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Articles 1 - 30 of 85
Full-Text Articles in Physical Sciences and Mathematics
The Gavel And The Camera: Environmental Law And Photojournalism's Relationship To Appalachian Identity, Emily S. Patton
The Gavel And The Camera: Environmental Law And Photojournalism's Relationship To Appalachian Identity, Emily S. Patton
Honors Theses
Both the federal government and photojournalism have played a substantial role in the “othering” of Appalachia while simultaneously attempting to save it. Examining both institutions demonstrates the exploitative processes that alter the perception of rural communities and their surrounding environment. Stacey Kranitz’s archival exhibit, As It Was Give(n) To Me, internalizes this precarious role of the camera in a region heavily journalized. By inhabiting the area for years, establishing close relationships, and researching the documented history of Appalachia, Kranitz’s work becomes her livelihood in the dissolution of profession vs. personal. She is critical of past projects whose objective portrayal of …
Guardians Of The Data: Government Use Of Ai And Iot In The Digital Age, Jannat Saeed
Guardians Of The Data: Government Use Of Ai And Iot In The Digital Age, Jannat Saeed
Honors Theses
The exponential growth of technology, epitomized by Moore's Law – “the observation that the number of transistors on an integrated circuit will double every two years”– has propelled the swift evolution of Artificial Intelligence (AI) and Internet of Things (IoT) technologies. This phenomenon has revolutionized various facets of daily life, from smart home devices to autonomous vehicles, reshaping how individuals interact with the world around them. However, as governments worldwide increasingly harness these innovations to monitor and collect personal data, profound privacy concerns have arisen among the general populace. Despite the ubiquity of AI and IoT in modern society, formal …
Screening Full-Sib And Half-Sib Families Of Chestnut Seedlings For Resistance To Cryphonectria Parasitica Using A Small Stem Assay And A Leaf-Disc Assay, Uma Plambeck
Honors Theses
Cryphonectria parasitica is the ascomycete fungus species that causes chestnut blight disease. Symptoms of chestnut blight include bark cankers and eventually the death of American chestnut, Castanea dentata. However, not all Castanea species are equally affected by the disease, and some Asian species appear highly resistant. The OALDS and SSA in this study aim to assist in screening for resistance to C. parasitica within a year. We investigated the effect of C. parasitica on three North American species, one European species, four East Asian species of Castanea, and nine full-sib families of TACF backcross hybrids. Our study used both a …
Do You Know The Pangolin?: Analyzing Biodiversity Awareness And Attitudes, Ariel "Jazz" Holcomb
Do You Know The Pangolin?: Analyzing Biodiversity Awareness And Attitudes, Ariel "Jazz" Holcomb
Honors Theses
Understanding the impact education has on environmental knowledge and values is critical for knowing how we can promote pro-environmental awareness and attitudes. Thus, this study investigated how environmental education level influences awareness and attitudes on environmental issues, specifically the Biodiversity Crisis. Through a survey primarily utilizing Likert scale statements, the researcher evaluated the differences in knowledge and care levels between classes taking an introductory environmental science course, one class of environmental science majors and one for non-majors. One focus point of the course is the world’s most trafficked mammal, the pangolin, so this species was used as a focus species …
Stress-Sensing In Flexible Epoxy Adhesives, Christine Rukeyser
Stress-Sensing In Flexible Epoxy Adhesives, Christine Rukeyser
Honors Theses
In mechanochemistry, mechanical force causes a chemical change using small molecules, called mechanophores, by covalently connecting them into polymer materials. Stress-sensing mechanophores give a visual signal of mechanical force on the molecular level within a material. To our knowledge, stress-sensing mechanophores have never been incorporated into a commercially available epoxy kit. In this work, the characterization of two 3MTM Scotch-Weld TM Epoxy Adhesive kits: DP100 Plus Clear and DP190 Translucent have been completed through FT-IR Spectroscopy. The addition of the mechanophore spiropyran to the 3M kits will be discussed; as well as preparation and characterization of three dimerized anthracene derivatives. …
Fostering A Sense Of Wonder: Promoting Experiential Learning Through Outdoor Discoveries On The Coast Of Maine, Joslyn Primicias
Fostering A Sense Of Wonder: Promoting Experiential Learning Through Outdoor Discoveries On The Coast Of Maine, Joslyn Primicias
Honors Theses
