Physical Sciences and Mathematics Commons^™

Determination Of The Internal Rotational Energy Of Gaseous 1,2-Dichloroethane In An Argon Matrix Using Fourier Transform Spectroscopy, Susan Lynn Clarke

Chemistry & Biochemistry Theses & Dissertations

A sample cell and delivery system for rapid matrix isolation of gas mixtures at constant gas temperature was designed and evaluated. The rotational energy differences of 1,2-dichlorosthane and of its deuterium compound wars then determined to test this technique.

The rotational energy barriers calculated from Boltzman plots of ths gases at different temperatures were; 1.21 + 0.38 keel/mole, 1.33 + 0.70 Real/mole, and 1.12 + 0.45 kcal/mole for the CH2 wagging„ C-Cl stretching and CD₂ wagging modes respectively. These values were in good agreement with previously published values.

These results allowed evaluation of this apparatus and experimental design and …

Characterization Of Trihalomethane Formation From Proteins In Chlorinated Water, Robert Aaron Kravitz

Chemistry & Biochemistry Theses & Dissertations

Traditionally humates have been considered the most significant precursor in the formation of trihalomethanes in finished drinking water. This study investigates another potential precursor, namely proteins. The chlorination of aqueous protein solutions yields significant levels of trihalomethanes in terms of the maximum contaminant level (MCL) of 0.100 mg/L imposed by the USEPA. Molar yields for several proteins were determined. The average yield per unit of organic carbon was 0.5% as compared to 0.8% for a humic acid studied. A model protein, bovine serum albumin, was studied extensively to ascertain the effects of total organic carbon, chlorine dose, and time on …

Triple Trigonometric Series And Their Application To Mixed Boundary Value Problems, Gordon Melrose

Mathematics & Statistics Theses & Dissertations

In this dissertation the author investigates some triple trigonometric series which occur in the solution of mixed boundary value problems in elasticity and potential theory. By choosing a suitable integral representation for the sequence of unknown constants, the problem is reduced to solving a singular integral equation of the first kind. Twenty four cases in which the integral equation can be solved in closed form are discussed in detail.

In later chapters, the application of triple trigonometric series to problems in physics and engineering is demonstrated and closed form solutions for the physical parameters of interest are obtained.

Estimating The Parameters Of Truncated Distributions, Mukul Mohan Mittal

Mathematics & Statistics Theses & Dissertations

The problem considered here is the estimation of the parameters of some special truncated distributions. If the sample observations are restricted to the interval {O, T} with T known, then it is well known in the literature that the method of maximum likelihood fails to provide a finite estimate, for the mean of an exponential distribution, whenever the sample mean is greater than T/2 (Deemer and Votaw, 1955, Ann. Math. Statist. 26, 498-504). Not so well known is the nonexistence of the maximum likelihood estimator (m.l.e.), under certain conditions, for the scale parameter of a gamma distribution from a truncated …

Fourier Series Analysis Of The Relationship Of Morphologic Variations And Bathymetry In Recent Bolivina (Foraminiferida) From The Northwestern Gulf Of Mexico, Anthony Cavedo Gary

OES Theses and Dissertations

Automated video digitization and closed-form Fourier series analysis were used to investigate the applicability of benthic foraminiferal test morphology for paleo-bathymetric/paleoenvironmental reconstructions. Sample relationships and harmonics with the greatest power for discriminating between samples were determined using canonical discriminant analysis. Samples were eleven short cores obtained from the northwestern Gulf of Mexico. Three species of Bolivina were analyzed, B. albatrossi, B. lowmani, and B. subspinescens.

Results show populations of Bolivina albatrossi from the upper bathyal and upper-middle bathyal zones to have more triangular tests and lobulate chambers than lower-middle and lower bathyal zone populations. Specimens of Bolivina subspinescens …

The Spatial And Temporal Distribution Of The Larvae Of Sympatric Pagurid Hermit Crabs (Decapoda, Anomura) In Virginian Estaurine And Coastal Waters, Philip Wesley Sadler

OES Theses and Dissertations

Thirteen stations were occupied at two - week intervals from May through September 1980 within the York River, lower Chesapeake Bay depths encompassing the entire water column.

