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- Electrochemical oxidation (2)
- Electroreduction (2)
- Fuel cell (2)
- Adsorbed antimony atom (1)
- Aldehydes (1)
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- Allyl alcohol (1)
- Anodic Pb(Ⅱ) film (1)
- Basic lead sulfates (1)
- Bioeletrochemistry (1)
- Calcium electrode (1)
- Callcium-thionyl chloride cells (1)
- Carbon materials (1)
- Carboxylic acids (1)
- Cathode ingredients (1)
- Cell performance (1)
- Corrosion (1)
- Current density (1)
- Electrocatalytic (1)
- Electrocatalytic oxidation (1)
- Electrochemieal-ESR (1)
- Electrocrystallization (1)
- Electrode surface (1)
- Energy efficiency (1)
- Gaseous recombination reaction (1)
- Hydrogen peroxide (1)
- Impedance tracing (1)
- Intercalation Reaction (1)
- LB monolayer (1)
- Lead (1)
- Lead acid battery (1)
Articles 1 - 18 of 18
Full-Text Articles in Physical Sciences and Mathematics
Comparison Of The Charge/Discharge Charasteristics Between Ni Cd And Ni Mh Battery And Its Improvement Of Manufacture Technique, Yumimg Wang
Journal of Electrochemistry
Based on the difference of charge discharge charasteristies between Ni Cd and Ni MH battery, some appropriate manufacture technoque to improve the battery performances or to extend its service life are adopted
Surface Modifications Of Carbon Materials Used As Anode Of Lithium Ion Battery Ⅰ.Influences Of Oxidation And Reduction Pretreatment On Anode Performance, Shuhua Ma, Hanju Guo, Ji Li, Hongze Liang, Xiabin Jing, Fosong Wang
Surface Modifications Of Carbon Materials Used As Anode Of Lithium Ion Battery Ⅰ.Influences Of Oxidation And Reduction Pretreatment On Anode Performance, Shuhua Ma, Hanju Guo, Ji Li, Hongze Liang, Xiabin Jing, Fosong Wang
Journal of Electrochemistry
The influences of the trace oxygen containing functional groups on surface of carbon material on cell performance of carbon anode for lithium ion batteries were studied by means of the pretreament in various oxidant/reductant systems.The results showed that the rich oxygen containing functional groups impaired the cell performance of carbon material anode,and the reduction of these groups in quantity and oxidation degree can increase charge/discharge capacity and improve first charge/discharge efficiency.The reason was also discussed in the light of effects of surface organic groups on decomposition reactivity of electrolyte and formation process of surface passivating film.
The Current Distribution On The Anode Surface Of The Seale Oval Tubular Lead Acid Battery, Renao Gu, Jianlin Yao, Zhengfa Deng, Ru Sun
The Current Distribution On The Anode Surface Of The Seale Oval Tubular Lead Acid Battery, Renao Gu, Jianlin Yao, Zhengfa Deng, Ru Sun
Journal of Electrochemistry
The current distribution on anode surface of sealed lead acid batter under different discharge current and degree was studied by chemical analytical method for the first time. We can conclude that the current distribution is not even. The current density on the edge of the electrode surface and the electrode terminal are bigger than other areas, that is, there are edge effect and terminal effect, and these effect are more obvious when the discharge current is 100 A and degree is 100%.
A Study On Electrochemical Oxidation Of Reduced Nicotinamide Coenzyme Nadh In Organic Media, Fangzu Yang, Wuhuihuang Wuhuihuang, Xushukai Xushukai, Zhoushsomin Zhoushsomin
A Study On Electrochemical Oxidation Of Reduced Nicotinamide Coenzyme Nadh In Organic Media, Fangzu Yang, Wuhuihuang Wuhuihuang, Xushukai Xushukai, Zhoushsomin Zhoushsomin
Journal of Electrochemistry
The behaviour of electrochemical oxidation of the reduced nicotinamide coenzyme NADH on glassy carbon was studied and some kinetic parameters were measured by means of voltammometry in the N-dimethylformamide(DMF)and 1,4-dioxane media respectively. The eletrochemical oxidation of NADH shows completely irriversable both in the two solvents,and the diagnostic experiments support that the process involves a fast chemical step.The oxidation rate and the diffusion coefficient of N ADH in DMP are smaller than those in 1,4-dioxane,but the response current is more stable in DMF. The experimental results are discussed by solvent effects.
