Use Of Carbonation For Treatment Of Coal Mine Drainage To Increase Limestone Dissolution And Generate Alkalinity, Dietrich Henry Kuhlmann Iv

Graduate Theses, Dissertations, and Problem Reports

Abstract

Use of Carbonation for Treatment of Coal Mine Drainage to Increase Limestone Dissolution and Generate Alkalinity

Dietrich Kuhlmann IV

Anoxic limestone drains (ALDs) are a common component used within passive treatment systems for coal mine drainage (CMD). Contact between limestone aggregate and CMD results in limestone dissolution, producing carbonate alkalinity. Though ALDs are one of the least expensive CMD treatment technologies, alkalinity generation is limited by limestone solubility. This necessitates a long retention time (>12 hours) and sometimes results in net acidic effluent which requires additional alkalinity generation steps downstream. One way to increase calcite dissolution and alkalinity …

Echoed Sites And The Unknowable Object, Joseph Canizales

MFA in Visual Art

This thesis will discuss the expanded field of sculpture, simulacra, digital technology, and two terms I’ve devised: the unknowable object, and echoed sites. Within these two terms, I’m concerned with the complicated relationship between humans and geology and how we extract material from the ground without reflecting on the geologic history of the site. In echoed sites I create sculptures with and without a geologic site or object, by way of digital technology. These forms display two states paradoxically in balance, where what’s presented leaves more questions than answers. Thus, as part of echoed sites, exists the unknowable object. …

Early Mississippian Ocean Anoxia Triggering Organic Carbon Burial And Enhancing Late Paleozoic Ice Age Onset: Evidence From Uranium Isotopes Of Marine Limestones, Keyi Cheng

Earth and Planetary Sciences ETDs

The Early Mississippian (Tournaisian) positive δ¹³C excursion (or TICE) is one of the largest recorded in the Phanerozoic and the organic carbon (OC) burial associated with its development is hypothesized to have driven global cooling and increased glaciation. We are testing the hypothesis that expanded ocean euxinia/anoxia drove widespread OC burial and the TICE and we are testing this hypothesis using uranium isotopes (δ²³⁸U) of Lower Mississippian marine limestones from southern Nevada as a global seawater redox proxy.

δ²³⁸U trends record a prominent mid-Tournaisian negative excursion (~0.30‰ magnitude) lasting ~1 My. The lack of …

Modeled Affinity Constants For Phosphorus Adsorption And Desorption Due To Saltwater Intrusion, Yasemin Taşcı

USF Tampa Graduate Theses and Dissertations

It is important to understand the processes that regulate phosphorus (P) fluxes to coastal environments, because P is an important nutrient in coastal ecosystems. Phosphorus adsorbs to the surface of minerals in sediment and bedrock, and an influx of seawater can cause some of that P to desorb, raising the P concentration of ambient water. Although seawater-induced P desorption is thought to be an important source of P to coastal environments, the chemical reactions that underlie it have not been established. Previous work provides some relevant surface reactions and associated affinity constants between various aqueous P species and the surface …

Facies Analysis, Sedimentary Petrology, And Reservoir Characterization Of The Lower Triassic Sinbad Limestone Member Of The Moenkopi Formation, Central Utah: A Synthesis Of Surface And Subsurface Data, Kristopher Michael Powell

Theses and Dissertations

Lower Triassic strata in the Wellington Flat and Tully cores reflect a lateral transition from shallow water strata (Wellington Flats core) to strata that indicate deposition on a relatively more distal, storm-dominated ramp (Tully core). The Sinbad Member, along with the upper part of the underlying Black Dragon Member and the lower part of the overlying Torrey Member (Moenkopi Formation), are composed of ten carbonate, siliciclastic and mixed carbonate/siliciclastic facies deposited on a west-facing ramp/shelf that reached maximum flooding during Smithian time. Individual beds and facies display a large degree of lateral homogeneity and regional persistence in the study area. …

Speleogenesis Of Critchfield Bat Caves And Associated Hydrogeology Of The Northern Edwards Aquifer, Williamson County, Texas, Ashley N. Landers

Electronic Theses and Dissertations

Karst development in the Edwards Aquifer has been significantly studied in the San Antonio and Barton Spring Segments; however, karst development remains poorly studied in the Northern Segment. Detailed characterization of the Northern Segment is vital for future water conservation because of increasing urban sprawl along the Interstate 35 corridor. The Northern Segment of the Edwards Aquifer consists of Lower Cretaceous strata of the Comanche Peak, Edwards, and Georgetown formations. The stratigraphy is dominated by Edwards Limestone as it is the only formation that crops out in the study area.