Three species of pagurids were identified: Pagurus longicarpus, P. pollicaris, and P. annulipes. The larvae of P. annulipes had not been previously identified from Virginian waters. The shapes of the antennae of P. pollicaris and P. annulipes weredistinctive, allowing rapid identification of these larvae. The shapes of the uropods were found to be useful in distinguishingthe glaucothoe· of P. longicarpus from P. annulipes. The larvae of these species …

Alternating Current Studies And Kinetic Analysis Of Valinomycin Mediated Charge-Transport Through Lipid Bilayer Membranes, Kenneth Lee Cox

Dissertations and Theses

In this study we have investigated the frequency dependence of bilayer lipid membranes for a series of glycerylmonoolein/n-decane bilayers in various aqueous ionic solutions containing the ionophore valinomycin. Reliable values of membrane capacitance and conductance were obtained over the frequency range 0.2 - 200 KHz using an automatic balancing bridge under the control of a microprocessor unit. The admittance data was then normalized and curve-fitted to produce relaxation times and amplitudes from which the kinetic rate parameters, as deduced from a single slab dielectric membrane model, were calculated. These ac experimental rate constants were then compared with those obtained from …

The Prospects Of The Kra Canal, Pannarai Chuapibul

Theses and Major Papers

The controversies over the prospects of the Kra Canal persuade me to write my major paper about it. Ever since the Thai government rejected the proposals for construction of the canal, the press has criticized that the actual reason why the government rejected the canal proposals was because of its fear of the irredentist movement with complete disregard of the enormous benefits of raising our balance of payments and standard of living. Nevertheless, there must be other important reasons. My opinions, which do not reflect those of the Thai government are based on problems of sources of capital, advantages and …

The Magnitude Of Charge Effects On The Fluorescence Quenching Of Peptidyl Tryptophan By Iodide, James L. Danziger

Honors Theses

The magnitude of charge effects on the quenching of tryptophan containing peptides by Iodine is compared for those peptides containing a positvely charged tryptophan to those peptides containing a negatively or uncharged tryptophan.

The Development Of An Optical Ph Sensor Based On Fluorescence, Kimberley Ann Forbes

Honors Theses

We are interested in developing optical pH sensors based on the fluorescence of an immobilized fluorophor confined on the end of a bifurcated fiber optic. Such optical pH sensors have several potential advantages: they should be inherently less sensitive to electrical noise than conventional pH electro1es, they require no reference electrode, and they make possible remote measurements. The fluorophors evaluated are bound electrostatically to an ion exchange membrane which is then attached to the common end of a bifurcated fiber optic, The fluorophor is excited through one arm and the fluorescence emission is passed through the other arm of the …

The Preparation Of Cyclic Organic Carbonyl Compounds From Ƞ5-Cyclopentadienyltetracarbonylvanadium And Substituted Acetylenes, Ronald C. Newbold

Honors Theses

Studies on the reactivity of many transition metal carbonyl complexes with various acetylenes have generated significant interest in the field of organometallic chemistry, but little effort has been put forth to make use of these compounds as genuine organic reagents. Most metal carbonyl compounds generate both organic and organometallic products, where oxidative cleavage becomes necessary to obtain the organic moiety. (35-c5H5)v(CO)4 is an oxygen-sensitive carbonyl complex which has been shown to thermally react with bis-(pentafluoro­phenyl)acetylene to produce cyclic carbonyl compounds in high yield, particularly the quinone derivative, with few organometallic products. The thermal reactivity of (35-c5H5)v(CO)4 is characterized with various …

Determination Of Aldehydes In Ambient Air By High Performance Liquid Chromatography With Fluorescence Detection, Carol B. Berman

Honors Theses

Two methods for the determination of aldehydes in ambient air were investigated. The methods involved derivatization of the aldehydes by 2-diphenylacetyl-1,3-indandione-1-hydrazone (DAIH) and 1-dimethylaminoaphthalene-5-sulfonylhydrazine (dansylhydrazine) in acetonitrile solution. The deriviatives were then separated by high performance liquid chromatography and detected and quantified by flourescence detection. The DAIH method was found to be unsuitable and was therefore abandoned. The dansyl hydrazine method was found to be a potentially uncomplicated, rapid, and senstitive procedure for the detection of aldehydes.

