Physical Sciences and Mathematics Commons^™

Crack-Ers (Crack Riddles Applying Cybersecurity Knowledge - Escape Room Scenario), Benjamin Acuff

Posters-at-the-Capitol

CRACK-ERS (Crack Riddles Applying Cybersecurity Knowledge - Escape Room Scenario) is a unique, beginner's level CTF game with riddle-based challenges on various cybersecurity topics. The game is driven by an adventure story-based escape room format. Existing literature indicates that traditional CTFs pose challenges for beginners with no cybersecurity background. The novelty of CRACK-ERS lies in its non-traditional design as an unplugged CTF with an adventure scenario-driven script, encouraging participants to solve cybersecurity-related riddles. CRACK-ERS targets beginner-level learners, fostering teamwork, explorative research, cybersecurity problem-solving, and riddle-cracking skills. Prior cybersecurity educational research notes limited instances of escape room-style CTF games and fewer …

Predicting The Reactions Of Cs2, Ocs, And Co2 With Group Iv And Group Vi Transition Metal Oxides, Marissa Shea Blair, Zachary Ryan Lee Phd, David A. Dixon Phd

Posters-at-the-Capitol

Building on a recent serious of high level electronic structure studies of Lewis acid gas reactions with metal oxide sorbents, DFT (B3LYP and ωB97X-D) and CCSD(T) methods are being used to predict the Lewis acid-base addition (physisorption) and formation of metal oxide carbonate/thiocarbonate formation (chemisorption) reactions of CS2, OCS, and CO2 of CS2, OCS, and CO2 with Group IV (MO2)n and Group VI (MO3)n (n = 1 - 3) nanoclusters. For the Group IV oxides, chemisorption to form terminal carbonates and thiocarbonates is predicted to be the most favored, with thiocarbonate ligand binding energies slightly more exothermic than their carbonate …

"Semiclassical Mastermind", Curtis Bair, Alexa S. Cunningham, Joshua Qualls

Posters-at-the-Capitol

Games are often used in the classroom to teach mathematical and physical concepts. Yet the available activities used to introduce quantum mechanics are often overwhelming even to upper-level students. Further, the "games" in question range in focus and complexity from superficial introductions to games where quantum strategies result in decidedly nonclassical advantages, making it nearly impossible for people interested in quantum mechanics to have a simple introduction to the topic. In this talk, we introduce a straightforward and newly developed "Semiclassical Mastermind" based on the original version of mastermind but replace the colored pegs with 6 possible qubits (x+, x-, …

Dual Ionic Liquid-Functionalized Cellulosic Materials: Thermal, Mechanical And Conductive Properties, Elizabeth Mcgrew, Kevin M. Miller Phd

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Cellulose, an inexpensive and renewable biomacromolecule, represents an intriguing synthetic foundation for new materials with task-specific properties. Here, we wish to report a synthetic route for functionalizing cellulose with a side chain containing two ionic liquid functional groups using azide-alkyne ‘click’ cyclization strategy, followed by quaternization of the two resulting heterocycles (1,2,3-triazole and imidazole). Through this functionalization strategy, the resulting cellulosic materials exhibited significant softening, with several glass transition (T_g) values observed below room temperature, indicating the amorphous nature of the materials, with the T_g dependent on both the length of the side chain and the …

Strategies For Identifying Important Residues In The Trna Modification Protein Trm732, Alex K. Mullins, Natalie N. Creech, Holly Funk, Michael Guy

Posters-at-the-Capitol

Post-transcriptional tRNA modifications are required for efficient protein translation. In yeast, the Trm7 methyltransferase forms a complex with Trm732 to modify tRNA at position 32. In humans, lack of the human homolog for Trm7, FTSJ1, causes intellectual disability. Little is known about the function of Trm732, although we have shown that one conserved motif in Trm732 is important for tRNA modification. We have identified other residues important for function using two strategies. First, we compared Trm732 proteins of different organisms using protein alignments to determine conserved regions to mutate for testing. We have generated four new Trm732 variants and have …

One-Pot Conversion Of Carboxylic Acids To Aldehydes, Hannah Khan, Michael Nantz, Saurin Sutaria

Posters-at-the-Capitol

There are many different ways to convert a carboxylic text acid to an aldehyde. A common way to accomplish this transformation is to use multiple steps (e.g., reduction of the carboxylic acid to the corresponding alcohol followed by selective oxidation to the aldehyde). Our success in reducing the diacid muconic acid (1) to muconaldehyde (4) in a relatively mild, one-pot process has led us to examine whether the method can be expanded to other carboxylic acids. We report here our findings using benzoic acid as a representative substrate.

