Physical Sciences and Mathematics Commons^™

Supramolecular Coordination Networks Of S- And F-Block Metals Featuring The 1,8-Naphthalimide Tecton, Andrew Paul Leitner

Theses and Dissertations

The reactions of (S)-2-(1,8-naphthalimido)propanoic acid (HLala), and (S)-2-(1,8- naphthalimido)-3-hydroxypropanoic acid (HLser), protonated forms of ligands that contain a carboxylate donor group, an enantiopure chiral center and a 1,8-naphthalimide π...π stacking supramolecular tecton and in the case of HLser an alcohol functional group, with the appropriate alkali metal hydroxide followed by a variety of crystallization methods leads to the formation of crystalline K(Lala)(MeOH) (1), K(Lala)(H2O) (2), Na(Lala)(H2O) (3), KLser (4), CsLser (5) and CsLala (6). Each of these new complexes has a solid state structure based on six-coordinate metals linked into homochiral helical rod SBU central cores. In addition to the …

Spectroscopy And Chemometrics For Cultural Heritage And Forensics: Conservation Of Magnetic Tape By Identifying Degraded Polymer Signatures; And Characterizing The Chemiluminescent Reaction Of Luminol With Blood, Brianna Marie Cassidy

Theses and Dissertations

The first half of this manuscript focuses on the identification of degraded magnetic tape using attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) and multivariate statistics. For several decades before the digital era, magnetic tape was the dominant audio and visual recording medium. A majority of magnetic tapes contain polyester urethane (PEU) binders, which are known to degrade via hydrolysis, making the retrieval of recorded data difficult and at times impossible. Degraded tapes are currently identified through visual inspection followed by playback on vintage equipment. However, if degraded tapes are played, they are likely to stick and shed onto player …

Fast Methods For Variable-Coefficient Peridynamic And Non-Local Diffusion Models, Che Wang

Theses and Dissertations

In previous studies, scientists developed the classical solid mechanic theory. The model has been widely used in scientific research and practical production. The main assumption of the classical theory of solid mechanics is that all internal forces act through zero distance. Because of this assumption, the mathematical model always leads to partial differential equations, which meet with problems when describing the spontaneous formation of discontinuities and other singularities. A peridynamic model was proposed as a reformation of solid mechanics [40, 41, 43, 44, 45], which leads to a non-local framework that does not explicitly involve the notion of deformation gradients, …

A Survey Of The Kinetic Monte Carlo Algorithm As Applied To A Multicellular System, Michael Richard Laughlin

Theses and Dissertations

We explore the origins and implementation of the Kinetic Monte Carlo method on a system of cells suspended in a liquid media. The situation presented herein has applications in the emerging field of biofabrication, which may have lasting impacts in medical science. The theory behind the method is explained in detail, starting with its emergence in the 1960s, and two major improvements to the scaling of the method are presented, along with a restriction to a special case. Finally, we give the results of several simulations.

Comparing The Geography Of Environmental Justice Guidelines, Fish Consumption Waterbodies, And Land Use/Land Cover In South Carolina, Matthew James Neet

Theses and Dissertations

Environmental justice (EJ) grew out of the Civil Rights movement of the 1960s, as well as grass roots organizations during the 1980s and early 1990s. However, it was not until President William J. Clinton signed Executive Order (EO) 12898 in 1994 that EJ became an official governmental policy. With this directive, federal agencies made EJ part of their daily operations. EO 12898 had two overriding goals, the fair treatment and meaningful involvement of all populations. As part of these goals, minority, low-income, and native populations would be analyzed for any disproportionate and adverse impacts on human or environmental health. Despite …

Optical Second Harmonic Generation In The Batio3 Phase On Magnetically Aligned Multiferroic Nanofibers, Katia Gasperi

Theses and Dissertations

Multiferroic materials enable the exploration of electrical control of magnetic properties and vice versa. Their increasing interest is especially due to their potential applications in the industry of information storage. Thanks to recent progress in nanotechnology, they have also been found to have many other applications such as transducers and sensors, and they already occupy a unique place in the biomedical field. The objective of this project is to study multiferroic nanofibers made of cobalt ferrite CoFe2O4 (CFO) and barium titanate BaTiO3 (BTO) with a specific focus in the characterization of the ferroelectric phase. We researched the state of knowledge …

