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Full-Text Articles in Physical Sciences and Mathematics

A Structural, Magnetic, And Mössbauer Spectral Study Of The Tbco₄₋ₓfeₓb Compounds With X=0, 1, And 2, Herv´ Mayot, Olivier Isnard, Fernande Grandjean, Gary J. Long Jun 2009

A Structural, Magnetic, And Mössbauer Spectral Study Of The Tbco₄₋ₓfeₓb Compounds With X=0, 1, And 2, Herv´ Mayot, Olivier Isnard, Fernande Grandjean, Gary J. Long

Chemistry Faculty Research & Creative Works

The TbCo4-x Fex B compounds with x=0, 1, and 2 have been investigated by x-ray and neutron diffraction, magnetic measurements, and iron-57 Mössbauer spectroscopy. The substitution of cobalt by iron induces both an anisotropic increase in the unit-cell volume and a large increase of approximately 250 K in the Curie temperature; the 4.2 K magnetization decreases continuously with increasing iron content. The powder neutron diffraction patterns and the Mössbauer spectra of the TbCo4-x Fex B compounds reveal a strong preferential substitution of iron for cobalt on the 2c site, small transition metal magnetic moments of approximately …


Magnetic Entropy Change Of V Substituted Ni–Mn–Ga Heusler Alloy, S G. Min, L Malkinski, Y D. Zhang, S C. Yu, K W. Lee, Y C. Kim Jan 2009

Magnetic Entropy Change Of V Substituted Ni–Mn–Ga Heusler Alloy, S G. Min, L Malkinski, Y D. Zhang, S C. Yu, K W. Lee, Y C. Kim

Physics Faculty Publications

The magnetization behaviors have been analyzed for Ni54Mn21−xVxGa25 (x = 0,2,4) alloys which were prepared by conventional arc melting method in argon atmosphere. The Curie temperature TC was found to be 325, 300, and 265 K and the austenitic transition temperature TA on heating was found to be 315, 217, and 124 K for x = 0, 2, and 4, respectively. The magnetic characteristics were performed with a Quantum Design superconducting quantum interference device magnetometer in the field of up to 20 kOe. A large magnetic entropy change Δ …