Recent generations of children have been experiencing a decrease in connection to Nature, causing various negative effects on personal development and well-being. Researchers are studying the impact of environmental education programs as a potential resolution to this issue dubbed “nature deficit disorder.” Studies have shown that while citizen science by youth is rapidly expanding, little research addresses conservation science with environmental education. Recognizing this gap, the summer camps at Wells NERR are designed to ensure children’s environmental stewardship as they learn about estuarine ecology alongside environmental issues. This educational study focuses on how environmental education through estuarine activities at summer …
Closing The Loop Of Food Systems: Analyzing Compost Within Community Bounds, Ellen A. Getter
Closing The Loop Of Food Systems: Analyzing Compost Within Community Bounds, Ellen A. Getter
Honors Theses
The aim of this thesis is to construct a philosophical and ecological argument that places great value on localized food systems in terms of waste. This composition develops the claim that building composting infrastructure on a community scale will curb the global climate crisis and enhance the interconnectedness humans have within themselves, each other, and the natural world. The first prong of this thesis entails a theoretical framework we must function under in order to implement such radical food revolutions in our communities informed by Buddhist principles. This proceeds an international case study of the composting infrastructure of Fort Albany …
The Hilbert Sequence And Its Associated Jacobi Matrix, Caleb Beckler
The Hilbert Sequence And Its Associated Jacobi Matrix, Caleb Beckler
Honors Theses
In this project, we investigate positive definite sequences and their associated Jacobi matrices in Hilbert space. We set out to determine the Jacobi matrix associated to the Hilbert sequence by methods described in Akhiezer’s book The Classical Moment Problem. Using methods in Teschl’s book Jacobi Operators and Completely Integrable Nonlinear Lattice, we determine the essential spectrum of the corresponding Jacobi matrix.
Modeling Surface Structures For The Capture Of Carbon Dioxide, Paige Freyre
Modeling Surface Structures For The Capture Of Carbon Dioxide, Paige Freyre
Honors Theses
Our research utilized a modified graphene surface model to simulate capture of carbon dioxide and nitrogen gas based on van der Waals forces and hydrogen bonding. We completed an extensive review of the literature for model and experimental surfaces used to trap carbon dioxide and nitrogen gas into structures and pores with varying functional groups, pore sizes, and pore structures. We replicated the design of selected published models and compared their and our calculated binding energies. We used Scigress (Fujitsu) software with the Molecular Mechanics MM3 parameter set to perform calculations to analyze a proposed graphene surface pore lined with …
Petrographic Observations Of Stromatolites In The Late Cambrian To Early Ordovician Knox Group, Northwest Georgia And Their Relationship To Stromatolitic Fabrics Over Geologic Time, Evan Ritchey
Honors Theses
Silica deposits are common in Proterozoic carbonate platforms and are interpreted to form early in the diagenetic history of the carbonate strata. Black early diagenetic chert deposits are often associated with evidence of ancient microbial mats, or stromatolites. Proterozoic chert nodules can contain well-preserved microfossils, because silicification occurs rapidly; however, silica deposition has changed over time and it is unclear if similar deposits exist in the Cambrian period after silica-utilizing organisms evolved. The Copper Ridge Dolomite in the Knox Group, northwest Georgia, which was deposited in the late Cambrian to early Ordovician, contains black chert nodules that follow the structure …
Studying Suspended Sediment Concentrations In The South Chickamauga Creek Of Chattanooga, Tn Using Satellite Imagery, Digital Image Processing, And Numeric Modeling, Abigail Faxon
Honors Theses
In recent years, Hamilton County, TN has experienced extensive urban growth. According to US Census data, Hamilton County welcomed more than 33,000 new residents in the last decade. There is increased concern about the environmental sustainability of Chattanooga’s urban growth because significant impervious surface development has taken place along the South Chickamauga Creek. This leaves the creek subject to increased urban runoff, which often carries sediments with different municipal pollutants. Thus, monitoring turbidity in the stream water is important to determine the sustainability of urban development in Chattanooga, TN. In this research, we have compared the viability of using different …
Theoretical Studies Of Benzoquinone Reactivity In Acidic And Basic Environments, Natali Majoras
Theoretical Studies Of Benzoquinone Reactivity In Acidic And Basic Environments, Natali Majoras
Honors Theses