Applications Of Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy For Forensic Analysis, Zhenyu Lu

Theses and Dissertations

Blood stains, which are among the traces encountered most frequently at crime scenes, are important for potential extraction and amplification of DNA for suspect identification, as well for spatter pattern analysis to reveal a sequence of events. Attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) was used in detection of blood stains and age estimation because of signature absorbances in the mid-infrared region at 3300 cm-1 (Amide A), 2800-3000 cm-1 (Amide B), ~1650 cm-1 (Amide I), ~1540 cm-1 (Amide II) ,and 1200-1350 cm-1 (Amide III). Position and intensity shifts for amide peaks were observed due to aging changes occurring as …

The Mistastin Lake Impact Structure As A Terrestrial Analogue Site For Lunar Science And Exploration, Marianne M. Mader

Electronic Thesis and Dissertation Repository

The impact cratering record on the Moon is important for many reasons, from understanding early solar system chronology to probing the lunar interior. In order to maximize scientific return from future lunar missions, it is useful to: 1) study terrestrial impact craters to better understand impact processes and products, and 2) develop appropriate human and robotic exploration strategies aligned with geological goals.

This research shows that the intermediate-size Mistastin Lake impact structure, in northern Labrador, Canada, is an unparalleled lunar analogue site, which includes both an anorthositic target and an almost complete suite of impact lithologies, including proximal ejecta deposits. …

Natural Vs. Anthropogenic Sedimentation: Does Reducing A Local Stressor Increase Coral Resilience To Climate Change?, Francesca Fourney

HCNSO Student Theses and Dissertations

Corals face serious worldwide population declines due to global climate change in combination with direct anthropogenic impacts. Global climate change is difficult to manage locally, but policy makers can regulate the magnitude of local stressors affecting reefs. The objective of this experiment is to investigate if reducing sedimentation will enable reef corals to better endure global climate change. It has been shown that some coral species can handle climate change stress when provided with additional energy resources. Here I tested if the capacity of corals to cope with climate change can be improved when their ability to feed and photosynthesize …

The Our Florida Reefs Coastal Use Survey: An Online Survey To Support Stakeholder Management Recommendations For Southeast Florida, Amanda Rose Costaregni

HCNSO Student Theses and Dissertations

Coral reefs are an important resource world-wide. Unfortunately, coral reef conditions are declining in many areas due to both global and local stressors. The objective of this study was to survey stakeholders in southeast Florida to better understand reef use in the region. Stakeholders spatially identified where and how often they conducted their activities. These data were compiled and analyzed in GIS to determine spatial use patterns. Both location and intensity of use were analyzed to determine which areas may be under greater stress from recreational activities. It was found that reef use was not evenly distributed in the region …

Silver Nanoparticle Transport Through Soil: Illuminating The Governing Pore-Scale Processes, Ian L. Molnar

Electronic Thesis and Dissertation Repository

Engineered nanoparticles are widely used and will eventually be released to the subsurface environment and contaminate groundwater resources. However, the transport of engineered nanoparticles through soil is currently not well understood and cannot be modelled in any fundamental manner, placing groundwater resources at risk from nanoparticle contamination. This inability to accurately simulate transport is due to a lack of experimental information on nanoparticle interactions in the pore spaces of real soils.

This thesis illuminates the pore-scale processes governing silver nanoparticle transport through soil. In addition, it examines the influence of surface chemistry and grain/pore distributions on those processes. For the …

Vibrational Imaging At The Nanoscale: Surpassing The Diffraction Limit Using Tip-Enhanced Raman Spectroscopy, Farshid Pashaee

Electronic Thesis and Dissertation Repository

A deep understanding of the chemical composition of surfaces, interfaces or nanoscale structure with a high spatial resolution is an important goal in nanoscience and nanotechnology. Structural information can be collected using a variety of high spatial resolution techniques such as atomic force microscopy (AFM), scanning tunneling microscopy (STM), scanning electron microscopy (SEM), or transmission electron microscopy (TEM). Nevertheless, these methods do not offer molecular information such as vibrational spectroscopy techniques that allow one to collect molecular or lattice vibrations yielding to a precise picture of the molecular interactions in bulk materials as well as in surfaces and interfaces. Unfortunately …