Studies On The Charge And Discharge Reaction Of Li/Lini_(0.3)Co_(0.7)O_2 Battery, Fupjng Zhang
Studies On The Charge And Discharge Reaction Of Li/Lini_(0.3)Co_(0.7)O_2 Battery, Fupjng Zhang
Journal of Electrochemistry
The charge and discharge reaction of Li/LiNi0.3Co0.7O2 battery have been studied by using CV,CT,XRD and GCP.It is shown that the discharge capacity of the cell reaches 120-140 mA·h·g(-1) in the 4.30-3.00 V in 1 mol/L LiClO4/PC electrolyte system. The discharge mechanism involve a two-step Li+ intercalation reaction. The thermodynamic data such as △G,△S,△H,of the reaction are given. Furthermore,the changes of the Dor σi of Li+ with its composition have been discussed.
Study On The Growth Process Of Lead Dioxide On Lead-Antimony Electrodes By Impedance Tracing Method, Guolin Wei, Hongxin Yang, Jiarong Wang
Study On The Growth Process Of Lead Dioxide On Lead-Antimony Electrodes By Impedance Tracing Method, Guolin Wei, Hongxin Yang, Jiarong Wang
Journal of Electrochemistry
The growth process of PbO2 formed by the oxidation of PbSO4 in the anodic film on lead-(1,3,5,7)wt%antimony electrodes was investigated with impedance tracing method of single frequency and the current-time transient method. The influence of antimony on this process was studied.The simulation curves obtained for capacity-time transients fit the experimental results very well.It has been shown that the mentioned growth process is a two-dimentional instantaneous nucleation and growth process,Antimony will inhibit the growth of PbO2 nucleus but enhance its nucleation.
An Esr Study Of Free Radicals In Electroreduction Process Of Allyl Alcohol, Jindong Zhang, Yafei Kuang, Shukun Huang, Naixian Xie
An Esr Study Of Free Radicals In Electroreduction Process Of Allyl Alcohol, Jindong Zhang, Yafei Kuang, Shukun Huang, Naixian Xie
Journal of Electrochemistry
Electrochemical-ESR technique with spin trap phenyl-t-butyl nitrone(PBN)was used to study the intermediates of electroreduction of allyl alcohol at platinized platinum electrode in acidic alcohol-aqua solution. Hydrogen and allyl group and(or)propyl group radicals were identified by a hyperfine spectrum of the radical adducts,and that provided a direct evidence for the presence of these radicals in the electroreduction of allyl alcohol.
A Study On Solid Polymer Electrolyte Fuel Cell, Hongfeng Xu, Ming Han, Baolian Yi, Xinge Zhang, Shanhai Ge
A Study On Solid Polymer Electrolyte Fuel Cell, Hongfeng Xu, Ming Han, Baolian Yi, Xinge Zhang, Shanhai Ge
Journal of Electrochemistry
Solid polymer electrolyte fuel cell(SPEFC)show promise of a high level of performance in the present fuel cell.In this paper,we report the method of SPEFC electrode preparation,and the effects of temperature,pressure and gas flow rate on the performance.
Status Of The Research And Development For Fuel Cell Technology Abroad, Naichao Li, Baolian Yi
Status Of The Research And Development For Fuel Cell Technology Abroad, Naichao Li, Baolian Yi
Journal of Electrochemistry
Status of the research and development for fuel cell technology abroad was overviewed,and at the aim of accelerating the research and development for fuel cell technology in China, the corresponding stategy for our country was recommended.
