian Mountains From Apatite And Zircon (U-Th)/He Thermochronology, Luke Coughtry Basler

Honors Projects

We present zircon and apatite (U-Th)/He (ZHe, closure temperature = 150-200ºC; AHe, closure temperature = 45-80ºC) results from two study regions in the Appalachians Mountains to investigate the timing, rates, and spatial trends of exhumation during Alleghanian orogenesis, Atlantic rifting, and post-rift passive margin conditions. Within West Virginia and Virginia, 10 ZHe dates along an across-orogen transect display an eastward younging trend, from ~425 million years (Ma) in the western Appalachian Plateau province, to ~250-300 Ma in the central Valley-Ridge fold-thrust belt, and 163 ± 29 Ma in the eastern Piedmont. Inverse thermal modeling of ZHe data using external geologic …

Landscape Evolution Of The Southern Colorado Plateau Using Low-Temperature Apatite Thermochronology And Detrital Zircon And Sanidine Provenance Studies, Carmen L. Winn

Earth and Planetary Sciences ETDs

Chapter 1: Westernmost Grand Canyon

Conflicting hypotheses about the timing of carving of the Grand Canyon involve either a 70 Ma (“old”) or < 6 Ma (“young”) Grand Canyon. This paper evaluates the controversial westernmost segment of the Grand Canyon where the following lines of published evidence firmly favor a “young” Canyon. 1) North-derived Paleocene Hindu Fanglomerate was deposited across the present track of the westernmost Grand Canyon, which therefore was not present at ~55 Ma. 2) The 19 Ma Separation Point basalt is stranded between high relief side canyons feeding the main stem of the Colorado River and was emplaced before these tributaries and the main canyon were incised. 3) Geomorphic constraints indicate that relief generation in tributaries and on plateaus adjacent to the westernmost Grand Canyon took place after 17 Ma. 4) The late Miocene-Pliocene Muddy Creek Formation constraint shows that no river carrying far-traveled materials exited at the mouth of the Grand Canyon until after 6 Ma.

Interpretations of previously-published low-temperature thermochronologic data conflict with these lines of evidence, but are reconciled in this paper via the integration of three methods of analyses on the same sample: apatite (U-Th)/He ages (AHe), ⁴He/³He thermochronometry (⁴He/³He), and apatite fission-track ages and lengths (AFT). “HeFTy” software was used to generate time-temperature (t-T) paths that predict all new and published ⁴He/³He, AH, and AFT data to within assumed …

The Modern Mississippi: Provenance Indicators And Human Impact, Brittney Anne Gregory

LSU Doctoral Dissertations

Given the significant degree to which the modern Mississippi River and its tributaries have been altered through dams, levees, and diversions, it is important to understand how sediment is transported from source to sink. The objective of this dissertation is to explore how the modern Mississippi River transports sediment from its tributaries to its delta using three independent proxies. Provenance indicators have traditionally been an effective way with which to characterize sediment transport in large river systems. First, detrital U-Pb zircon dating is used to investigate modern flux and possible anthropogenic influences on coarse-grained sediment within the modern Mississippi River. …

Multiscale Expression Of Apatite Dissolution, Adele Conde

Graduate College Dissertations and Theses

The weathering of apatite is the foundation of the phosphorus cycle and essential to life, yet little is known about the nanoscale mechanisms driving apatite weathering. Deciphering nanoscale dissolution in apatite is a significant step to understand phosphate weathering behavior, that was key to the development of life. Determining what controls apatite weathering can impact many areas of environmental and medical mineralogy such as dentistry, contaminant scavenging, geochronology, and paleoenvironment studies. The aim of this study was to characterize apatite dissolution across scales with an emphasis on the nanoscale mechanisms. Recent research on the weathering of silicate minerals at the …

Low Temperature Thermochronologic Constraints Across The East-Central Denali Fault: Evaluating Vertical Tectonics Along A Transpressive Orogen, Thomas Stuart Warfel

Theses - ALL

The Denali Fault is an active intracontinental structure located ~500 km north of the southern Alaskan plate boundary. In 2002, a M 7.9 earthquake initiated on a previously unmapped thrust fault subsidiary to the Denali Fault (Susitna Glacier Thrust) and propagated ~227 km eastward along the east-central segment of the Denali Fault and the Totschunda Fault. The objective of this thesis is to evaluate how fault geometry and rheologic strength control spatial-temporal patterns of exhumation along large-scale transpressive structures. Apatite fission track (AFT) thermochronology and apatite (U-Th)/He (AHe) dating are used on a combination of bedrock and cobble samples to …

Mechanisms Of Calcium Phosphate Mineralization On Biological Interfaces And Their Engineering Applications, Doyoon Kim

McKelvey School of Engineering Theses & Dissertations

All living organisms utilize phosphorus (P) as an essential component of their cell membranes, DNA and RNA, and adenosine triphosphate. Bones, in addition to bearing loads, play an important role in balancing P levels in our bodies. In bones, a network of collagen templates and calcium phosphate (CaP) nanocrystals builds hierarchical levels, from nano- to macroscale. Within this architecture, the thermodynamic properties of CaP minerals are influential. Despite the importance of nucleation, growth, and crystallization in collagen structures for tissue development, little kinetic study of these processes has been conducted due to the limited in situ techniques for monitoring these …

