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Full-Text Articles in Physical Sciences and Mathematics

Fabrication, Characterization, And Application Of Carbon Nanoparticles For The Detection Of Heavy Metal Ions In Aqueous Media, Aaron Michael Simpson Dec 2015

Fabrication, Characterization, And Application Of Carbon Nanoparticles For The Detection Of Heavy Metal Ions In Aqueous Media, Aaron Michael Simpson

MSU Graduate Theses

This research set out to develop a method for producing Carbon nanoparticles (CNPs) from glycerol and use them to detect Cu2+, Hg2+, and Pb2+ ions in aqueous solution. Three synthesis methods were developed using the following mixtures: (1) glycerol and silica, (2) glycerol, silica, and H3PO4, and (3) glycerol with H3PO4. The structure of the particles was characterized using a variety of spectroscopic techniques. Size distributions were obtained from scanning electron microscopy images. The particles were spherical with average diameters of 66, 58, and 89 nm respectively and believed to consist of a carbon core with carboxylic acid and alcohol …


Synthesis And Functionalization Of Fluorescent Quantum Dot Bioconjugates For Cellular Imaging Of Directed Gene Therapy, Jason Matthew Davis Jul 2015

Synthesis And Functionalization Of Fluorescent Quantum Dot Bioconjugates For Cellular Imaging Of Directed Gene Therapy, Jason Matthew Davis

MSU Graduate Theses

Herein, I optimize a method for synthesis and bioconjugation of water-soluble, fluorescent CdSe/ZnS quantum dots (QDs) for targeted cellular delivery of DNA. Core CdSe QDs were synthesized in high temperature organic solvents and passivated with a ZnS shell to increase quantum yield. The fluorescent QD nanoparticles were made water-soluble by enveloping them with an amphiphilic polymer. These aqueous nanoparticles were functionalized with tertiary amines to impart a positive charge, allowing electrostatic binding to negatively-charged DNA. The conjugated QDs were characterized using zeta potential and electrophoresis to gauge their ability to electrostatically bind DNA. The QDs were further modified by conjugation …


Recent Shoreline Erosion Rates Along Black River Bay, Jamaica: Erosion And Recovery After Hurricane Ivan In 2004, Karen Louise Zelzer May 2015

Recent Shoreline Erosion Rates Along Black River Bay, Jamaica: Erosion And Recovery After Hurricane Ivan In 2004, Karen Louise Zelzer

MSU Graduate Theses

Rising sea level is threatening coastal areas, particularly those in the Caribbean which rely heavily on tourism and marine resources to support local economies. The purpose of this study is to analyze shoreline position along the south coast of Jamaica to determine the locations and rates of coastal change. IKONOS satellite imagery sets for 2003, 2007 and 2012 were used to monitor land use and shoreline changes along Black River Bay, including Galleon Beach Fish Sanctuary, in St. Elizabeth, Jamaica. In particular, the effect of Hurricane Ivan in 2004 on shoreline changes was evaluated. Erosion rates were significantly higher during …


Aspects Of Fourier Analysis On Euclidean Space, Joseph William Roberts Jan 2015

Aspects Of Fourier Analysis On Euclidean Space, Joseph William Roberts

MSU Graduate Theses

The field of Fourier analysis encompasses a vast spectrum of mathematics and has far reaching applications in all STEM fields. Here we introduce and study the Fourier transform and Fourier series on Euclidean space. After defining the Fourier transform, establishing its basic properties, and presenting some classical results we looked into what impact the smoothness of a function has on the growth and integrability of its Fourier transform. This endeavor also involved a brief study of Bessel functions and interpolation of operators. Having established several results indicating that the behavior of a function's Fourier transform is largely dictated by the …


Gravity And Magnetic Investigations Into Possible Economic Mineral Deposits Within The Northwest St. Francois Terrane, Southeastern Missouri, Brandon Todd Ives Jan 2015

Gravity And Magnetic Investigations Into Possible Economic Mineral Deposits Within The Northwest St. Francois Terrane, Southeastern Missouri, Brandon Todd Ives

MSU Graduate Theses

The exposed Precambrian St. Francois Mountains in southeast Missouri are a well-studied terrane of rhyolites, granites, and basaltic dikes, but much of the buried basement lithology west of the exposed region is still poorly delineated. The western St. Francois is host to large hydrothermal Pb-Zn and Fe-oxide ore deposits, some of which were located with previous geophysical investigations. The economic ore deposits specifically in the Pea Ridge Mine in Washington County contain known economic minerals and rare earth element deposits. In order to further investigate the Precambrian basement lithologies and the possible locations of additional economic ore deposits, a gravity …


Stream Bank Erosion Trends And Sediment Contributions In A Southwestern Missouri River, Ezekiel Allen Kuehn Jan 2015

Stream Bank Erosion Trends And Sediment Contributions In A Southwestern Missouri River, Ezekiel Allen Kuehn

MSU Graduate Theses

Bank erosion can be a significant source of in-stream sediment that negatively affects water quality and aquatic habitat. However, assessments of the role that eroding banks play in suspended and bed sediment supply are rarely available to managers. The purpose of this study was to quantify bank erosion rates for a 7 km conservation easement the James River in southwest Missouri to evaluate the annual contributions of bank sediment to the channel. The objectives were to: (1) monitor an eroding 260 m bank to better understand short-term, reach scale bank erosion rates; (2) determine historical rates of bank erosion for …


Vitis Gene Expression Profiling Using Mixed Models, Yin Yin Jan 2015

Vitis Gene Expression Profiling Using Mixed Models, Yin Yin

MSU Graduate Theses

The purpose of this thesis is to analyze gene expression in grapevine under different treatments using a mixed linear statistical model. The experiment involves two Vitis species (V. vinifera Cabernet sauvignon and V. aestivalis Norton) and applies two different treatments to them (inoculation with Erysiphe necator conidiospores and mock inoculation). There are three biological replicates measured at each of the following six assigned time points: 0, 4, 8, 12, 24, and 48 hours. By setting up split-plot model for the data, statistical hypotheses concerning gene expressions, especially gene expressions in terms of treatment effect, are tested. The result of the …