Electrocatalytic Oxidation Of Some C 2 Compounds(Alcohols, Aldehydes, And Carboxylic Acids) On A Pt/Sb Ad Electrode, Hong Li, Lincai Jiang, Xiong Jiang
Electrocatalytic Oxidation Of Some C 2 Compounds(Alcohols, Aldehydes, And Carboxylic Acids) On A Pt/Sb Ad Electrode, Hong Li, Lincai Jiang, Xiong Jiang
Journal of Electrochemistry
The electrocatalytic oxidation behavior of some C 2 compounds(alcohols, aldehydes and carboxylic acids) on a Pt/Sb ad electrode prepared in situ or ex situ UPD was investigated using pontential sweep and rotating disc electrode methods. It is confirmed that Pt/Sb ad electrode show the most electrocatalytical active to the oxidation of aldehyde functional group and only a little activity to the oxidation of hydroxyl group, but no activity for the oxidation of carboxyl group. The experimental results show that the activity of the Pt/Sb ad electrode prepared by ex situ UPD is higher than that prepared by in situ UPD. …
The Reduction Of Oxygen To Hydrogen Peroxide In An Acidic Trickle Bed Cell Using Graphite Chip Cathode, Zhaoe Lu, Guanyong Zhang, Tiangeng Zhong, Guonu Fang
The Reduction Of Oxygen To Hydrogen Peroxide In An Acidic Trickle Bed Cell Using Graphite Chip Cathode, Zhaoe Lu, Guanyong Zhang, Tiangeng Zhong, Guonu Fang
Journal of Electrochemistry
The authors investigated the electrochemical reduction of oxygen to hydrogen peroxide in 0.05 mol/L H 2SO 4 solution by the trickle bed electrode using graphite chip. The bed dimension was 14×5×0.6 cm. The current efficiency and the concentration of H 2O 2 in the catholyte were determined at various current strengths and various rates of adding the electrolyte. The proper current was 0.15 A. i.e. the current density was 2.1 mA/cm 2 vertical cross section area of the bed. The concentration of H 2O 2 reached 7×10 -3 mol/L with the current efficiency of 0.2. If the concentration of H …
Problems On The Study Of Anodic Films On Pb In Sulfuric Acid Solution(Ⅱ), Houtian Liu, Qunzhou Wang, Yongqin Wan, Weifang Zhou
Problems On The Study Of Anodic Films On Pb In Sulfuric Acid Solution(Ⅱ), Houtian Liu, Qunzhou Wang, Yongqin Wan, Weifang Zhou
Journal of Electrochemistry
The conditions for the growth of the different phases in the anodic Pb(Ⅱ) film on Pb in sulfuric acid solution were discussed.
Electrocatalytic Reduction Of Nitrite In The Presence Of Complex Of Cobalt(Ⅱ) And 1,10 Phenanthroline, Jian Tong, Xiaojun Dang, Hulin Li
Electrocatalytic Reduction Of Nitrite In The Presence Of Complex Of Cobalt(Ⅱ) And 1,10 Phenanthroline, Jian Tong, Xiaojun Dang, Hulin Li
Journal of Electrochemistry
The electrochemistry of cobalt(Ⅱ) 1,10 phenanthroline Co(Phen) 2+ 2 complex and its ability to electrocatalyze the reduction of nitrite were studied , we found that this complex could act as a catalyst in alkaline or neutral solution for nitrite reduction. We have investigated the effect of the complex composition on electrocatalytic ability. The effects of pH value, complex concentration, regeneration and activation of electrocatalyst on the catalytic current have been studied and discussed.