Wastewater-Based Estimation Of Substances Discharged At The Rest Areas Along The State Highways In Kentucky, Katherine E. Gray, Eugene Shin, Tyler Whitt, Andrew Windhorst, Houston Hampton, Chris Delcher, Bikram Subedi

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The availability of licit and illicit stimulants and its adverse consequences on public health has emerged as a major drug threat to communities in the United States. Despite several drug-involved traffic incidents along the interstate highways, this report represents the first comprehensive and quantitative report of drugs discharged at the rest areas along the interstate highways. In this National Institute of Justice-funded study, the amount of several discharged drugs focusing on stimulants but also including opioids and prescription antipsychotics are being measured in raw wastewater collected from five rest areas and a truck servicing facility using a state-of-the-art mass …

Comparative Analysis Of Rgb-Based Eye-Tracking For Large-Scale Human-Machine Applications, Brett Thaman, Trung Cao

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Gaze tracking has become an established technology that enables using an individual’s gaze as an input signal to support a variety of applications in the context of Human-Computer Interaction. Gaze tracking primarily relies on sensing devices such as infrared (IR) cameras. Nevertheless, in the recent years, several attempts have been realized at detecting gaze by acquiring and processing images acquired from standard RGB cameras. Nowadays, there are only a few publicly available open-source libraries and they have not been tested extensively. In this paper, we present the result of a comparative analysis that studied a commercial eye-tracking device using IR …

Weather And Climate Research At The Kentucky Climate Center Based On Mesonet Observations, Brittany Pekara, Eric Rappin

Posters-at-the-Capitol

The Kentucky Mesonet is a great asset for the Commonwealth of Kentucky in a multitude of ways, from real-time storm monitoring to building a detailed climate record. A detailed climate record is essential as causality between observations and extreme weather can be identified, making it a great tool in an evolving climate system. The climate record being developed at the 75+ Kentucky Mesonet observation stations consists of approximately 75 indices that reflect frequency, extremes, range, duration, trends of precipitation, droughts, and extreme temperatures. Calculations are done for daily, weekly, monthly, seasonal, bi-annual, and annual aggregation periods. Tools will also be …

Design And Construction Of A Modular Nai(Tl) Detector Array For Use In The Parity- And Time Reversal Violation Measurements For Noptrex, Jon Mills, Jason Fry

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The goal of the NOPTREX collaboration is to probe the Standard Model by utilizing the properties of low energy neutron-nucleus resonances to find evidence of parity- and time-reversal-odd violations. In order to conduct these sensitive experiments, it is needed to design and simulate an array of modular, high precision NaI(Tl) detectors. These detectors will be designed to operate in both pulse and current modes. We have tentative beam time at LANSCE to perform a search for new parity violation in heavy nuclei as candidates for time reversal and to perform a research and development effort on the n+d=t+gamma experiment. We …

Root Cause Analysis And Method Development Of Calorimetry Experiments, Anya M. Deaton, Lydia R. Deaton, John M. Farrar Dr.

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First year chemistry students learn a broad range of concepts that are also proven out in the lab environment. These concepts are a basis for a solid foundation for future chemistry learning. When the lab experiments don’t produce the expected results, students understanding in these concepts diminish and overall confidence and grades suffer. Our project details the root cause analysis and subsequent method development work for two experiments related to calorimetry; heat of solution and freezing point depression. The team sought to refine these experiments after finding that many of the students were unable to generate the expected results for …

Galaxy And Mass Assembly: A Comparison Between Galaxy-Galaxy Lens Searches In Kids/Gama, Shawn Knabel, Benne Holwerda

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Strong gravitational lenses are cases where a distant background galaxy is located directly behind a massive foreground galaxy, whose gravity causes the light from the background galaxy to bend around the foreground galaxy. In addition to being visually stunning, these rare events are useful laboratories for furthering our understanding of gravity and cosmology and to determine properties, such as the mass and dark matter content, of the lensing galaxies themselves. The trouble is finding enough of these strong gravitational lenses for further study. The immensity of the catalogs being collected by state-of-the-art telescopes requires equally innovative methods for interpreting that …

