Use Of Carbonation For Treatment Of Coal Mine Drainage To Increase Limestone Dissolution And Generate Alkalinity, Dietrich Henry Kuhlmann Iv

Graduate Theses, Dissertations, and Problem Reports

Abstract

Use of Carbonation for Treatment of Coal Mine Drainage to Increase Limestone Dissolution and Generate Alkalinity

Dietrich Kuhlmann IV

Anoxic limestone drains (ALDs) are a common component used within passive treatment systems for coal mine drainage (CMD). Contact between limestone aggregate and CMD results in limestone dissolution, producing carbonate alkalinity. Though ALDs are one of the least expensive CMD treatment technologies, alkalinity generation is limited by limestone solubility. This necessitates a long retention time (>12 hours) and sometimes results in net acidic effluent which requires additional alkalinity generation steps downstream. One way to increase calcite dissolution and alkalinity …

Echoed Sites And The Unknowable Object, Joseph Canizales

MFA in Visual Art

This thesis will discuss the expanded field of sculpture, simulacra, digital technology, and two terms I’ve devised: the unknowable object, and echoed sites. Within these two terms, I’m concerned with the complicated relationship between humans and geology and how we extract material from the ground without reflecting on the geologic history of the site. In echoed sites I create sculptures with and without a geologic site or object, by way of digital technology. These forms display two states paradoxically in balance, where what’s presented leaves more questions than answers. Thus, as part of echoed sites, exists the unknowable object. …

Early Mississippian Ocean Anoxia Triggering Organic Carbon Burial And Enhancing Late Paleozoic Ice Age Onset: Evidence From Uranium Isotopes Of Marine Limestones, Keyi Cheng

Earth and Planetary Sciences ETDs

The Early Mississippian (Tournaisian) positive δ¹³C excursion (or TICE) is one of the largest recorded in the Phanerozoic and the organic carbon (OC) burial associated with its development is hypothesized to have driven global cooling and increased glaciation. We are testing the hypothesis that expanded ocean euxinia/anoxia drove widespread OC burial and the TICE and we are testing this hypothesis using uranium isotopes (δ²³⁸U) of Lower Mississippian marine limestones from southern Nevada as a global seawater redox proxy.

δ²³⁸U trends record a prominent mid-Tournaisian negative excursion (~0.30‰ magnitude) lasting ~1 My. The lack of …

Modeled Affinity Constants For Phosphorus Adsorption And Desorption Due To Saltwater Intrusion, Yasemin Taşcı

USF Tampa Graduate Theses and Dissertations

It is important to understand the processes that regulate phosphorus (P) fluxes to coastal environments, because P is an important nutrient in coastal ecosystems. Phosphorus adsorbs to the surface of minerals in sediment and bedrock, and an influx of seawater can cause some of that P to desorb, raising the P concentration of ambient water. Although seawater-induced P desorption is thought to be an important source of P to coastal environments, the chemical reactions that underlie it have not been established. Previous work provides some relevant surface reactions and associated affinity constants between various aqueous P species and the surface …

Lithology And Depositional Environments Of A Portion Of The Clays Ferry Formation (Middle And Upper Ordovician) Exposed At Silver Creek, Madison County, Kentucky, Autumn Murray, Walter S. Borowski

EKU Faculty and Staff Scholarship

We measure, describe, and interpret a carbonate stratigraphic section within the Clays Ferry Formation (Middle and Upper Ordovician) cropping out in Madison County, Kentucky (USGS Kirksville 7.5” quadrangle). Outcrops are exposed within the bed of Silver Creek along Ky 876 (Barnes Mill Road) from ~100 m downstream of where a bridge crosses the stream, then upstream and upsection for a distance of ~300 m over several sets of falls until bedrock exposure becomes sporadic to absent. We sampled the stratigraphic section at approximately half-meter intervals, also taking samples at lithology changes. We collected a total 18 samples, all of which …

Lithology And Depositional Environments Of A Portion Of The Clays Ferry Formation (Middle And Upper Ordovician) Exposed At Silver Creek, Madison County, Kentucky, Autumn Murray

EKU Faculty and Staff Scholarship

We measure, describe, and interpret a carbonate stratigraphic section within the Clays Ferry Formation (Middle and Upper Ordovician) cropping out in Madison County, Kentucky (USGS Kirksville 7.5” quadrangle). The total thickness of the measured section is 4.76 m. We sampled the stratigraphic section at approximately half-meter intervals, also taking samples at lithology changes. We collected a total 20 samples, all of which were slabbed, and then selected 12 samples for thin section analysis.