A Comparison Of Infaunal Community Structure Between Pre- And Post Construction Sampling Of Artificial Fdot Rock- Pile Reefs In Broward County, Florida, Joan Lorraine Guerra

HCNSO Student Theses and Dissertations

Artificial reefs (ARs) are generally created with the intention of increasing local fish populations, biodiversity and corresponding habitat productivity, most often in support of commercial and recreational uses (e.g., diving and fishing). Numerous studies have investigated the communities that develop on artificial reefs. By contrast, far less research has focused on the surrounding infaunal communities, which represent critical trophic resources for many species that populate both natural and artificial reefs, and which may be affected both by AR deployment and the organisms that subsequently recruit to them. This study compared infaunal organism abundances at four sites between the inner and …

Bm3d Image Denoising Using Learning-Based Adaptive Hard Thresholding, Farhan Bashar

Electronic Thesis and Dissertation Repository

Image denoising is an important pre-processing step in most imaging applications. Block Matching and 3D Filtering (BM3D) is considered to be the current state-of-art algorithm for additive image denoising. But this algorithm uses a fixed hard thresholding scheme to attenuate noise from a 3D block. Experiments show that this fixed hard thresholding deteriorates the performance of BM3D because it does not consider the context of corresponding blocks. In this thesis, we propose a learning based adaptive hard thresholding method to solve this issue. Also, BM3D algorithm requires as an input the value of the noise level in the input image. …

Solvothermal Synthesis And Characterization Of Cuins2, Cuinse2 And Agins2 Nanoparticles From Single Source Precursors, Xuzhao Zhao

Electronic Thesis and Dissertation Repository

Nanoscale semiconductors have emerged as alternative candidates for the absorber layer in solar cells. Group 11-13-16 semiconductors have received a lot attention because of their direct band gap energies, high absorption coefficients and environmental friendly nature. To date, CuInS₂, CuInSe₂ and AgInS₂ semiconductors are three of the main ternary nanomaterials investigated. Besides the application in solar cells, these nanoscale semiconductors can also be applied in areas such as biosensors and hydro catalysis.

However, it is often challenging to prepare small-sized nanoparticles with uniform size and shape, especially for large scale production. In this thesis, the synthesis …

Connectivity Of Coastal And Oceanic Ecosystems: Pelagic Habitat Use By Juvenile Reef Fishes In The Gulf Of Mexico, Katie Bowen

HCNSO Student Theses and Dissertations

The assemblage structure, abundance, biomass, and vertical distribution of juvenile reef fishes in the offshore pelagic habitat of the northern Gulf of Mexico are described as part of the NOAA-supported Offshore Nekton Sampling and Analysis Program. The results presented here are from a 3-month, continuous sampling series in 2011 in which discrete depth strata from 0 to 1500 m were sampled using a 10-m² MOCNESS midwater trawl. This is the first study to examine pelagic juvenile reef fish distributions across the entire oceanic northern Gulf of Mexico seaward of the continental shelf break after the Deepwater Horizon Oil Spill. …

Adaptive Non-Local Means Using Weight Thresholding, Asif Khan

Electronic Thesis and Dissertation Repository

Non-local means (NLM) is a popular image denoising scheme for reducing additive Gaussian noise. It uses a patch-based approach to find similar regions within a search neighborhood and estimate the denoised pixel based on the weighted average of all the pixels in the neighborhood. All the pixels are considered for averaging, irrespective of the value of their weights. This thesis proposes an improved variant of the original NLM scheme, called Weight Thresholded Non-Local Means (WTNLM), by thresholding the weights of the pixels within the search neighborhood, where the thresholded weights are used in the averaging step. The key parameters of …

Morphological, Structural And Spectral Mapping Of The Central Uplifts Of The Alga And Verlaine Craters, Mars, Bianca D'Aoust

Electronic Thesis and Dissertation Repository

Impact cratering is a ubiquitous geological process that has shaped planetary bodies of the Solar System and beyond. While the impact cratering record on Earth has been poorly preserved, the Martian surface is characterized by a very old and cratered terrain. Central uplifts within complex impact craters are of particular interest as they expose deep-seated material, some of which may correspond to samples of the early Martian crust. Central uplift formation is, however, still a poorly understood geological process. This research investigated the origin of the exposed bedrock in the central uplifts of two Martian complex craters as well as …