Determination Of Cannabinoids, Cathinones, And Synthetic Fentanyls Using Wastewater-Based Epidemiology, Catherine O'Rourke, Bikram Subedi

Posters-at-the-Capitol

Unregulated new psychoactive substances (NPS) in “pure” or “preparation” forms are designed to mimic the effects of controlled substances, and are introduced and reintroduced in the market as a cheap substitute for established regulated drugs in quick succession to loophole the law enforcement efforts on combating drugs. For example, carfentanil, a synthetic opioid activates the opioid receptors similar to morphine but it is astoundingly potent compared to a typical drug of abuse (100 times more potent than fentanyl and 10,000 times more powerful than morphine). Based on the cost- and time-intensive forensic analysis, National Drug Early Warning System reported the …

A Terrestrial Reconstruction Of Gona, Ethiopia Before And During The African Humid Period, Marie N. White, Gary E. Stinchcomb

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The African Humid Period (AHP) resulted in more humid conditions across Northern and Eastern Africa from 15 to 5 thousand years ago (ka). This wetter climate affected flora, fauna and the Homo sapiens living in East Africa. The lack of terrestrial paleoenvironmental reconstructions is a problem in East Africa, especially during the AHP, where most are done utilizing lacustrine or marine proxies. In the case of Gona, Ethiopia, terrestrial proxies are desired due to the rich archaeological and fossil concentrations that occur in the area. Paleosols provide more direct, localized reconstructions that provide context for these finds. This study utilizes …

The Effects Of Erosion Structures On Triplett Creek From The Fall Of 2016, 2017, And 2018, Haylee Winters

Posters-at-the-Capitol

Triplett Creek is a tributary of the Licking River. It runs through Morehead, KY, where we are conducting our research.

The creek was modified in the 1970s but construction was halted before the project was complete. Unfortunately, the result was an increase in overflow and subsequent riverbank erosion. The city installed sediment trap rocks in hopes of slowing down the water and decreasing erosion. We are using drones and photogrammetric software to map the area and compare images of the river to determine erosion rates. The new images will be compared to ones taken in previous years to visualize the …

Observing Soil Changes Under Common Cropping Practices In Kentucky, Samantha Peterson, Iin Handayani, Alyx Shultz Dr, Brian Parr

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Cropping production and tillage systems lead to loss of soil organic matter (SOM), lowering soil pH, and soil compaction in Kentucky. However, the magnitude of the changes varied among the soil properties. Therefore, the objective of this research was to evaluate the changes in SOM, soil pH, and soil compaction under different cropping systems like corn-soybean-tobacco rotation (Field #1), continuous corn field (Field #2), hemp field (Field #3), wheat field (Field #4), pasture with animal grazing (Field #5), and canola field (Field #6). The prominent soil textures in all fields are silt loam and silty clay loam. Disturbed soil samples …

Elevated Calcium Levels In Kentucky Lake: A Possible Emerging Problem With An Invasive Species, Adam T. Martin

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Zebra mussels (Dreissena polymorpha) are an exotic and invasive mollusk that have spread extensively through various rivers and lakes in the United States. These mussels are notorious for their “biofouling” capabilities costing billions of dollars in their removal from industrial, public, and power plant water supply lines. While having been present in the Tennessee River drainage with occasional small reproducing populations since the early 1990s, zebra mussels were never abundant or widespread. In 2017, high densities were found on structures and solid substrates throughout the lower portion of Kentucky Lake. Calcium is one of the essential elements that contributes …

Creating A Computational Tool To Simulate Vibration Control For Piezoelectric Devices, Ahmet Ozkan Ozer, Emma J. Moore

Posters-at-the-Capitol

Piezoelectric materials have the unique ability to convert electrical energy to mechanical vibrations and vice versa. This project takes a stab to develop a reliable computational tool to simulate the vibration control of a novel “partial differential equation” model for a piezoelectric device, which is designed by integrating electric conducting piezoelectric layers constraining a viscoelastic layer to provide an active and lightweight intelligent structure. Controlling unwanted vibrations on piezoelectric devices (or harvesting energy from ambient vibrations) through piezoelectric layers has been the major focus in cutting-edge engineering applications such as ultrasonic welders and inchworms. The corresponding mathematical models for piezoelectric …