Observed lithologies represent discrete depositional environments. The rocks are dominantly limestones with some carbonate shales deposited in shallow-water depositional environments that are generally open-marine, subtidal with perhaps …

Facies Analysis, Sedimentary Petrology, And Reservoir Characterization Of The Lower Triassic Sinbad Limestone Member Of The Moenkopi Formation, Central Utah: A Synthesis Of Surface And Subsurface Data, Kristopher Michael Powell

Theses and Dissertations

Lower Triassic strata in the Wellington Flat and Tully cores reflect a lateral transition from shallow water strata (Wellington Flats core) to strata that indicate deposition on a relatively more distal, storm-dominated ramp (Tully core). The Sinbad Member, along with the upper part of the underlying Black Dragon Member and the lower part of the overlying Torrey Member (Moenkopi Formation), are composed of ten carbonate, siliciclastic and mixed carbonate/siliciclastic facies deposited on a west-facing ramp/shelf that reached maximum flooding during Smithian time. Individual beds and facies display a large degree of lateral homogeneity and regional persistence in the study area. …

Speleogenesis Of Critchfield Bat Caves And Associated Hydrogeology Of The Northern Edwards Aquifer, Williamson County, Texas, Ashley N. Landers

Electronic Theses and Dissertations

Karst development in the Edwards Aquifer has been significantly studied in the San Antonio and Barton Spring Segments; however, karst development remains poorly studied in the Northern Segment. Detailed characterization of the Northern Segment is vital for future water conservation because of increasing urban sprawl along the Interstate 35 corridor. The Northern Segment of the Edwards Aquifer consists of Lower Cretaceous strata of the Comanche Peak, Edwards, and Georgetown formations. The stratigraphy is dominated by Edwards Limestone as it is the only formation that crops out in the study area.

Karst, stratigraphic, GIS, and geochemical studies were conducted to evaluate …

Experimental Limestone Dissolution And Changes In Multiscale Structure Using Small- And Ultra Small- Angle Neutron Scattering, Chad Alan Novack

Masters Theses

Small angle neutron scattering (SANS), ultra-small angle neutron scattering (USANS), and backscatter electron (BSE) imaging, along with neutron computed tomography (NCT) were used in this study to experimentally quantify pore size, distribution, and connectivity of dissolved limestone geometries. Eight samples of Indiana limestone of two different initial permeabilities (2-4 mD and 70 mD ) [millidarcy] were reacted with HCl [hydrochloric acid] solutions at differing pH (2 and 4), and flow rates (0.1 and 10 cm³/min) [cubic centimeters per minute] to describe a broad range of parameters that affect limestone dissolution. NCT was first used to image the dissolution …

Carbon Isotope Variations Associated With A Middle Ordovician Karstic Unconformity, Patricia Suzanne Williams

UNLV Theses, Dissertations, Professional Papers, and Capstones

Large negative carbon isotope (δ¹³C) excursions have been documented from late Neoproterozoic-Paleozoic successions. These δ¹³C excursions have been widely used for regional and global stratigraphic correlation, particularly in strata with limited paleontological and radiometric age controls. Recent studies, however, argued that some negative δ¹³C excursions from stratigraphic record may have been resulted from meteoric/burial diagenesis, which commonly shifts both carbon and oxygen isotopes toward lower values. Testing the diagenetic origin of δ¹³C excursions in stratigraphic successions without independent stratigraphic framework has been difficult because it evolves into circular arguments about stratigraphic completeness …

Validity Of Holocene Analogs For Ancient Carbonate Stratigraphic Successions: Insights From A Heterogeneous Pleistocene Carbonate Platform Deposit, Colby Hazard

Theses and Dissertations

Observations of modern carbonate depositional environments and their accompanying depositional models have been used for decades in the reconstruction and interpretation of ancient carbonate depositional environments and stratigraphic successions. While these Holocene models are necessary for interpreting their more ancient counterparts, they inherently exclude important factors related to the erosion, diagenesis, and ultimate preservation of sediments and sedimentary structures that are ubiquitous in shallow marine carbonate environments. Andros Island, Bahamas is an ideal location to examine the validity of Holocene conceptual models, where geologically young (Late Pleistocene) limestones can be studied immediately adjacent to their well-documented modern equivalents. For this …

Economic Geology Of The San Bernardino Mountains, California, Nicolette Deannah Grill

Electronic Theses, Projects, and Dissertations

The San Bernardino Mountains are well known for their rich mining history, especially, gold in the mid-1800s and the current mining of one of the world’s largest deposits of high purity limestone. The purpose of this study was to compile new, current, and historical data of the major economic resources that are present and mining that has gone on in the San Bernardino Mountains. It is estimated that historical mining of the Holcomb Valley recovered $457,660,000 of gold or about 350,000 troy ounces based on samples collected for this study and 2013 gold price. The current major geologic resource is …

