Physical Sciences and Mathematics Commons^™

Meteoric 10Be, FeD, And Clay In Critical Zone Soils, Front Range, Colorado, Cianna Wyshnytzky, James Mccarthy

Cianna E Wyshnytzky

The critical zone is the zone within which meteoric water, atmospheric gases, soil, and bedrock interact, encompassing the zone of soil formation (Anderson et al., 2007). The concentrations of various pedogenic compounds at a given location indicate the degree of weathering that has taken place in the Critical Zone. Among the products of chemical weathering are secondary phyllosilicate minerals (clays) and iron (Birkeland, 1999). At stable sites, chronosequence studies have shown that the amount of pedogenic iron oxide and clay increase as soils become older (McFadden and Hendricks, 1985).

Meteoric ¹⁰Be is a cosmogenic nuclide produced from oxygen and nitrogen …

Synthesis Of Trifluoromethyl-Imines By Solid Acid/Superacid Catalyzed Microwave-Assisted Approach, Abid Shaikh, Markku Savolainen, Shainaz M. Landge, Jinbo Hu, G. K. S. Prakash, George A. Olah, Béla Török

Abid Shaikh

Trifluoromethyl, Imine, Clay, Solid acids, Solid superacid, Catalysis, Microwave irradiation Abstract: A new solid acid/superacid catalyzed microwave assisted synthesis of trifluoromethyl-imines is described. Various α,α,α-trifluoromethylketones react readily with primary amines to produce the corresponding imines. Two different strategies have been employed; one is the application of microwave irradiation coupled with solvent-free solid acid catalysis. The other method, for highly deactivated substrates includes the use of a pressure vessel at 175 °C temperature, with solid superacid catalysis. Using the solid acid K-10 montmorillonite or the superacidic perfluorinated resinsulfonic acid Nafion-H, a wide variety of trifluoromethylated imines have been synthesized using the …