Controls On Erosion In The Western Tarin Basin: Implications For The Uplift Of Northwest Tibet And The Parmir, Peter D. Clift, Hongbo Zheng, Andrew Carter, Philipp Böning, Tara N. Jonell, Hannah Schorr, Xin Shan, Katharina Pahnke, Xiaochun Wei, Tammy M. Rittenour

Geosciences Faculty Publications

We present here bulk sediment major element chemistry, Nd and Sr isotope ratios, and detrital apatite fission-track (AFT) and U-Pb zircon ages to characterize the provenance of the southwestern Taklimakan Desert (northwest China) and the three major rivers draining this region. We establish the spatial and temporal controls on erosion and sediment transport in the modern Tibetan rain shadow. The Hotan River drains the North Kunlun block and is characterized by zircon populations at 160–230 Ma and 370–520 Ma. The Yarkand River shares these grains with the Hotan, but also has a very prominent zircon population at 40–160 Ma, which …

Isotopic Characterization Of Bedrock, Sediments, And Minerals As Provenance Tools: Examples From An Inselberg In The Mojave Desert Of Se California, Mariana Belen Bonich-Wissink

Dissertations - ALL

Our understanding of the evolution of the Earth’s surface is driven by our knowledge and comprehension of the processes which shape the landscape. The source, formation, and transport pathways of sediment are critical components to understanding crustal processes and changes and are often grouped under the broad scope of provenance analysis. Much of what we know of how sediments evolve and shape our landscape stems from provenance analysis, which tries to trace the pathway of source to sink. However, complexities arise when the final composition or signature of the detrital material is altered, which results in provenance signature deviations from …

Mechanisms Of Nutrient Limitation And Nutrient Acquisition In Managed And Unmanaged Forest Ecosystems, Matthew A. Vadeboncoeur

Doctoral Dissertations

Understanding the interactions between global change, human and natural disturbances, and other factors on biogeochemical processes in forests is necessary to ensure the sustainability of forest management. Here I report the results of several investigations into nutrient acquisition processes in the forests of New Hampshire. I begin with a meta-analysis of fertilization studies showing that phosphorus (P) and calcium (Ca) as well as nitrogen (N) may limit primary production in deciduous forests of the region. Because these limiting nutrients are all removed from the ecosystem when trees are harvested, I compared nutrient budgets under a range of harvesting scenarios with …

Position Preference And Diffusion Path Of An Oxygen Ion In Apatite-Type Lanthanum Silicate La9.33si6o26: A Density Functional Study, Ting Liao, Taizo Sasaki, Shigeru Suehara, Ziqi Sun

Australian Institute for Innovative Materials - Papers

Using density functional theory, we investigated the position preference and diffusion mechanisms of interstitial oxygen ions in lanthanum silicate La_9.33Si₆O₂₆, which is an apatite-structured oxide and a promising candidate electrolyte material for solid oxide fuel cells. The reported lanthanum vacancies were explicitly taken into account by theoretically determining their arrangement with a supercell model. The most stable structures and the formation energies of oxygen interstitials were determined for each charged state. It was found that the double-negatively charged state is stable over a wide range of the Fermi level, and that the excess oxygen …

Apatite-Bearing Magnetite Deposit Of Pinarbaşi (Adiyaman); Geological, Geochemical Properties And Economical Potential, Hüseyin Çelebi̇, Cahit Helvaci, Ali Uçurum

Bulletin of the Mineral Research and Exploration

In the near vicinity of the apatitebearing magnetite deposit of Pýnarbaşı Permianaged Malatya Metamorphites consisting of, from bottom to top, chlorite schists, cericite schists, calcschists and recrystallized limestones cover large areas. These folded and faulted metamorphic rocks, which thrust over the Eoceneaged Maden Complex, underwent one regional metamorphism and one subsequent retrograde metamorphism in the greenschist facies. Mineralizations associated with chloritesericite schists are in the form of magnetitebearing apatite lenses. The ore horizons, which reach a thickness of 15 m and have a northsouth strike, dip approximately 30 degrees to the west. In the field, massive, banded and disseminated ore …

Geochemical Fingerprinting Of Volcanic Airfall Deposits : A Tool In Stratigraphic Correlation, Soumava Adhya

Legacy Theses & Dissertations (2009 - 2024)

Chemical fingerprints of volcanic airfall deposits obtained from high-precision electron microprobe analysis of glass and phenocrysts phases provide geochemical correlations with temporal precision unattainable by other methods. In this research electron microprobe analysis (EMA) techniques, to fingerprint chemically and correlate fresh and altered volcanic airfall deposits, have been utilized to test the value of this tool for future research on stratigraphic correlation. The following samples were chosen from within a variety of sedimentary rocks widely separated spatially and temporally: