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2018

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Michigan Technological University

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Articles 1 - 30 of 53

Full-Text Articles in Physical Sciences and Mathematics

Monitoring The Impact Of Groundwater Pumping On Infrastructure Using Geographic Information System (Gis) And Persistent Scatterer Interferometry (Psi), Kirsten Deprekel, El Hachemi Bouali, Thomas Oommen Dec 2018

Monitoring The Impact Of Groundwater Pumping On Infrastructure Using Geographic Information System (Gis) And Persistent Scatterer Interferometry (Psi), Kirsten Deprekel, El Hachemi Bouali, Thomas Oommen

Department of Geological and Mining Engineering and Sciences Publications

Transportation infrastructure is critical for the advancement of society. Bridges are vital for an efficient transportation network. Bridges across the world undergo variable deformation/displacement due to the Earth’s dynamic processes. This displacement is caused by ground motion, which occurs from many natural and anthropogenic events. Events causing deformation include temperature fluctuation, subsidence, landslides, earthquakes, water/sea level variation, subsurface resource extraction, etc. Continual deformation may cause bridge failure, putting civilians at risk, if not managed properly. Monitoring bridge displacement, large and small, provides evidence of the state and health of the bridge. Traditionally, bridge monitoring has been executed through on-site surveys. …


Revisiting The Paleomagnetism Of The Neoarchean Uauá Mafic Dyke Swarm, Brazil: Implications For Archean Supercratons, J. Salminen, E. P. Oliveira, Elisa J. Piispa, Aleksey Smirnov, R. I. F. Trindade Dec 2018

Revisiting The Paleomagnetism Of The Neoarchean Uauá Mafic Dyke Swarm, Brazil: Implications For Archean Supercratons, J. Salminen, E. P. Oliveira, Elisa J. Piispa, Aleksey Smirnov, R. I. F. Trindade

Michigan Tech Publications

The original connections of Archean cratons are becoming traceable due to an increasing amount of paleomagnetic data and refined magmatic barcodes. The Uauá block of the northern São Francisco craton may represent a fragment of a major Archean craton. Here, we report new paleomagnetic data from the 2.62 Ga Uauá tholeiitic mafic dyke swarm of the Uauá block in the northern São Francisco craton, Eastern Brazil. Our paleomagnetic results confirm the earlier results for these units, but our interpretation differs. We suggest that the obtained characteristic remanent magnetization for the 2.62 Ga swarm is of primary origin, supported by a …


Winding Around Non-Hermitian Singularities, Qi Zhong, Mercedeh Khajavikhan, Demetrios Christodoulides, Ramy El-Ganainy Nov 2018

Winding Around Non-Hermitian Singularities, Qi Zhong, Mercedeh Khajavikhan, Demetrios Christodoulides, Ramy El-Ganainy

Department of Physics Publications

Non-Hermitian singularities are ubiquitous in non-conservative open systems. Owing to their peculiar topology, they can remotely induce observable effects when encircled by closed trajectories in the parameter space. To date, a general formalism for describing this process beyond simple cases is still lacking. Here we develop a general approach for treating this problem by utilizing the power of permutation operators and representation theory. This in turn allows us to reveal a surprising result that has so far escaped attention: loops that enclose the same singularities in the parameter space starting from the same point and traveling in the same direction, …


Oil Spills Detection By Means Of Uas And Low-Cost Airborne Thermal Sensors, A. Al-Shammari, Eugene Levin, R. Shults Nov 2018

Oil Spills Detection By Means Of Uas And Low-Cost Airborne Thermal Sensors, A. Al-Shammari, Eugene Levin, R. Shults

School of Technology Publications

This paper provides an overview of oil spill scenarios and the remote sensing methods used for detection and mapping the spills. It also discusses the different kinds of thermal sensors used in oil spills detection. As UAS is becoming an important player in the oil and gas industry for the low operating costs involved, this research involved working with a cheap thermal airborne sensor mounted on DJI Phantom 4 system. Data were collected in two scenarios, first scenario is collecting data in Michigan’s Upper Peninsula at a petroleum company location and the second scenario was an indoor experiment simulating an …


Fine-Scale Droplet Clustering In Atmospheric Clouds: 3d Radial Distribution Function From Airborne Digital Holography, Michael L. Larsen, Raymond Shaw, Alexander Kostinski, Susanne Glienke Nov 2018

Fine-Scale Droplet Clustering In Atmospheric Clouds: 3d Radial Distribution Function From Airborne Digital Holography, Michael L. Larsen, Raymond Shaw, Alexander Kostinski, Susanne Glienke

Department of Physics Publications

The extent of droplet clustering in turbulent clouds has remained largely unquantified, and yet is of possible relevance to precipitation formation and radiative transfer. To that end, data gathered by an airborne holographic instrument are used to explore the three-dimensional spatial statistics of cloud droplet positions in homogeneous stratiform boundary-layer clouds. The three-dimensional radial distribution functions g(r) reveal unambiguous evidence of droplet clustering. Three key theoretical predictions are observed: the existence of positive correlations, onset of correlation in the turbulence dissipation range, and monotonic increase of g(r) with decreasing r. This implies that current theory captures the essential processes contributing …


Target Localization And Tracking By Fusing Doppler Differentials From Cellular Emanations With A Multi-Spectral Video Tracker, Casey D. Demars, Michael Roggemann, Adam Webb, Timothy C. Havens Oct 2018

Target Localization And Tracking By Fusing Doppler Differentials From Cellular Emanations With A Multi-Spectral Video Tracker, Casey D. Demars, Michael Roggemann, Adam Webb, Timothy C. Havens

Michigan Tech Publications

We present an algorithm for fusing data from a constellation of RF sensors detecting cellular emanations with the output of a multi-spectral video tracker to localize and track a target with a specific cell phone. The RF sensors measure the Doppler shift caused by the moving cellular emanation and then Doppler differentials between all sensor pairs are calculated. The multi-spectral video tracker uses a Gaussian mixture model to detect foreground targets and SIFT features to track targets through the video sequence. The data is fused by associating the Doppler differential from the RF sensors with the theoretical Doppler differential computed …


Scale Dependence Of Cloud Microphysical Response To Turbulent Entrainment And Mixing, Bipin Kumar, Paul Gotzfried, Neethl Suresh, Jörg Schumacher, Raymond Shaw Oct 2018

Scale Dependence Of Cloud Microphysical Response To Turbulent Entrainment And Mixing, Bipin Kumar, Paul Gotzfried, Neethl Suresh, Jörg Schumacher, Raymond Shaw

Michigan Tech Publications

The dynamics and lifetime of atmospheric clouds are tightly coupled to entrainment and turbulent mixing. This paper presents direct numerical simulations of turbulent mixing followed by droplet evaporation at the cloud‐clear air interface in a meter‐sized volume, with an ensemble of up to almost half a billion individual cloud water droplets. The dependence of the mixing process on domain size reveals that inhomogeneous mixing becomes increasingly important as the domain size is increased. The shape of the droplet size distribution varies strongly with spatial scale, with the appearance of a pronounced negative exponential tail. The increase of relative dispersion during …


A Redox Conjugated Polymer-Based All-Solid-State Reference Electrode, Ke Qu, Mingxi Fang, Shuwei Zhang, Haiying Liu, Xiangqun Zeng Oct 2018

A Redox Conjugated Polymer-Based All-Solid-State Reference Electrode, Ke Qu, Mingxi Fang, Shuwei Zhang, Haiying Liu, Xiangqun Zeng

Department of Chemistry Publications

This work reports the design, synthesis, and characterization of a novel redox-active conjugated polyaniline containing quinone moiety as a solid state reference electrode. The union of electro-active quinone with π-conjugated polyaniline was created by the first chemical synthesis of para-dimethoxybenzene-functionalized aniline as a monomer using a palladium-mediated coupling. The successful polymerization of the as-prepared monomer was accomplished without acid additives. Its post-polymerization modification with strong Lewis acid boron tribromide furnished unique poly (aniline quinone/hydroquinone) with desired properties for all-solid-state reference electrode (RE) applications. The electrochemical responses from the conjugated polyaniline backbone in this unique polymer have been “suppressed” by the …


Turbulence Induced Cloud Voids: Observation And Interpretation, Katarzyna Karpinska, Jonathan F. E. Bodenschatz, Szymon P. Malinowski, Jakub L. Nowak, Steffen Risius, Tina Schmeissner, Raymond Shaw, Holger Siebert, Hengdong Xi, Haitao Xu, Eberhard Bodenschatz Oct 2018