Karst, stratigraphic, GIS, and geochemical studies were conducted to evaluate …

Experimental Limestone Dissolution And Changes In Multiscale Structure Using Small- And Ultra Small- Angle Neutron Scattering, Chad Alan Novack

Masters Theses

Small angle neutron scattering (SANS), ultra-small angle neutron scattering (USANS), and backscatter electron (BSE) imaging, along with neutron computed tomography (NCT) were used in this study to experimentally quantify pore size, distribution, and connectivity of dissolved limestone geometries. Eight samples of Indiana limestone of two different initial permeabilities (2-4 mD and 70 mD ) [millidarcy] were reacted with HCl [hydrochloric acid] solutions at differing pH (2 and 4), and flow rates (0.1 and 10 cm³/min) [cubic centimeters per minute] to describe a broad range of parameters that affect limestone dissolution. NCT was first used to image the dissolution …

Carbon Isotope Variations Associated With A Middle Ordovician Karstic Unconformity, Patricia Suzanne Williams

UNLV Theses, Dissertations, Professional Papers, and Capstones

Large negative carbon isotope (δ¹³C) excursions have been documented from late Neoproterozoic-Paleozoic successions. These δ¹³C excursions have been widely used for regional and global stratigraphic correlation, particularly in strata with limited paleontological and radiometric age controls. Recent studies, however, argued that some negative δ¹³C excursions from stratigraphic record may have been resulted from meteoric/burial diagenesis, which commonly shifts both carbon and oxygen isotopes toward lower values. Testing the diagenetic origin of δ¹³C excursions in stratigraphic successions without independent stratigraphic framework has been difficult because it evolves into circular arguments about stratigraphic completeness …

Validity Of Holocene Analogs For Ancient Carbonate Stratigraphic Successions: Insights From A Heterogeneous Pleistocene Carbonate Platform Deposit, Colby Hazard

Theses and Dissertations

Observations of modern carbonate depositional environments and their accompanying depositional models have been used for decades in the reconstruction and interpretation of ancient carbonate depositional environments and stratigraphic successions. While these Holocene models are necessary for interpreting their more ancient counterparts, they inherently exclude important factors related to the erosion, diagenesis, and ultimate preservation of sediments and sedimentary structures that are ubiquitous in shallow marine carbonate environments. Andros Island, Bahamas is an ideal location to examine the validity of Holocene conceptual models, where geologically young (Late Pleistocene) limestones can be studied immediately adjacent to their well-documented modern equivalents. For this …

Economic Geology Of The San Bernardino Mountains, California, Nicolette Deannah Grill

Electronic Theses, Projects, and Dissertations

The San Bernardino Mountains are well known for their rich mining history, especially, gold in the mid-1800s and the current mining of one of the world’s largest deposits of high purity limestone. The purpose of this study was to compile new, current, and historical data of the major economic resources that are present and mining that has gone on in the San Bernardino Mountains. It is estimated that historical mining of the Holcomb Valley recovered $457,660,000 of gold or about 350,000 troy ounces based on samples collected for this study and 2013 gold price. The current major geologic resource is …

Subsurface Sequence Stratigraphy And Reservoir Characterization Of The Mississippian Limestone (Kinderhookian To Meramecian), South Central Kansas And North Central Oklahoma, Thomas Cahill

Graduate Theses and Dissertations

Both conventional and unconventional Mississippian reservoirs in the mid-continent are largely comprised of chert-rich carbonates of Osagean and Meramecan age. The conventional reservoir target is the Mississippian "chat," a high porosity, chert residuum interval found immediately beneath the Mississippian-Pennsylvanian unconformity. The unconventional reservoir target occurs in the lower porosity, cherty, mud-rich intervals that occur in the lower portion of the Mississippian succession.