Quinones are a class of organic compounds containing a six-membered unsaturated ring with two carbonyl groups. They are biologically relevant mostly due to their ability to participate in redox reactions. Prior experiments in our lab showed that quinones can induce protein modifications that are pH dependent. In an acidic environment the modifications were less significant than in a basic environment. Previous computational studies have also been carried out to model, in neutral solutions, the reaction between various quinones and various amines. Various amine groups are used as a model for the amino group of lysine to represent protein modification. The …
Synthesis And Characterization Of Organometallic Complexes For Biological Imaging, Emily Stumbo
Synthesis And Characterization Of Organometallic Complexes For Biological Imaging, Emily Stumbo
Honors Theses
Luminescent transition metal complexes are of interest for biological imaging applications due to their unique photophysical properties including large Stokes shift, long fluorescence lifetimes, and tunable emission. Altering ligand structure is a useful way to manipulate the charge transfer (CT) and mixed character states that give these complexes their photophysical properties. A series of organometallic complexes containing ligands with externally facing nitrogens has been prepared and synthesized. Complexes of the form Pt (II)(tbbpy)(C2-py), Re(CO)3(N^N), Ir(C^N)2(N^N), and Ir(C^N)2(N^O) have been studied for their potential application as biological imaging agents. The goal of this project is to compare the properties of these …
The Impact Of Water Infrastructure Inequality On Marginalized Communities, Indra Khalsa
The Impact Of Water Infrastructure Inequality On Marginalized Communities, Indra Khalsa
Honors Theses
America’s current system of water infrastructure poses a threat not only to the environment but also to public health. The water crisis reveals the stark inequalities that exist from both an environmental justice and a social justice perspective. There is a growing concern that without adequate investment from federal resources, the problems related to this issue will only worsen the longer they are neglected. There is little information about how specific environmental and social factors combine with water infrastructure to create long-term infrastructure inequalities. However, this thesis explores the disparities in water infrastructure affordability, vulnerability patterns, and environmental hazards. It …
The Effects Of Dissolved And Suspended Solids On Freshwater Meiofauna, Jessica Cline
The Effects Of Dissolved And Suspended Solids On Freshwater Meiofauna, Jessica Cline
Honors Theses
Meiofauna include small-sized animals (< 1mm) distributed in all aquatic ecosystems on Earth, where they play fundamental trophic and ecological roles. The biodiversity of marine meiofauna and its links with anthropogenic activities is routinely investigated, however, freshwater communities are less known. This is particularly true for the Southeastern United States, which is greatly investigated and elected a hotspot of biodiversity for larger species but very little is known about the meiofauna. The purpose of this research is to reveal the biodiversity of meiofauna from the Tennessee River and test for potential correlations with anthropogenic activities. As a proxy for pollution, dissolved and suspended solids were considered in this study. The research hypothesis is that meiofaunal biodiversity would be affected by possible changes of dissolved and suspended solids in the water column. Possible mechanisms causing biodiversity shifts could be ascribed to osmotic stresses of animals to cope with variation in dissolved solids or, more indirectly, because different sunlight penetration caused by suspended solids would affect primary production. To test the hypothesis, water samples were collected from nine stations located along the Tennessee River in Hamilton County. Each station was visited three times, and, during each visit, environmental parameters (including dissolved and suspended solids) were measured. Meiofauna biodiversity (estimated as richness, community composition, and phylogenetic diversity) was revealed using a metagenomic approach. Statistical analyses were applied to test for possible correlations between the biodiversity estimates and the measured environmental parameters. Results show a high biodiversity of meiofauna with more than 200 amplicon-sequence variants distributed across 10 metazoan phyla. Environmental conditions are highly variable among stations and statistical analyses show that while both dissolved solids (TDS) and turbidity (suspended solids, NTU) did not significantly affect meiofauna biodiversity in the collected samples, various other water, and sediment metrics were found to be significant predictors of meiofauna biodiversity. In conclusion, the results of this project not only reveal for the first time the meiofauna biodiversity from the Tennessee River, but also suggest that meiofauna could be used as bioindicators for several anthropogenic activities in freshwater ecosystems.