Turbulence Induced Cloud Voids: Observation And Interpretation, Katarzyna Karpinska, Jonathan F. E. Bodenschatz, Szymon P. Malinowski, Jakub L. Nowak, Steffen Risius, Tina Schmeissner, Raymond Shaw, Holger Siebert, Hengdong Xi, Haitao Xu, Eberhard Bodenschatz

Department of Physics Publications

The phenomenon of cloud voids, i.e., elongated volumes inside a cloud that are devoid of droplets, was observed with laser sheet photography in clouds at a mountain-top station. Two experimental cases, similar in turbulence conditions yet with diverse droplet size distributions and cloud void prevalence, are reported. A theoretical explanation is proposed based on the study of heavy inertial sedimenting particles inside a Burgers vortex. A general conclusion regarding void appearance is drawn from theoretical analysis. Numerical simulations of polydisperse droplet motion with realistic vortex parameters and Mie scattering visual effects accounted for can explain the presence of voids with …


A Near-Infrared Fluorescent Probe Based On A Fret Rhodamine Donor Linked To A Cyanine Acceptor For Sensitive Detection Of Intracellular Ph Alternations, Yibin Zhang, Jianheng Bi, Shuai Xia, Wafa Mazi, Shulin Wan, Logan Mikesell, Rudy Luck, Haiying Liu Oct 2018

A Near-Infrared Fluorescent Probe Based On A Fret Rhodamine Donor Linked To A Cyanine Acceptor For Sensitive Detection Of Intracellular Ph Alternations, Yibin Zhang, Jianheng Bi, Shuai Xia, Wafa Mazi, Shulin Wan, Logan Mikesell, Rudy Luck, Haiying Liu

Department of Chemistry Publications

A fluorescence resonance energy transfer (FRET)-based near-infrared fluorescent probe (B+) for double-checked sensitive detection of intracellular pH changes has been synthesized by binding a near-infrared rhodamine donor to a near-infrared cyanine acceptor through robust C-N bonds via a nucleophilic substitution reaction. To demonstrate the double-checked advantages of probe B+, a near-infrared probe (A) was also prepared by modification of a near-infrared rhodamine dye with ethylenediamine to produce a closed spirolactam residue. Under basic conditions, probe B+ shows only weak fluorescence from the cyanine acceptor while probe A displays nonfluorescence due to retention of the closed …


First Observations Of Volcanic Eruption Clouds From The L1 Earth-Sun Lagrange Point By Dscovr/Epic, Simon Carn, N. A. Krotov, B. L. Fisher, C. Li, A. J. Prata Oct 2018

First Observations Of Volcanic Eruption Clouds From The L1 Earth-Sun Lagrange Point By Dscovr/Epic, Simon Carn, N. A. Krotov, B. L. Fisher, C. Li, A. J. Prata

Michigan Tech Publications

Volcanic sulfur dioxide (SO2) emissions have been measured by ultraviolet sensors on polar‐orbiting satellites for several decades but with limited temporal resolution. This precludes studies of key processes believed to occur in young (~1–3 hr old) volcanic clouds. In 2015, the launch of the Earth Polychromatic Imaging Camera (EPIC) aboard the Deep Space Climate Observatory (DSCOVR) provided an opportunity for novel observations of volcanic eruption clouds from the first Earth‐Sun Lagrange point (L1). The L1 vantage point provides continuous observations of the sunlit Earth, offering up to eight or nine observations of volcanic SO2 clouds in the …


Molecular And Physical Characteristics Of Aerosol At A Remote Free Troposphere Site: Implications For Atmospheric Aging, Simeon Schum, Bo Zhang, Katja Džepina, Paolo Fialho, Claudio Mazzoleni, Lynn Mazzoleni Oct 2018

Molecular And Physical Characteristics Of Aerosol At A Remote Free Troposphere Site: Implications For Atmospheric Aging, Simeon Schum, Bo Zhang, Katja Džepina, Paolo Fialho, Claudio Mazzoleni, Lynn Mazzoleni

Department of Chemistry Publications

Aerosol properties are transformed by atmospheric processes during long-range transport and play a key role in the Earth's radiative balance. To understand the molecular and physical characteristics of free tropospheric aerosol, we studied samples collected at the Pico Mountain Observatory in the North Atlantic. The observatory is located in the marine free troposphere at 2225m above sea level, on Pico Island in the Azores archipelago. The site is ideal for the study of long-range-transported free tropospheric aerosol with minimal local influence. Three aerosol samples with elevated organic carbon concentrations were selected for detailed analysis. FLEXPART retroplumes indicated that two of …


Mid-Atlantic Forest Ecosystem Vulnerability Assessment And Synthesis: A Report From The Mid-Atlantic Climate Change Response Framework Project, Patricia Leopold, Louis Iverson, Frank R. Thompson Iii, Leslie A. Brandt, Stephen D. Handler, Danielle Shannon, Matt Kelly, Et. Al. Oct 2018

Mid-Atlantic Forest Ecosystem Vulnerability Assessment And Synthesis: A Report From The Mid-Atlantic Climate Change Response Framework Project, Patricia Leopold, Louis Iverson, Frank R. Thompson Iii, Leslie A. Brandt, Stephen D. Handler, Danielle Shannon, Matt Kelly, Et. Al.

College of Forest Resources and Environmental Science Publications

Forest ecosystems will be affected directly and indirectly by a changing climate over the 21st century. This assessment evaluates the vulnerability of 11 forest ecosystems in the Mid-Atlantic region (Pennsylvania, New Jersey, Delaware, eastern Maryland, and southern New York) under a range of future climates. We synthesized and summarized information on the contemporary landscape, provided information on past climate trends, and described a range of projected future climates. This information was used to parameterize and run multiple forest impact models, which provided a range of potential tree responses to climate. Finally, we brought these results before two multidisciplinary panels of …


Data Supporting The Paper "Turbulence Induced Cloud Voids: Observation And Interpretation", Katarzyna Karpinska, Jonathan F. E. Bodenschatz, Szymon P. Malinowski, Jakub L. Nowak, Steffen Risius, Tina Schmeissner, Raymond Shaw, Holger Siebert, Hengdong Xi, Haitao Xu, Eberhard Bodenschatz Oct 2018

Data Supporting The Paper "Turbulence Induced Cloud Voids: Observation And Interpretation", Katarzyna Karpinska, Jonathan F. E. Bodenschatz, Szymon P. Malinowski, Jakub L. Nowak, Steffen Risius, Tina Schmeissner, Raymond Shaw, Holger Siebert, Hengdong Xi, Haitao Xu, Eberhard Bodenschatz

Department of Physics Publications

No abstract provided.


Dispersion Aerosol Indirect Effect In Turbulent Clouds: Laboratory Measurements Of Effective Radius, K. K. Chandrakar, Will Cantrell, A. Kostinski, Raymond Shaw Sep 2018

Dispersion Aerosol Indirect Effect In Turbulent Clouds: Laboratory Measurements Of Effective Radius, K. K. Chandrakar, Will Cantrell, A. Kostinski, Raymond Shaw

Department of Physics Publications

Cloud optical properties are determined not only by the number density nd and mean radiusof cloud droplets but also by the shape of the droplet size distribution. The change in cloud optical depth with changing nd, due to the change in distribution shape, is known as the dispersion effect. Droplet relative dispersion is defined as d=σr / ṝ . For the first time, a commonly used effective radius parameterization is tested in a controlled laboratory environment by creating a turbulent cloud. Stochastic condensation growth suggests d independent of nd for a nonprecipitating cloud, …


Organization And Oscillations In Simulated Shallow Convective Clouds, Guy Dagan, Ilan Koren, Alexander Kostinski, Orit Altaratz Sep 2018

Organization And Oscillations In Simulated Shallow Convective Clouds, Guy Dagan, Ilan Koren, Alexander Kostinski, Orit Altaratz

Department of Physics Publications

Physical insights into processes governing temporal organization and evolution of cloud fields are of great importance for climate research. Here using large eddy simulations with a bin microphysics scheme, we show that warm convective cloud fields exhibit oscillations with two distinct periods (~10 and ~90 min, for the case studied here). The shorter period dominates the nonprecipitating phase, and the longer period is related to the precipitating phase. We show that rain processes affect the domain's thermodynamics, hence forcing the field into a low‐frequency recharge‐discharge cycle of developing cloudiness followed by precipitation‐driven depletion. The end result of precipitation is stabilization …


Molecular Insights On Aging And Aqueous-Phase Processing From Ambient Biomass Burning Emissions-Influenced Po Valley Fog And Aerosol, Matthew Brege, Marco Paglione, Stefania Gilardoni, Maria Cristina Facchini, Lynn Mazzoleni Sep 2018

Molecular Insights On Aging And Aqueous-Phase Processing From Ambient Biomass Burning Emissions-Influenced Po Valley Fog And Aerosol, Matthew Brege, Marco Paglione, Stefania Gilardoni, Maria Cristina Facchini, Lynn Mazzoleni

Department of Chemistry Publications

To study the influence of regional biomass burning emissions and secondary processes, ambient samples of fog and aerosol were collected in the Po Valley (Italy) during the 2013 Supersito field campaign. After the extent of fresh vs. aged biomass burning influence was estimated from proton nuclear magnetic resonance (1H NMR) and high-resolution time-of-flight aerosol mass spectrometry (HR-ToF-AMS), two samples of fog water and two samples of PM1 aerosol were selected for ultrahigh-resolution Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) analysis. Molecular compositions indicated that the water-soluble organic matter was largely non-polymeric without clearly repeating units. The …


Approximating The Generalized Singular Value Expansion, Mark Gockenbach, Matthew J. Roberts Sep 2018

Approximating The Generalized Singular Value Expansion, Mark Gockenbach, Matthew J. Roberts

Department of Mathematical Sciences Publications

The generalized singular value expansion (GSVE) simultaneously diagonalizes a pair of operators on Hilbert space. From a theoretical point of view, the GSVE enables a straightforward analysis of, for example, weighted least-squares problems and the method of Tikhonov regularization with seminorms. When the operators are discretized, an approximate GSVE can be computed from the generalized singular value decomposition of a pair of Galerkin matrices. Unless the discretization is carefully chosen, spurious modes can appear, but a natural condition on the discretization guarantees convergence of the approximate GSVE to the exact one. Numerical examples illustrate the pitfalls of a poor discretization …


Data Supporting The Paper "Dispersion Aerosol Indirect Effect In Turbulent Clouds: Laboratory Measurements Of Effective Radius", K. K. Chandrakar, Will Cantrell, A. Kostinski, R. A. Shaw Sep 2018

Data Supporting The Paper "Dispersion Aerosol Indirect Effect In Turbulent Clouds: Laboratory Measurements Of Effective Radius", K. K. Chandrakar, Will Cantrell, A. Kostinski, R. A. Shaw

Department of Physics Publications

No abstract provided.


Simulation Data Supporting The Paper "Optical Properties And Radiative Forcing Of Fractal-Like Tar Ball Aggregates From Biomass Burning", Janarjan Bhandari, Swarup China, Giulia Girotto, Barbara Scarnato, Kyle Gorkowski, Allison Aiken, Manvendra Dubey, C. Mazzoleni Aug 2018

Simulation Data Supporting The Paper "Optical Properties And Radiative Forcing Of Fractal-Like Tar Ball Aggregates From Biomass Burning", Janarjan Bhandari, Swarup China, Giulia Girotto, Barbara Scarnato, Kyle Gorkowski, Allison Aiken, Manvendra Dubey, C. Mazzoleni

Department of Physics Publications

Simulations data supporting the paper "Optical properties and radiative forcing of fractal-like tar ball aggregates from biomass burning," to be submitted to the Journal of Quantitative Spectroscopy and Radiative Transfer.


On The Convergence Of A Heuristic Parameter Choice Rule For Tikhonov Regularization, Mark Gockenbach, Elaheh Gorgin Aug 2018

On The Convergence Of A Heuristic Parameter Choice Rule For Tikhonov Regularization, Mark Gockenbach, Elaheh Gorgin

Department of Mathematical Sciences Publications

Multiplicative regularization solves a linear inverse problem by minimizing the product of the norm of the data misfit and the norm of the solution. This technique is related to Tikhonov regularization with the parameter chosen to make the data misfit and regularization terms (of the Tikhonov objective function) equal. This suggests a heuristic parameter choice method, equivalent to the rule previously proposed by Reginska. Reginska's rule is well defined provided the data is sufficiently close to exact data and does not lie in the range of the operator. If a sufficiently large portion of the data error lies outside the …


Measurement And Modeling Of The Multiwavelength Optical Properties Of Uncoated Flame-Generated Soot, Sara D. Forestieri, Taylor M. Helgestad, Andrew T. Lambe, Lindsay Renbaum-Wolff, Paulo Massoli, Eben S. Cross, Claudio Mazzoleni, Et. Al. Aug 2018

Measurement And Modeling Of The Multiwavelength Optical Properties Of Uncoated Flame-Generated Soot, Sara D. Forestieri, Taylor M. Helgestad, Andrew T. Lambe, Lindsay Renbaum-Wolff, Paulo Massoli, Eben S. Cross, Claudio Mazzoleni, Et. Al.

Michigan Tech Publications

Optical properties of flame-generated black carbon (BC) containing soot particles were quantified at multiple wavelengths for particles produced using two different flames: a methane diffusion flame and an ethylene premixed flame. Measurements were made for (i) nascent soot particles, (ii) thermally denuded nascent particles, and (iii) particles that were coated and then thermally denuded, leading to the collapse of the initially lacy, fractal-like morphology. The measured mass absorption coefficients (MACs) depended on soot maturity and generation but were similar between flames for similar conditions. For mature soot, here corresponding to particles with volume-equivalent diameters >∼160 nm, the MAC and absorption …


Observation Of A Link Between Energy Dissipation Rate And Oscillation Frequency Of The Large-Scale Circulation In Dry And Moist Rayleigh-Bénard Turbulence, Dennis Niedermeier, Kelken Chang, Will Cantrell, Kamal Kant Chandrakar, David Ciochetto, Raymond Shaw Aug 2018

Observation Of A Link Between Energy Dissipation Rate And Oscillation Frequency Of The Large-Scale Circulation In Dry And Moist Rayleigh-Bénard Turbulence, Dennis Niedermeier, Kelken Chang, Will Cantrell, Kamal Kant Chandrakar, David Ciochetto, Raymond Shaw

Department of Physics Publications

In this study both the small- and large-scale flow properties of turbulent Rayleigh-Bénard convection are investigated. Experiments are carried out using the Π chamber (aspect ratio Γ=2) for Rayleigh number range Ra∼108–109 and Prandtl number Pr≈0.7. Furthermore, experiments are run for dry and wet conditions, i.e., top and bottom surfaces of the chamber are dry and wet, respectively. For wet conditions we further distinguish between conditions with and without the presence of sodium chloride aerosol particles which, if supersaturated conditions are achieved, lead to cloud droplet formation. We therefore refer to these conditions as moist and cloudy, …


Identification And Characterization Of An Anomaly In Two-Dimensional Video Disdrometer Data, Michael L. Larsen, Michael Schönhuber Aug 2018

Identification And Characterization Of An Anomaly In Two-Dimensional Video Disdrometer Data, Michael L. Larsen, Michael Schönhuber

Michigan Tech Publications

The two-dimensional video distrometer (2DVD) is a well known ground based point-monitoring precipitation gauge, often used as a ground truth instrument to validate radar or satellite rainfall retrieval algorithms. This instrument records a number of variables for each detected hydrometeor, including the detected position within the sample area of the instrument. Careful analyses of real 2DVD data reveal an artifact—there are time periods where hydrometeor detections within parts of the sample area are artificially enhanced or diminished. Here, we (i) illustrate this anomaly with an exemplary 2DVD data set, (ii) describe the origin of this anomaly, (iii) develop and present …


Lucius Lee Hubbard, One Of The Copper Country's Greatest Mineral Collectors (1849–1933), Christopher J. Stefano, William B. Barr Jr. Aug 2018

Lucius Lee Hubbard, One Of The Copper Country's Greatest Mineral Collectors (1849–1933), Christopher J. Stefano, William B. Barr Jr.

A. E. Seaman Mineral Museum Publications

No abstract provided.


Light Absorption By Polar And Non-Polar Aerosol Compounds From Laboratory Biomass Combustion, Deep Sengupta, Vera Samburova, Chiranjiva Bhattarai, Elena Kirillova, Lynn Mazzoleni, Michealene Iaukea-Lum, Adam Watts, Audrey Khlystov Aug 2018

Light Absorption By Polar And Non-Polar Aerosol Compounds From Laboratory Biomass Combustion, Deep Sengupta, Vera Samburova, Chiranjiva Bhattarai, Elena Kirillova, Lynn Mazzoleni, Michealene Iaukea-Lum, Adam Watts, Audrey Khlystov

Department of Chemistry Publications

Fresh and atmospherically aged biomass-burning (BB) aerosol mass is mostly comprised of strongly light-absorbing black carbon (BC) and of organic carbon (OC) with its light-absorbing fraction – brown carbon (BrC). There is a lack of data on the physical and chemical properties of atmospheric BB aerosols, leading to high uncertainties in estimates of the BB impact on air quality and climate, especially for BrC. The polarity of chemical compounds influences their fate in the atmosphere including wet/dry deposition and chemical and physical processing. So far, most of the attention has been given to the water-soluble (polar) fraction of BrC, while …


A Method For Computing The Three-Dimensional Radial Distribution Function Of Cloud Particles From Holographic Images, Michael L. Larsen, Raymond Shaw Jul 2018

A Method For Computing The Three-Dimensional Radial Distribution Function Of Cloud Particles From Holographic Images, Michael L. Larsen, Raymond Shaw

Michigan Tech Publications

Reliable measurements of the three-dimensional radial distribution function for cloud droplets are desired to help characterize microphysical processes that depend on local drop environment. Existing numerical techniques to estimate this three-dimensional radial distribution function are not well suited to in situ or laboratory data gathered from a finite experimental domain. This paper introduces and tests a new method designed to reliably estimate the three-dimensional radial distribution function in contexts in which (i) physical considerations prohibit the use of periodic boundary conditions and (ii) particle positions are measured inside a convex volume that may have a large aspect ratio. The method …


The Interactive Stratospheric Aerosol Model Intercomparison Project (Isa-Mip): Motivation And Experimental Design, Claudio Timmreck, Graham W. Mann, Valentina Aquila, Rene Hommel, Lindsay A. Lee, Simon Carn, Et. Al. Jul 2018

The Interactive Stratospheric Aerosol Model Intercomparison Project (Isa-Mip): Motivation And Experimental Design, Claudio Timmreck, Graham W. Mann, Valentina Aquila, Rene Hommel, Lindsay A. Lee, Simon Carn, Et. Al.

Michigan Tech Publications

The Stratospheric Sulfur and its Role in Climate (SSiRC) Interactive Stratospheric Aerosol Model Intercomparison Project (ISA-MIP) explores uncertainties in the processes that connect volcanic emission of sulfur gas species and the radiative forcing associated with the resulting enhancement of the stratospheric aerosol layer. The central aim of ISA-MIP is to constrain and improve interactive stratospheric aerosol models and reduce uncertainties in the stratospheric aerosol forcing by comparing results of standardized model experiments with a range of observations. In this paper we present four co-ordinated inter-model experiments designed to investigate key processes which influence the formation and temporal development of stratospheric …


On The Detection Of Statistical Heterogeneity In Rain Measurements, A. R. Jameson, Michael L. Larsen, A. Kostinski Jul 2018

On The Detection Of Statistical Heterogeneity In Rain Measurements, A. R. Jameson, Michael L. Larsen, A. Kostinski

Department of Physics Publications

The application of the Wiener–Khintchine theorem for translating a readily measured correlation function into the variance spectrum, important for scale analyses and for scaling transformations of data, requires that the data be wide-sense homogeneous (stationary), that is, that the first and second moments of the probability distribution of the variable are the same at all times (stationarity) or at all locations (homogeneity) over the entire observed domain. This work provides a heuristic method independent of statistical models for evaluating whether a set of data in rain is wide-sense stationary (WSS). The alternative, statistical heterogeneity, requires 1) that there be no …


Production Of Trimethylaluminum (Me3al) With Counterfeit Refrigerant Chloromethane (R-40), Reactivity Of Me3al With Refrigerant Oils And Methods To Deactivate Me3al, Zhichao Chen, Rudy Luck Jun 2018

Production Of Trimethylaluminum (Me3al) With Counterfeit Refrigerant Chloromethane (R-40), Reactivity Of Me3al With Refrigerant Oils And Methods To Deactivate Me3al, Zhichao Chen, Rudy Luck

Michigan Tech Publications

Reactions between Al containing materials and counterfeit refrigerant chloromethane (R-40) were investigated under various conditions. The addition of Mg effected a reaction indicating that trimethylaluminum may have been produced in the reaction. A different study involving Al-foil, AlCl3 and chloromethane resulted in cracks detected on the Al-foil which reduced in weight by 19% and methane was detected. Studies conducted either at room temperature or at 80°C with two other genuine refrigerants, R-142b (1-chloro-1,1-difluoroethane) and R-133a (2-chloro-1,1,1-trifluoroethane) did not form organoaluminum compounds. Several commercially available refrigerant oils were subjected to Me3Al. Only polyester oil resulted in a decrease …