There has been considerable debate surrounding the sequence stratigraphic interpretations, depositional models, and formation names applied to the reservoir intervals within the subsurface. Another major issue with regard to the subsurface is the stratigraphic position and origin of …

Taphonomic And Sedimentologic Study Of The Cretaceous Tepee Buttes Limestone, Hilary G. Close

Honors Papers

The Tepee Buttes methane seep deposits exist today as topographically defined limestone features in the surrounding Pierre Shale of the Campanian Western Interior Seaway. The present sloping surface has previously been assumed to be indicative of original seep structure, and biofacies were interpreted as roughly ringing a central vent core. Contradictory field observations in this study have prompted a more detailed taphonomic approach to the Tepee Buttes limestone, and certain depositional features such as reworked horizontal shell beds were noted and examined in detail for the first time. The results of a taphonomic and sedimentologic analysis reveal a complex history …

Sequence Stratigraphy Of The Bridal Veil Falls Limestone, Carboniferous, Lower Oquirrh Group, On Cascade Mountain, Utah: A Standard Morrowan Cyclostratigraphy For The Oquirrh Basin, David Joseph Shoore

Theses and Dissertations

The Bridal Veil Falls Limestone (lowest 400 meters of the Permo-Carboniferous Oquirrh Group) is well exposed on the flanks of Cascade Mountain (Wasatch Front and adjacent mountain ranges) near Provo, Utah. Because of its excellent exposure and location in the heart of the Oquirrh depocenter, this area was selected to develop a sequence stratigraphic framework for Morrowan rocks that may be applied throughout the Oquirrh basin (NW Utah and southern Idaho) as well as the adjacent Ely and Bird Springs troughs. Eleven partial to complete sections of the Bridal Veil Falls Limestone were measured along the west and north flanks …

Microstructures And Deformation In Some Fault Rocks From The Mcconnell Thrust At Mount Yamnuska (Alberta): Implications For Fluid Flow And Faulting And Cycles Of Strain-Hardening And Softening, Lowell Miyagi

Honors Papers

Fault rocks from the McConnell thrust consist of limestone mylonite, carbonate and shale cataclasites, and deformed sandstones. The limestone mylonite in the hanging wall mayor may not show different levels of cataclastic overprint. Just below these hanging wall rocks is a zone of comminuted material. This zone contains cataclasites that are produced by the mixing of hanging wall and footwall materials. Underneath this unit are the shale cataclasites of the footwall and beneath this are deformed sandstones that become progressively less deformed further from the fault zone. Based on microstructural evidence these rocks show cycles of mesoscopically brittle and ductile …

The Origin Of Brucite In Hydrothermally Altered Limestone Near Devil Peak, Nevada, Rhonda L. Knupp

UNLV Theses, Dissertations, Professional Papers, and Capstones

Open-space brucite was identified in veins crosscutting hydrothermally altered limestone near the Devil Peak rhyolite plug in southern Nevada. The brucite occurs with serpentine, calcite, chalcedony, hydromagnesite, dolomite, and clinochlore.

Brucite usually forms as a replacement mineral, but textural evidence indicates that the brucite at Devil Peak precipitated in open space. The presence of chalcedony in veins indicates the temperature of the hydrothermal fluid was <180^oC during and after mineral deposition. Thermodynamic modeling shows this temperature is too low for replacement brucite to form, thus the low temperature of alteration may be a factor in this unusual occurrence of …

Lithofacies Of The Pliocene-Pleistocene Lucayan Limestone, Great Abaco Island, Little Bahama Bank, Mary K. Mullen

OES Theses and Dissertations

Petrographic and sedimentologic analyses of eleven shallow subsurface cores (3 to 19 meters in length) from the Lucayan Limestone where it occurs along northeastern Great Abaco Island (little Bahama Bank) are used to delineate five carbonate lithofacies. The most prevalent lithofacies is a mottled, nonskeletal, peloidal packstone to grainstone. Other lithofacies include a rudstone, a laminated nonskeletal grainstone, a crossbedded grainstone and a mudstone-wackestone.

