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Full-Text Articles in Physical Sciences and Mathematics

Microfabrication, Characterization, And Application Of Carbon Nanotube Templated Thin Layer Chromatography Plates, And Functionalization Of Porous Graphitic Carbon, David S. Jensen Nov 2012

Microfabrication, Characterization, And Application Of Carbon Nanotube Templated Thin Layer Chromatography Plates, And Functionalization Of Porous Graphitic Carbon, David S. Jensen

Theses and Dissertations

This dissertation contains the following sections. Chapter 1 contains a detailed description of the theory of thin layer chromatography (TLC). Chapter 2 describes the benefits and practical considerations of elevated temperatures in liquid chromatography (LC). The porous graphitic carbon (PGC) I modified as part of my work is often used in elevated temperature LC. Chapter 3 shows a thermodynamic analysis of chromatographic retention at elevated temperature, and Chapter 4 contains a closer look at the van 't Hoff equation in LC and how it can be used in retention modeling. In Chapter 5, I describe a new procedure for microfabricating …


Effects Of Metallic, Semiconducting, And Insulating Substrates On The Coupling Involving Radiative Polaritons In Thin Oxide Films, Anita J. Vincent-Johnson, Kyle A. Vasquez, Giovanna Scarel, James S. Hammonds Jr., Mathieu Francoeur Feb 2012

Effects Of Metallic, Semiconducting, And Insulating Substrates On The Coupling Involving Radiative Polaritons In Thin Oxide Films, Anita J. Vincent-Johnson, Kyle A. Vasquez, Giovanna Scarel, James S. Hammonds Jr., Mathieu Francoeur

Department of Physics and Astronomy - Faculty Scholarship

Through simulations, this work explores the effects of conducting, semiconducting, and insulating substrates on the absorption of infrared radiation by radiative polaritons in oxide layers with thicknesses that range from 30 nm to 9 μm. Using atomic layer deposition, oxide layers can be formed in the nanometer scale. Our results suggest that the chemistry and conductivity of the substrate determine the amount of absorption by radiative polaritons in oxide layers thinner than the skin depth. The effects of the chemistry and conductivity of the substrate are especially effective for oxide films thinner than about 250 nm, which we label as …