Subsurface Sequence Stratigraphy And Reservoir Characterization Of The Mississippian Limestone (Kinderhookian To Meramecian), South Central Kansas And North Central Oklahoma, Thomas Cahill

Graduate Theses and Dissertations

Both conventional and unconventional Mississippian reservoirs in the mid-continent are largely comprised of chert-rich carbonates of Osagean and Meramecan age. The conventional reservoir target is the Mississippian "chat," a high porosity, chert residuum interval found immediately beneath the Mississippian-Pennsylvanian unconformity. The unconventional reservoir target occurs in the lower porosity, cherty, mud-rich intervals that occur in the lower portion of the Mississippian succession.

There has been considerable debate surrounding the sequence stratigraphic interpretations, depositional models, and formation names applied to the reservoir intervals within the subsurface. Another major issue with regard to the subsurface is the stratigraphic position and origin of …

Geoanalytical Analysis Of Speleogenetic Development In The Owl Mountain And Nolan Creek Provinces: Fort Hood Military Installation, Texas (Abstract], Melinda G. Shaw-Faulkner, Kevin W. Stafford, Aaron W. Bryant

Faculty Presentations

No abstract provided.

Limetstone And Dolomite Resources Of Kentucky, Garland R. Dever Jr., Gerald A. Weisenfluh

Map and Chart--KGS

Large quantities of limestone and dolomite suitable for construction, agriculture, and industrial uses are available in Kentucky. Deposits of hard and durable stone are quarried and mined for construction. The stone is crushed to produce aggregate for concrete and asphalt used in the construction of highways, streets, and buildings. Much of the state’s stone being produced for construction also meets the chemical and physical specifications for aglime, which is used to adjust the pH of soils for agricultural crops and pastures. Deposits of chemically pure stone are used for the manufacture of lime and cement, and for industrial applications such …

An Inventory And Condition Survey Of The Western Australian Part Of The Nullarbor Region, P A. Waddell, A K. Gardner, P Hennig

Technical Bulletins

The inventory and condition survey of the Western Australian part of the Nullarbor region, undertaken by the Department of Agriculture and Food, Western Australia (DAFWA) between 2005 and 2007, describes and maps the natural resources of the region. This survey report provides a baseline record of the existence and condition of the area's natural resources, to assist with the planning and implementation of land management practices. The report identified and described the condition of soils, landforms, vegetation, habitat, ecosystems, and declared plants and animals. It also assessed the impact of pastoralism and made land management recommendations. The Nullarbor region has …

Generalized Geologic Map For Land-Use Planning: Green County, Kentucky, Daniel I. Carey, Adam Pike

Map and Chart--KGS

This map is not intended to be used for selecting individual sites. Its purpose is to inform land-use planners, government officials, and the public in a general way about geologic bedrock conditions that affect the selection of sites for various purposes. The properties of thick soils may supercede those of the underlying bedrock and should be considered on a site-to-site basis. At any site, it is important to understand the characteristics of both the soils and the underlying rock.

Generalized Geologic Map For Land-Use Planning: Barren County, Kentucky, Daniel I. Carey, Joshua J. Johnson

Map and Chart--KGS

This map is not intended to be used for selecting individual sites. Its purpose is to inform land-use planners, government officials, and the public in a general way about geologic bedrock conditions that affect the selection of sites for various purposes. The properties of thick soils may supercede those of the underlying bedrock and should be considered on a site-to-site basis. At any site, it is important to understand the characteristics of both the soils and the underlying rock.

Generalized Geologic Map For Land-Use Planning: Martin County, Kentucky, Daniel I. Carey

Map and Chart--KGS

This map is not intended to be used for selecting individual sites. Its purpose is to inform land-use planners, government officials, and the public in a general way about geologic bedrock conditions that affect the selection of sites for various purposes. The properties of thick soils may supercede those of the underlying bedrock and should be considered on a site-to-site basis. At any site, it is important to understand the characteristics of both the soils and the underlying rock.

Generalized Geologic Map For Land-Use Planning: Menifee County, Kentucky, Daniel I. Carey, Peter Eclov

Map and Chart--KGS

This map is not intended to be used for selecting individual sites. Its purpose is to inform land-use planners, government officials, and the public in a general way about geologic bedrock conditions that affect the selection of sites for various purposes. The properties of thick soils may supercede those of the underlying bedrock and should be considered on a site-to-site basis. At any site, it is important to understand the characteristics of both the soils and the underlying rock.