Conformational Energy Calculations On Valinomycin, Rachel J. Cohen

Honors Theses

The antibiotic action of the ionophore valinomycin is a result of its ability to preferentially bind potassium ions and transport them across cellular membranes. Complexation is solely due to the molecular structure of this cyclic depsipeptide. In solution, the molecule exists in different conformers depending upon solvent polarity. Exact knowledge as to the structure of valinomycin in the aqueous and lipid cellular layers is thus difficult to determine. Many spectral studies of valinomycin have been undertaken utilizing a variety of instrumental methods and conformations existing in different solvents have been proposed. We have performed energy minimization procedures on these structures. …

Chronic Respiratory Disease Symptom Effects Of Long-Term Cumulative Exposure To Passive Tobacco Smoke And To Ambient Levels Of Tsp, Oxidants, So2, And No2 In Southern California, Gary L. Euler

Loma Linda University Electronic Theses, Dissertations & Projects

To assess risk of chronic respiratory disease symptoms due to long-term exposure to the ambient levels of TSP, oxidants, SO2 and NO2 in photochemical air pollution, symptoms were ascertained using NHLBI questions on 8,572 Southern California Seventh-day Adventist, nonsmokers, 25 years and older, who lived eleven years or longer in their 1977 residential area. Tobacco smoke, active and passive, and occupational exposures were measured by questionnaires, as well as lifestyle characteristics relative to pollution exposure such as time spent outside and residence history. A pulmonary function feasibility study was done on a subsample of 86 women 50-64 years of age …

The Effect Of Dietary Alpha - Linolenic Acid On Apparent Risk Factors Of Cardiovascular Disease, Kelvin D. Lindbeck

Loma Linda University Electronic Theses, Dissertations & Projects

Eight healthy male lacto-ovo-vegetarian subjects averaging 28.0 ± 3.6 years of age (22 to 53 years) were fed a diet rich in α-linolenic acid (18:3 ω 3) for four weeks. Arterial blood pressure and body weight were recorded each week. Plasma 6-keto-prostaglandin F_1α (6-keto- PGF_1α ), thromboxane B₂ (TXB₂), total cholesterol, triglyceride, and total phospholipid fatty acid composition were analyzed at 0, 2 and 4 weeks.

Systolic blood pressure increased significantly between weeks 0 and 1 (106.5 ± 2.7 mmHg to 114.0 ± 3.7 mmHg; p < 0.003), but decreased to 107.3 t 2.6 mrHg (p < 0.02) at week 2. There was an insignificant increase in both systolic and diastolic blood pressures after four weeks. There was no significant change in either total cholesterol or triglyceride levels during the four weeks.

Plasma 6-keto-PGF_1α levels increased significantly from 60.13 ± …

The Microstructure Determination Of Poly(B-Pinene), Kevin G. Perrigno

Honors Theses

The microstructure of poly(B-pinene) was determined through analysis of pyrolysis products.

Synthesis And Spectral Studies Of Amides Of 9-Anthroic Acid, Juliana Rodgers

Honors Theses

The fluorescence energy, shape of the fluorescence spectrum, and the fluorescence efficiency of 9-anthramide (9-CONH2) and N,N-diethyl-9-anthramide (9-CONEt2) have been investigated as a function of solvent. For the 9-CONH2, the Sl energy decreases and the fluorescence spectra become structureless at the polar and nonpolar extremes of the solvent scale. This unusual solvent-dependent fluorescence behavior for 9-CONH2 is explained by a significant geometry change subsequent to excitation, whereby the exocyclic group rotates about the anthracene rings. In contrast, 9-CONEt2 shows solvent-independent behavior. The Sl energy generally remains constant and the fluorescence spectra show well-defined vibrational structure in a wide variety of …

Detection And Quantification Of Atmospheric Carbonyl Compounds, Peter Gerard Schulam