Consumption Profiles Of Illicit And Neuropsychiatric Drugs In Urban And Rural Communities In Kentucky Using Sewage Epidemiology, Tara Croft, Katelyn Foppe, Rhiannon Huffines, Bikram Subedi

Posters-at-the-Capitol

The drug overdose deaths in the USA increased by ~20% from 2015 to 2016 to the total >63,600 drug overdose deaths in 2016. Kentucky is among the highest rate of drug overdose death states in the USA. The current estimates of the prevalence of substance abuse are based on the self-reported surveys, overdose/toxicological reports, and drug-related crime statistics. Survey-based conventional approaches are not only cost and time-intensive but also underestimate the actual consumption of drugs. As “wastewater never lie,” the drug residues in raw wastewater collected from the centralized wastewater treatment plants were utilized to determine the consumption rate of …

Performance Of The Parallelized Monte-Carlo Tree Search Approach For Dots And Boxes, Pranay Agrawal, Uta Ziegler

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The Monte-Carlo tree search (MCTS) is a method designed to solve difficult learning problems. MCTS performs random simulations from the current situation and stores the results in order to distinguish decisions based on their past success. MCTS will then select the best decision and finally repeat the process. Parallelizing the MCTS means to divide the learning process among independent learners. Then, after a fixed number of simulations, the data is shared and combined. Past research has shown that this approach is faster than non-parallelized approaches. Therefore, we anticipated that the time reduced from dividing the learning outweighs the potential costs …

Variations Of Soil Qualities In Urban And Rural Areas, Gabby Barnes, Iin Handayani, Steve Still

Posters-at-the-Capitol

The purpose of this study was to evaluate the variations of soil characteristics under different management practices in rural soils versus urban soils. In this study, soil samples from rural areas in Kentucky were collected from a woodland plot, a no-till plot, and a tilled plot. The soil samples from the rural were taken from two depths in order to better evaluate the effect of tillage on the soil. A shallow depth of 0-7cm and a deep depth of 7-15cm were used. Soil samples were also taken from urban plots in Memphis, TN. The sampled plots included were an animal …

Longitudinal Study Of Water Quality In Jennings Creek, Bowling Green, Kentucky: Urbanization Impacts On Karst Groundwater, Lea Mitchell, Jason S. Polk, Rachel Kaiser, Ethan Givan, Kegan Mcclanahan

Posters-at-the-Capitol

Karst groundwater systems, which occur in areas where caves, sinkholes, and underground rivers dominate the landscape, are vulnerable to pollution from surface contaminants. In urban areas, like Bowling Green, Kentucky, which is home to extensive caves and groundwater supplies, the immediate transport of heavy metals, organic waste, chemicals, and other pollutants from surface activities into groundwater poses a serious threat. This research project was done to examine the water quality of urban karst sites in Bowling Green, Kentucky at Jennings Creek, which is a local river primarily fed from springs; the water quality of Jennings Creek was never tested before …

Two-Dimensional Layered Materials (Graphene-Mos2) Nanocatalysts For Hydrogen Production, Jacob Dobler, Taylor Robinson, Sanju Gupta 7455940

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Recent development of two-dimensional layered materials including graphene-family and related nanomaterials have arisen as potential game changer for energy, water and sensing applications. While graphene is a form of carbon arranged hexagonally within atomic thin sheet, MoS₂ is becoming a popular, efficient, and cost-effective catalyst for electrochemical energy devices, in contrast to expensive platinum and palladium catalysts. In this work, we electrochemically desulfurize few-layer molybdenum disulfide (MoS₂) and aerogels with reduced graphene oxide (rGO) prepared under hydrothermal conditions ((P< 20 bar, T< 200 ^oC), for improving hydrogen evolution reaction (HER) activity via point defects (S-vacancy). Moreover, the interactions between rGO …

Physical Properties Of Engineered Nanocomposites For Defense Applications, Alex Henson, Sanju Gupta