Generalized Geologic Map For Land-Use Planning: Bath County, Kentucky, Daniel I. Carey

Map and Chart--KGS

This map is not intended to be used for selecting individual sites. Its purpose is to inform land-use planners, government officials, and the public in a general way about geologic bedrock conditions that affect the selection of sites for various purposes. The properties of thick soils may supercede those of the underlying bedrock and should be considered on a site-to-site basis. At any site, it is important to understand the characteristics of both the soils and the underlying rock.

Generalized Geologic Map For Land-Use Planning: Monroe County, Kentucky, Daniel I. Carey

Map and Chart--KGS

This map is not intended to be used for selecting individual sites. Its purpose is to inform land-use planners, government officials, and the public in a general way about geologic bedrock conditions that affect the selection of sites for various purposes. The properties of thick soils may supercede those of the underlying bedrock and should be considered on a site-to-site basis. At any site, it is important to understand the characteristics of both the soils and the underlying rock.

Generalized Geologic Map For Land-Use Planning: Greenup County, Kentucky, Daniel I. Carey

Map and Chart--KGS

This map is not intended to be used for selecting individual sites. Its purpose is to inform land-use planners, government officials, and the public in a general way about geologic bedrock conditions that affect the selection of sites for various purposes. The properties of thick soils may supercede those of the underlying bedrock and should be considered on a site-to-site basis. At any site, it is important to understand the characteristics of both the soils and the underlying rock.

Generalized Geologic Map For Land-Use Planning: Casey County, Kentucky, Daniel I. Carey, Garland R. Dever Jr.

Map and Chart--KGS

This map is not intended to be used for selecting individual sites. Its purpose is to inform land-use planners, government officials, and the public in a general way about geologic bedrock conditions that affect the selection of sites for various purposes. The properties of thick soils may supercede those of the underlying bedrock and should be considered on a site-to-site basis. At any site, it is important to understand the characteristics of both the soils and the underlying rock.

Generalized Geologic Map For Land-Use Planning: Washington County, Kentucky, Daniel I. Carey

Map and Chart--KGS

This map is not intended to be used for selecting individual sites. Its purpose is to inform land-use planners, government officials, and the public in a general way about geologic bedrock conditions that affect the selection of sites for various purposes. The properties of thick soils may supercede those of the underlying bedrock and should be considered on a site-to-site basis. At any site, it is important to understand the characteristics of both the soils and the underlying rock.

Generalized Geologic Map For Land-Use Planning: Taylor County, Kentucky, Daniel I. Carey, Adam Pike

Map and Chart--KGS

This map is not intended to be used for selecting individual sites. Its purpose is to inform land-use planners, government officials, and the public in a general way about geologic bedrock conditions that affect the selection of sites for various purposes. The properties of thick soils may supercede those of the underlying bedrock and should be considered on a site-to-site basis. At any site, it is important to understand the characteristics of both the soils and the underlying rock.

Generalized Geologic Map For Land-Use Planning: Hart County, Kentucky, Daniel I. Carey, Joshua J. Johnson

Map and Chart--KGS

This map is not intended to be used for selecting individual sites. Its purpose is to inform land-use planners, government officials, and the public in a general way about geologic bedrock conditions that affect the selection of sites for various purposes. The properties of thick soils may supercede those of the underlying bedrock and should be considered on a site-to-site basis. At any site, it is important to understand the characteristics of both the soils and the underlying rock.

Generalized Geologic Map For Land-Use Planning: Metcalfe County, Kentucky, Daniel I. Carey

Map and Chart--KGS

This map is not intended to be used for selecting individual sites. Its purpose is to inform land-use planners, government officials, and the public in a general way about geologic bedrock conditions that affect the selection of sites for various purposes. The properties of thick soils may supercede those of the underlying bedrock and should be considered on a site-to-site basis. At any site, it is important to understand the characteristics of both the soils and the underlying rock.

Generalized Geologic Map For Land-Use Planning: Cumberland County, Kentucky, Daniel I. Carey, Courtney Snapp

Map and Chart--KGS

No abstract provided.

Generalized Geologic Map For Land-Use Planning: Lincoln County, Kentucky, Daniel I. Carey, Sally Sloan

Map and Chart--KGS

This map is not intended to be used for selecting individual sites. Its purpose is to inform land-use planners, government officials, and the public in a general way about geologic bedrock conditions that affect the selection of sites for various purposes. The properties of thick soils may supercede those of the underlying bedrock and should be considered on a site-to-site basis. At any site, it is important to understand the characteristics of both the soils and the underlying rock.