Optical Flow At Occlusion Boundaries And In Occlusion Regions, Hua Meng

Electronic Thesis and Dissertation Repository

Optical flow is an important research area in the Computer Vision field, with the estimation of optical flow at occlusion still an open problem. Traditional approaches to this problem have either used additional terms in a regularization calculation (the flow still tends to “bleed” across occlusion boundaries) or a local least squares calculation that attempted to minimize the influence of two adjacent differently moving regions on the optical flow at points close to both regions (the flow still tends to be “corrupted” by the two regions). Ideally, optical flow for two adjacent differently moving regions should be distinct right up …

Faunal Composition And Distribution Of Pelagic Larval And Juvenile Flatfishes (Teleostei: Pleuronectiformes) In The Northern Gulf Of Mexico: Connectivity Between Coastal And Oceanic Epipelagic Ecosystems, Lacey Malarky

HCNSO Student Theses and Dissertations

Pleuronectiformes (flatfishes) occur throughout the global oceans, and have high ecological and commercial importance in some areas. Though much is known regarding life history, abundance, and distribution for the benthic adult stage of flatfish species, much less is known about the pelagic larval phases of flatfishes in the open ocean. Taxonomic uncertainty and limited sampling in the oceanic Gulf of Mexico contribute to data gaps with respect to the distribution of early life history stage of flatfishes in this region. Knowledge of the faunal composition, abundance and distribution of larval flatfishes, such as members of Bothus, which have extended …

Feeding Ecology Of The Invasive Lionfish (Pterois Spp.) And Comparison With Two Native Species: Schoolmaster Lutjanus Apodus (Walbaum, 1792) And Graysby Cephalopholis Cruentata (Lacepède, 1802), Jesse J. Secord

HCNSO Student Theses and Dissertations

Predator satiation and prey-size preference were determined for locally caught lionfish, schoolmaster, and graysby, all co-occurring predatory fishes in the Florida coral reef ecosystem. Individuals were evaluated by exposing them to wild-caught killifish over a gradient of four size classes (20 mm to 60 mm, in 10 mm increments). Preference trials extended over a 2 hr time period and were filmed to determine the order in which each prey item was consumed. Satiation was evaluated by exposing the predators to an equal number of excess prey items for 24 hrs and evaluating consumed prey weight. Lionfish and schoolmaster showed a …

An Investigation Of The Effects Of Chemical And Physical Weathering On Submerged Karst Surfaces, Bryan Charles Booth

USF Tampa Graduate Theses and Dissertations

Reports an investigation of the effects of chemical and physical weathering on submerged karst surfaces that pairs laboratory studies with computer modeling studies. The first study attempts to quantify the production of carbonate fines; soluble sediments produced by the incomplete dissolution of karst minerals during chemical weathering. Results show carbonate fine production in relation to dissolutional action; Chalk: 42.8%; Coquina: 2.6%; Dolomite: 3.1%; Gray Limestone: 4.8%; Ocala Limestone: 3.1%; Shell Limestone: 6.1%; Travertine: 8.6%. Due to the use of hydrochloric acid as opposed to carbonic acid these results may not be fully valid for application to natural speleogenic processes. The …

Gigapan Education, Marissa Morgan

Honors Theses

Secondary-school students and teachers need a safe, secure website where they can experience the life of their peers around the world through GigaPan panoramic images. Using a simple point and shoot camera, students can create deep-zoomable panoramas called GigaPans. A Ruby on Rails website was created to provide a location and interface for sharing and discussing these GigaPan panoramas between students and teachers across the globe. By sharing experiences and culture through this technology, the website aims to create a community of technologically and culturally aware young people.

Surface Reconstruction From Noisy And Sparse Data, Mark A. Brophy

Electronic Thesis and Dissertation Repository

We introduce a set of algorithms for registering, filtering and measuring the similarity of unorganized 3d point clouds, usually obtained from multiple views.

We contribute a method for computing the similarity between point clouds that represent closed surfaces, specifically segmented tumors from CT scans. We obtain watertight surfaces and utilize volumetric overlap to determine similarity in a volumetric way. This similarity measure is used to quantify treatment variability based on target volume segmentation both prior to and following radiotherapy planning stages.