Cementation varies from poor to very well cemented core intervals. Cements observed included equant granular, equant blocky, drusy, meniscus, and needle fiber "whisker" cements. These cements reflect a variety of diagenetic environments such as the vadose, …

Depositional And Diagenetic History Of The Middle Ordovician Carbonates Of The Shenandoah Valley, Northern Virginia, Lynn Ellen Weyenberg

OES Theses and Dissertations

An examination of the Middle Ordovician carbonates in northwest Virginia has revealed a particularly sensitive record of deposition and subsidence. Two-hundred acetate peels from six measured stratigraphic sections in Shenandoah County, Virginia were examined to interpret the depositional and diagenetic history. Two major lithofacies have been recognized within the New Market Limestone and three have been recognized in the Lincolnshire Formation. These five lithofacies represent an overall transgressive sequence. This transgression was not uniform but paused several times to allow carbonate deposition to reach sea-level. These shoaling events suggest a slowly subsiding basin in this region. The carbonate rocks within …

Petrology Of The Middle Jurassic Twin Creek Limestone, Lincoln And Sublette Counties, Southwestern Wyoming, David R. Raubvogel

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The Twin Creek Limestone of Middle Jurassic age was studied in the Tunp, Salt River, and Wyoming Ranges in southwestern Wyoming. Modern carbonate environments and their ancient analogs were compared with information obtained from field study and petrographic analysis of samples of the Twin Creek Limestone in order to delineate environments of deposition, paleogeography, and diagenetic history.

Six major lithofacies were recognized: (1) carbonate mudstone; (2) carbonate mudstone breccia; (3) fossiliferous wackestone; (4) packstone-grainstone; (5) terrigenous mudstone; and (6) sandstone. These lithofacies were deposited in a variety of environments, including outer shelf platforms (carbonate mudstone and fossiliferous wackestone), oolitic sand …

Petrology Of The Middle Cambrian Blacksmith Formation, North-Central Utah, Howard William Hay Jr.

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The dolostones and dolomitic limestones of the Middle Cambrian Blacksmith Formation were studied in the Bear River and Malad Ranges and the Wellsville Mountains of north-central Utah. The depositional textures and sedimentary structures retained within the rocks form the basis of subdivisions of measured sections, interpretation of depositional paleogeography, and reconstruction of environments.

Other studies of modern carbonate environments and their ancient analogues provided the basis for interpretation of the depositional textures found within the rocks of the Blacksmith Formation. Four identifiable lithofacies were recognized within the study area. These facies include: (1) oolite shoal; (2) restricted lagoon; (3) low- …

Structural Geology Of Eastern Part Of The Malad Summit Quadrangle, Idaho, Jay Nevin Shearer

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The mapped area represents the eastern three-fourths of the Malad Summit Quadrangle, Idaho. It lies mainly in the Bannock Range of southeastern Idaho. The northern and southern margins of the area are 25.5 miles and 17.0 miles, respectively, north of the Idaho-Utah State Line.

The Caddy Canyon Formation of Late Precambrian age is the oldest exposed stratigraphic unit. The youngest unit, exclusively of Precambrian age, is the Mutual Formation. The Brigham Formation is considered to be of Late Precambrian to Early Cambrian(?) age. Younger formations of Cambrian to Silurian age are present. The Precambrian units, as well as the Brigham, …

Geology Of The Summer Ranch And North Promontory Mountains, Utah, O. Clair Adams

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The Summer Ranch and North Promontory Mountains have not been studied in detail geologically, although the surrounding mountains have been extensively investigated. Within the limits of this area, sedimentary rocks of Mississippian through Permian crop out. Sedimentary and volcanic rocks of Tertiary age are also exposed. Extensive Lake Bonneville deposits underlie the valleys and overlap the foothills.

The Elkhorn Mine Of Jefferson County, Montana, David D. Walker

Bachelors Theses and Reports, 1928 - 1970

In 1901, after yielding metals valued in excess of five million dollars, it was considered worked out. Since that time the mine has passed through the hands of several own­ers, none of whom have failed to realize a profit from it. Although at no time since its zenith did it ever regain its once great production, it did provide a livelihood for those who worked it. Now with the American Smelting and Refining Company interested in it, perhaps it will once again become an important producer.