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Polymer nanocomposites are significant for modern and future technologies (aerospace, defense, water purification etc.) due to their tailored properties, lightweight and low cost. However, ‘forward’ engineered polymer (host matrix) composites with smaller size nanoparticles (guest) providing desired properties targeting specific applications remains a challenging task as they depend largely on nanoparticles size, shape and loading (volume fraction). This study develops polymer nanocomposites impregnated with ‘organic-inorganic’ silsesquioxane nanoparticles and graphene nanoribbons, and investigates microscopic structure and dynamics of interfacial layer to predict macroscale properties. The nanocomposites consist of poly(2-vinylpyridine) (P2VP) polymer (segment ~5nm) with spherical silsesquioxane nanoparticles (diameter ~2-5nm) and planar …

The Undeniable Attraction Of Lunar Swirls, Cierra Waller, Dhananjay Ravat

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Lunar swirls are complex patterns on the Moon with distinct brightness signatures and magnetic characteristics. Current research has suggested that the formation of lunar swirls relies on local magnetic fields to shield impinging solar wind, based on a shift in electromagnetic wavelength peaks related to solar radiation and space weathering. Our research combined recent models and methods to characterize these anomalies at the surface of the Moon, exploring the effects of field strength and position. We have produced a high resolution map of a famous swirl named Reiner Gamma using magnetic dipole modeling. These maps and models are considered when …

Cloud Security, Isabella Roth, Jose Salazar, Yi Hu

Posters-at-the-Capitol

Isabella Roth

Jose Salazar

Professor Yi Hu

Computer Information Technology

Cloud Security: AWS Abstract

With enterprises moving their IT infrastructure to the cloud using providers like Amazon Web Services (AWS), security problems have not been reduced. In fact, cloud computing brings new security challenges. Our research investigated better solutions to the security problems that come with using the cloud to store a companies data.

The cloud is a general term for using the internet to receive some sort of data vs connecting directly to a server. This makes it easier to do things such as connecting to an online app …

Catalytic Deoxygenation Of Model And Realistic Feeds To Fuel-Like Hydrocarbons Over Supported Nickel-Copper Catalysts, Deyshon Ward, Kazi Javed

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The goal was to make a renewable fuel by using catalysts to remove oxygen molecules from fats. This is a current issue that society faces today because nonrenewable fossil fuels hurt the environment more than they help it. There are two components that make up a heterogeneous catalyst, a support and a reduced metal active phase. The active metal phases Nickel, Palladium, Platinum have been studied in the past on an alumina and carbon supports. We were investigating other supports using Nickel as the active phase component to determine the effect the support has on the catalyst removing oxygen of …

An In Vitro Study On Skin Protection Across The Uv Spectra, Cheyenne Boone

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Skin cancer is the number one cancer in the United States. Lack of awareness of how harmful UV radiation is could be the cause of the over two million cases reported since 2012. It appears that there is not a lot information on the active ingredients used in sunscreens. Some of the compounds have been linked to birth defects, hormone disruptions, and the bleaching of coral reefs. Samples of commonly used sunscreens (both sprays and creams), cosmetic foundation, essential oils, lotions, and three pure organic actives were tested at specific concentrations and ran through a UV spectrometer. The results have …

Shape Modeling And Boulder Mapping Of Asteroid 1992 Uy4, Nicholas Duong

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The structure and history of near-Earth asteroids are important to
study because they collide with Earth, sometimes with significant consequences for
climate and the survival of many species, including our own. If NASA is ever to deflect an asteroid on a collision course, it is crucial to know as much as possible about its size, composition, structure and boulder distribution. The boulder
distribution in turn helps to map the asteroid's gravitational field.

1992 UY4 is a near-Earth asteroid discovered in 1992. In August 2005, UY4 made a
``close" (for space) pass of Earth, about 15x farther than the Moon. It …

Tunable Copper Complexes For Sustainable Photocatalysis, David Kline

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Photoredox catalysis has direct applications in sustainable chemistry and thus an immense impact on our environment. With the ability to harness energy directly from the sun to catalyze useful chemical reactions, photocatalysts can help to eliminate the need for harsh reaction conditions and reduce generation of hazardous chemical waste. Photocatalysts based on Earth-abundant metals such as copper have recently emerged as sustainable alternatives to rare-earth metals including iridium and ruthenium, which are no longer required for many photocatalyzed chemical transformations.