We also contribute an algorithm for the drift-free registration of thin, non- rigid scans, where drift is the build-up …

The Effects Of Petroleum Pollutants On Sea Urchins Reproduction And Development, Kellie C. Pelikan

HCNSO Student Theses and Dissertations

Disturbances, such as mass pollution events, threaten the health of vulnerable ecosystems. Recent media attention has focused on the devastating mass oil spills, but daily petroleum input from recreational and commercial ship bilge release has been overlooked. The focus of this study was the effect of petroleum products found in bilge water on fertilization success and larval viability of two sea urchin species, Lytechinus variegatus and Eucidaris tribuloides. Unlike other pollutant studies that have focused on sperm characteristics and concentrations, I chose to examine how egg integrity was compromised by petroleum products. Scanning electron microscopy revealed eggs were degraded when …

A New Technique For Interpreting Depolarization Measurements Using The Crl Atmospheric Lidar In The Canadian High Arctic, Emily M. Mccullough

Electronic Thesis and Dissertation Repository

Linear depolarization measurement capabilities were added to the CANDAC Rayleigh-Mie-Raman lidar (CRL) at Eureka, Nunavut, in the Canadian High Arctic. This upgrade enables inferences of the phases (liquid versus ice) of cold and mixed-phase clouds, including during polar winter. A rotating-polarizer module was installed in the lidar, and depolarization measurements were calibrated according to existing methods. An alternate calculation technique, using the lidar's existing visible Rayleigh elastic channel in combination with the new rotating polarizer channel, was developed. A detailed mathematical description of both methods and their calibrations is presented. The new method is superior to the traditional method for …

Recent Advances In Accumulating Priority Queues, Na Li

Electronic Thesis and Dissertation Repository

This thesis extends the theory underlying the Accumulating Priority Queue (APQ) in three directions. In the first, we present a multi-class multi-server accumulating priority queue with Poisson arrivals and heterogeneous services. The waiting time distributions for different classes have been derived. A conservation law for systems with heterogeneous servers has been studied. We also investigate an optimization problem to find the optimal level of heterogeneity in the multi-server system. Numerical investigations through simulation are carried out to validate the model.

We next focus on a queueing system with Poisson arrivals, generally distributed service times and nonlinear priority accumulation functions. We …

Social Learning Systems: The Design Of Evolutionary, Highly Scalable, Socially Curated Knowledge Systems, Nolan Hemmatazad

Student Work

In recent times, great strides have been made towards the advancement of automated reasoning and knowledge management applications, along with their associated methodologies. The introduction of the World Wide Web peaked academicians’ interest in harnessing the power of linked, online documents for the purpose of developing machine learning corpora, providing dynamical knowledge bases for question answering systems, fueling automated entity extraction applications, and performing graph analytic evaluations, such as uncovering the inherent structural semantics of linked pages. Even more recently, substantial attention in the wider computer science and information systems disciplines has been focused on the evolving study of social …

Methodology For Generating Simplified Cross Section Data Sets For Neutron Transport Calculations, Thomas Jay Harrison

Doctoral Dissertations

Neutron shielding problems involve radiation transport calculations over a wide range of energies. Fission neutrons have initial energy on the order of MeV, fusion neutrons have initial energy on the order of 10s of MeV, and space-origin neutrons have initial energy on the order of 100s of MeV or higher. Shielding calculations must track the neutrons from their initial energies until they are no longer of interest; for deep-penetration neutrons, this final energy can be on the order of eV before the neutron is no longer tracked. Thus, for deep-penetration space radiation shielding problems, the calculation may require tracking the …

Terahertz Radiation From High-Temperature Superconducting Bscco Mesas Of Various Geometries, Daniel P. Cerkoney

HIM 1990-2015

The purpose of this thesis is to examine the radiation from high-temperature superconducting mesas of Bi2Sr2CaCu2O8+ (BSCCO). This is motivated by the need for coherent sources of continuous wave terahertz (THz) emission capable of radiating practically in the THz frequency band. As BSCCO has been shown to be tunable from 0.5–2.4 THz (i.e., through the entire socalled terahertz gap centered about 1 THz), and has a higher peak operating temperature near 1 THz than most alternative sources, it is a good candidate for imaging and spectroscopy device applications [1]. When a static DC voltage is applied to a BSCCO mesa, …