Mineralogy Of The Silver King Mine Of Park City, Utah, Pierce D. Parker

Bachelors Theses and Reports, 1928 - 1970

Except for the early work of Boutwell and Irving, little has been published on the geology of the Park City mining district. For this reason and because of the availability of a selected suite of ores from the Silver King mine of this area, this writer chose the mineralogy of the Silver King mine as a senior thesis for the de­partment of Geology of the Montana School of Mines.

Faunal Studies Of The Sappington Sandstone Of Southwestern Montana, Howard E. Banta

Bachelors Theses and Reports, 1928 - 1970

The exact upper boundary of the Devonian of Mont­ana has long been a controversy, as is true of the Dev­onian-Mississippian contact in many other localities. In an effort to delimit the upper Devonian, various paleontologic studies have been made, more especially in the southwestern part of the state.

A Listing Of Montana Invertebrate Fossils And A Bibliography Of Montana Paleontology, Robert G. Ingersoll

Bachelors Theses and Reports, 1928 - 1970

The oldest system in which identifiable invertebrate fossils have been found is the Cambrian. The basal Cambrian formation found in Montana is the Flathead sandstone and quartzite of Middle Cambrian age. No fossils have been reported from this formation. Above the Flathead is the Wolsey formation composed of green fissile shale with sandy and limy members. This fossiliferous member of the Middle Cambrian is known in Northwestern Montana as Gordon, and in the Philipsburg quadrangle as the Silver Hill formation.

Studies Of Antimony Occurrence With Special Relation To Its Effective Extraction, San Jose Antimony Mines, Wadley, San Luis Potosi, Mexico, J. C. Archibald Jr.

Bachelors Theses and Reports, 1928 - 1970

The mines at San Jose which are within the Wadley unit are the largest antimony mines in Mexico. These mines produce more than half of the antimony produced by the company from its mining operations. Since the time of the author's connection with the company, a number of changes have been made in planning of development work, handling of labor, methods of mine development, cost improvement, and other problems inherent in the successful guidance of an operation.

Importance Of Unconformities To Oil Occurrence In Montana, Robert E. Evenson

Bachelors Theses and Reports, 1928 - 1970

Although the majority of geologic structures in Montana have been tested in the search for petroleum, only a few have been found to contain commercial quantities of either oil or gas, and with each successive dry hole, producers are becoming more and more wary of investing capital in new wells located on structural features alone. It is apparent that if new oil and gas fields are to be found in Montana, exploration must be done on the basis of some­thing other than structure, or combined with structure.

Fauna Of The Pilgrim Formation Of The South Boulder Creek Area In Southwestern Montana, John T. Eastlick

Bachelors Theses and Reports, 1928 - 1970

This paper, a study of the fauna of the Pilgrim formation at South Boulder Creek in southwestern Montana, represents a laboratory study of the fossil specimens collected by Dr. Alvin Hanson during the summer of 1949. The scope of investigation includes identification and classification of the faunas, their stratigraphic relationship and zonal subdivisions.

Structure Of Southwestern Montana, Donald W. Levandowski

Bachelors Theses and Reports, 1928 - 1970

Intrusions of granitic rocks on a large scale are commonly found in the central part of folded mountain systems. Igneous rocks, intrusive and extrusive, are widespread in the mountains of southwestern Montana. An examination of the structural pattern of this area indicates that the fold trends form a radial pattern. How and why this pattern formed and its relation to the igneous activity in the area have not yet been discussed in the literature.

The Christensen Sillimanite Deposit Southeast Of Dillon, Montana, Everett O. Bracken

Bachelors Theses and Reports, 1928 - 1970

The minerals sillimanite, kyanite, andalusite, dumortierite, and topaz comprise a group of minerals whose high alumina content and physical properties are particularly desirable in the manufacture of refractory products. Sillimanite is the least plentiful of the minerals of this group, and for this reason it is not used extensively at the present time. However, it would be very desirable to the refractory industry if a suitable domestic source of supply could be established.