Research On Molten Carbnate Fuel Cell, Naichao Li, Baolian Yi, Lianying Kong, Enjun Zhang, Huaxin Lin, Tianxi Qu, Yingcai Cheng
Research On Molten Carbnate Fuel Cell, Naichao Li, Baolian Yi, Lianying Kong, Enjun Zhang, Huaxin Lin, Tianxi Qu, Yingcai Cheng
Journal of Electrochemistry
Cold-roll-milling has been evaluated as a technique for preparing porous LiAlO_2 matrices for use as a molten carbonate fuel cell electrolyte matrix. This technique produces reliable electrolyte structures with the following characteristics and advantages: ease of handling, uniform thickness, using nontoxic inorganic solvents, controlled pore size distribution, and ability to be impregnated with the alkali carbonate without fracrure.The Molren Carbnatod Fuel Cell(MCFC) was assembled from sintered Ni electrodes and LiAlO_2 electrolyte matrix, the electrode area is 28 cm￣2, the effect of operating conditions on cell performance was tested, it was found that the cell performance changed little with many times …
An Indirect Electrochemical Oxidation Of Toluene─Catalytic Effects Of Ag(Ⅰ) On Mn(Ⅱ)/Mn(Ⅲ) Couple Transition At Pt Electrode, Zhonghua Wang, Yunan Qu, Xingguo Yan, Qngmin Hua, Guacai Chen, Zhongquan Wang
An Indirect Electrochemical Oxidation Of Toluene─Catalytic Effects Of Ag(Ⅰ) On Mn(Ⅱ)/Mn(Ⅲ) Couple Transition At Pt Electrode, Zhonghua Wang, Yunan Qu, Xingguo Yan, Qngmin Hua, Guacai Chen, Zhongquan Wang
Journal of Electrochemistry
The Catalytic effects of Ag(Ⅰ) on toluene oxidation by Mn(Ⅲ) as well as the anodic generation of Mn(Ⅲ) were investigated. The rates of toluene oxidation were first order with respect to both Ag(Ⅰ) and Mn(Ⅲ). Ag(Ⅱ) formed on the surface of the platinum anode when Ag(Ⅰ) was present in the anolyte, which catalyic the Mn(Ⅱ) to Mn(Ⅲ) in solution.
Study Of The Calcium-Thionyl Chloride Cells, Baohong Zhang, Meng Chen, Yingdong Wang, Dongsheng Xu
Study Of The Calcium-Thionyl Chloride Cells, Baohong Zhang, Meng Chen, Yingdong Wang, Dongsheng Xu
Journal of Electrochemistry
The properties of CaCl_2 SEI covered on the ca electrode surface in thionyl chloride, the influence of various salts in thionyl chloride on the porformance of the Ca anede and carbon cathode, and the function of the additive CuCl_2 and CuBr_2 to cathode in the improvement of the cathode performance were studied by AC impedance, constant current discharge, and SEM. As a result,the Ca-SOCl_2 cell was able to discharge at 50 mA·cm￣(-2)and the capacity reached 17.5 mAh ·cm￣(-2).
The Inhibition Of Amphipathic S- And N-Containing Compounds On Carbon Steel Corrosion, Wei Xing, Yibin Shan, Du Guo, Tianhog Lu, Shiquan Xi
The Inhibition Of Amphipathic S- And N-Containing Compounds On Carbon Steel Corrosion, Wei Xing, Yibin Shan, Du Guo, Tianhog Lu, Shiquan Xi
Journal of Electrochemistry
Ordered monolayers of S- and N-containing amphipathic corrosion inhibitors were depoitod onto the surfaces of carbon steel electrode with super-molecular assembly technique. The effect of molecular aggregation of monolayers on carbon steel corrosion in 0. 05 mol dl￣(-3)H_2SO_4 and the mechanisms of these inhibitors were discussed in details. It was found that the transport of hydrated hydrogen ion to the surface of steel depends strongly on the inhibitor molecular aggregation in the monolayers.
The Influence Of Cathode Ingredients In Zinc Chloride Type Battery On The Discharge Ability, Shen Qi, Zhuang Biao
The Influence Of Cathode Ingredients In Zinc Chloride Type Battery On The Discharge Ability, Shen Qi, Zhuang Biao
Journal of Electrochemistry
The influence of cathodic powder ingredients in ZnCl_2 type heavy duty battery on the discharge ability has been studied, a suitable battery ingredients is founds.