Honors Theses

Ambient air aldehyde analysis was performed in Schenectady, NY. The Technique, as prescribed by Kuntz et. Al. (7), entailed the trapping of the volatile aldehydes as their 2,4-dinitrophenylhydrazone derivatives in an acetonitrile solution. The derivatives were then separated on a reversed phase HPLC column and detexted by UV absorption at 254 and 360 nm., simultaneously. The air in Schenectady was found to contain formaedehyde and acetaldehyde at concentrations which ranged from .70 to 30.5 ppb and below that of detection to 1.6 ppb, respectively. Formaldehyde's daily average in Schenectady was 7.6 ppb. The formaldehyde and acetaldehyde levels at Whiteface Mtn. …

Palynology And Age Of The Alvord Creek Formation, Steens Mountain, Southeastern Oregon, Stephen F. Barnett

Loma Linda University Electronic Theses, Dissertations & Projects

The age of the Alvord Creek Formation of Steens Formation, southeastern Oregon, has been a center of controversy since Axelrod's 1944 paleobotanical assignment of a Lower Pliocene age to the tuffaceous leaf-bearing shales. This date varies from earlier determinations by Chaney and MacGinitie that the flora was Mascall (Upper Miocene) equivalent. However, it is more sharply contradicted by the report of a Middle Miocene (Barstovian) fauna in the apparently overlying Steens Basalt and by a 21.3 m.y. radiometric date obtained on a basalt flow 61 meters above the leaf-bearing beds.

Palynomorphs recovered from three exposures of the leaf-bearing beds show …

Third Molar Eruption Prediction, Michael L. Jacobsen

Loma Linda University Electronic Theses, Dissertations & Projects

The diagnosis and treatment of third molars has often been cited as a special problem to the orthodontist. If the prognosis of third molars could be determined, orthodontic treatment could progress on a more positive basis.

This study was designed to provide a method of deciding whether developing third molars will erupt or become impacted.

Records from 130 orthodontically treated cases of Dr. Fredsall⁸ were studied. Several factors were evaluated and measured using the patients' cephalometric radiographs.

The actual fate of the third molars were recorded in the hope it could be used to predict what to expect from …

Measuring The Effectiveness Of Patient Teaching In Postpartum Patients, Nancy Racine

Loma Linda University Electronic Theses, Dissertations & Projects

[Abstract Not Included]

Quantitative Evaluation Of Substituent Effects On Stabilization Energies Of Strained And Unsaturated Molecules, Tyler Arthur Stevenson

Theses

Thermodynamic stabilization energies are presented for a series of monosubstituted vinyl, cyclopropyl, ethynyl, and phenyl compounds. The energies are calculated using ab initio molecular orbital calculations at the 4-31G level, and also with published experimental heat of formation data. Correlation analyses are then attempted with the dual substituent parameter approach with the stabilization energies. The analyses are also attempted with a triple-parameter approach using Topsom's theoretically calculated X, F, and Ro constants. Among the findings are the facts that π-donating substituents correlate well, while π-accepting substituents do not. Indications of the relative sensitivities of hydrocarbon frameworks to substituent electrostatic and …

Synthesis Of Cyclobutenyl Ketals, Atef Z. Boulos

Theses

A series of dialkoxy derivatives of N,N'-di-tert-butyl-2-butylamino-3,3-dichloro-4-dichloromethylene cyclobutenyl carboxamidinum chloride, were prepared by dissolving either Na+ or K+ alkoxide in the appropriate alcohol, or by treatment with potassium hydroxide in the appropriate alcohols. Thus, the dimethoxy, diethoxy, di-isopropoxy, di-n-butoxy, di-tertbutoxy derivatives were obtained.

Derivatives Of Trifluorovinylsulfur Pentafluoride And F-(Tert-Butyl) Hypochlorite, Jo Ann Marie Canich

Dissertations and Theses

Trifluorovinylsulfur pentafluoride dimerizes to (SF₅CFCF₂)₂ in the presence of cesium fluoride. Two derivatives of trifluorovinylsulfur pentafluoride, SF₅CF(CF₃)C(O)F and SF₅CF(CF₃)C(O)NH₂, were used to prepare the new compounds, SF₅CF(CF₃)CO₂H and SF₅CF(CF₃)CN, respectively. The first was prepared by reacting the SF₅-acid fluoride with water, while the second involved the abstraction of water from the SF₅-amide using P₄O₁₀. The attempted preparation of a bis-pentafluorosulfur ketone and a pentafluorosulfur containing acid anhydride …

The Emerging Regime Of Islands As Archipelagic States, Frank Gable

Theses and Major Papers

This essay will discuss the significance of islands as archipelagos, i.e. any two or more islands identified politically as one entity. Within the body of this report will be references regarding the historical background to archipelagos and how they emerged into international topics of law. Further, the differences international law affords coastal archipelagos as opposed to outlying mid-ocean archipelagos will be interpreted. These differences include, for instance, the design of baselines used to enclose territorial waters. As the paper progresses, the reader will being to see how the Third United Nations Conference on the Law of the Sea (UNCLOS (III) …

Coral Reef Islands And Their Problems, Peter C. Schroeder

Theses and Major Papers

Small islands and in particular those more or less dependent on their reefs as a resource were often self-contained units, maintaining a fragile equilibrium in which even small changes could and have wrought fatal disturbances. The pressures of the modern world have endangered these vulnerable units economically, socially, and biologically. In all instances the "'population factor has played an important role. Coral reef islands appear to be more susceptible to the side effects of rapidly growing modernization than other types of islands. No clear answer or solution to this problem can be given but recognition of the threats to them …

Geology, Alteration And Mineralization Of A Silicic Volcanic Center, Glass Buttes, Oregon, Michael James Johnson

Dissertations and Theses

Glass Buttes, a Pliocene silicic volcanic complex within the High Lava Plains province of Oregon, was erupted approximately 5.0 to 5.8 million years ago. Geologic mapping revealed that the eastern portion of the complex is underlain by rhyolitic glass domes, flows and rare pyroclastis flows. Basalt flows are interlayered with and onlap the silicic glass. Younger basalt flows, erupted from local vents, overlie silicic glass and onlapping basalts.

The eastern end of Glass Buttes is hydrothermally altered at the surface; a weak geothermal anomaly coincides with the altered areas. Alteration, localized by northwest trending normal faults, occurs primarily as opalite …

Structure And Petrology Of Tertiary Volcanic Rocks In Parts Of Toms Cabin Spring And Lucin Nw Quadrangles (Box Elder Co.), Utah, Bruce Edward Scarbrough

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

A series of late Tertiary rhyolitic and dacitic flows, domes, and minor pyroclastic rocks form an elongate volanic mass along the northwestern Utah-northeastern Nevada border. The structure of the flow banding and the linear arrangement of vents indicate that the mass represents a multi-sourced extrusive complex which erupted through many fissure-type conduits. A 39 km² area at the southern end of the mass was studied in detail in order to gain a better understanding of the eruptive nature and history of these Tertiary volcanic rocks. Age dating reveals that volcanism in the study area was episodic, and covered a …

Unbalanced Analysis Of Variance Comparing Standard And Proposed Approximation Techniques For Estimating The Variance Components, James P. Pugsley

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This paper considers the estimation of the components of variation for a two-factor unbalanced nested design and compares standard techniques with proposed approximation procedures. Current procedures are complicated and assume the unbalanced sample size to be fixed. This paper tests some simpler techniques, assuming sample sizes are random variables. Monte Carlo techniques were used to generate data for testing of these new procedures.

Photoaffinity Labeling Of The Antimycin Binding Site In Rhodopseudomonas Sphaeroides, Emily Wilson

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The purpose of this study was to identify the site of interaction of antimycin with the ubiquinone-cytochrome b-c1 oxidoreductase in the photosynthetic bacteria, Rhodopseudomonas sphaeroides. To accomplish this goal, three areas of research were undertaken: the synthesis of a radiolabeled, photoaffinity analog of antimycin, identification of the inhibitory characteristics of this analog, and the photoaffinity labeling of the antimycin binding site. All three areas were accomplished.

The major finding of this study was the identification of an 11,000 dalton polypeptide as the predominantly labeled protein. Although this polypeptide was not exclusively labeled, it was consistently labeled and showed competition …