Synthesis, Characterization, And Reactivity Of Organometallic Complexes For Catalytic Carbon-Hydrogen Bond Activation, Sophia Neglia
Synthesis, Characterization, And Reactivity Of Organometallic Complexes For Catalytic Carbon-Hydrogen Bond Activation, Sophia Neglia
Honors Theses
Styrene can be produced directly from benzene and ethylene through an atom economical oxidative hydroarylation process. In this process, an electrophilic homogeneous transition metal catalyst activates the C-H bond in benzene. I propose to explore this reaction in two fronts: 1) the synthesis of electron-poor trans-spanning bidentate pyridine ligands and 2) the computational study of pyridine-functionalized bidentate diimines. The trans-spanning ligand will utilize either a Ru(II) or Co(III) metallohinge with cis-coordinated 2-ethynylpyridine ligands. The complex [(p-cym)Ru(PMe3)(C2-2-py)2] (1) where (p-cym = para-cymene and C2-2-py = 2-ethynylpyridine) can be prepared from (p-cym)Ru(PMe3)(Cl)2 and HC2-2-py in the presence of lithium bis(trimethylsilyl)amide (LiHMDS). Complex …
Security Fatigue And Its Effects On Perceived Password Strength Among University Students, Chase Carroll
Security Fatigue And Its Effects On Perceived Password Strength Among University Students, Chase Carroll
Honors Theses
This study was performed with the goal of observing the effect, if any, that security fatigue has on students’ perceived strength of passwords. In doing so, it was hoped to find some correlation between the two that would help in establishing a measurable effect of the phenomenon in students. This could potentially aid organizational decision-makers, such as security policy writers and system admins, to make more informed decisions about implementing security measures. To achieve the goal of observing this fatigue and attempting to measure it, a survey was distributed to numerous students on the University of Tennessee at Chattanooga campus. …
The Effect Of The Apolipoprotein A1 (Apoa1): The Stability And Folding In Potassium Chloride Environment, Alexandra Paladian
The Effect Of The Apolipoprotein A1 (Apoa1): The Stability And Folding In Potassium Chloride Environment, Alexandra Paladian
Honors Theses
Healthy levels of potassium chloride (KCl) can significantly affect the workings of the cholesterol level of the human body and how they pertain to an individual person. The search for a better salt additive for the human diet can provide a better option for people who experience high cholesterol levels and heart disease. The study focuses on the experimental design of the Molecular Dynamic (MD) simulation of the Apolipoprotein A1 (APOA1) in the potassium ion solution environment to determine the stability and folding of the protein. The study also compares its data to the previous experimental design of chloride ions …
Simplifying The Creation Of Virtual Topologies Using Mpi Sessions, Tom Herschberg
Simplifying The Creation Of Virtual Topologies Using Mpi Sessions, Tom Herschberg
Honors Theses
As supercomputers have approached exascale performance, several scalability issues have emerged within MPI. These issues arise because MPI includes all processes in the World model, which consumes unacceptable amounts of time and resources at large scale. The Sessions model was developed to combat these issues by removing the requirement of MPI_COMM_WORLD, which provides a more scalable method of creating communication groups in large jobs. Additionally, the Sessions model enables the creation of virtual topologies directly from sets of processes allocated to the execution of a parallel application rather than building virtual topologies from an existing communication group such as MPI_COMM_WORLD. …
Understanding Shear Thinning Using Brownian Dynamics Simulation, Mackenzie Nicole Wall
Understanding Shear Thinning Using Brownian Dynamics Simulation, Mackenzie Nicole Wall
Honors Theses
In this work, we study the changes in structure during the shear thinning regime using Brownian Dynamics with a simple steady-state shear flow of binary charged colloidal suspension. Previous research has analyzed the viscosity, radial distribution, elasticity and plasticity of materials with rheo-SANS experimentation; however, less research has been conducted to replicate the experiment through computer simulations. With Brownian Dynamic Simulation, this study was able to reproduce the results obtained in a recent rheo-SANS experiment and it also explored the viscosity, radial distribution, elastic and plastic behavior of a system under different parameters. The comparison of simulated data with experimental …
Molecular Dynamic Simulation Of The Complex Folding Patterns Of Apolipoprotein A1 In Various Concentrations Of Potassium Chloride, Hannah Holmberg
Molecular Dynamic Simulation Of The Complex Folding Patterns Of Apolipoprotein A1 In Various Concentrations Of Potassium Chloride, Hannah Holmberg
Honors Theses
Apopliprotein or ApoA-1 is a complex lipoprotein that functions in the removal of cholesterol from the blood, removing cholesterol from the area around white blood cells and promoting the excretion of lipids through the lymphatic system. Previous research has found that ApoA-1 shows both folded and unfolded conformations depending on the concentration of NaCl in solution in the water around it. The protein was studied using molecular dynamics simulations. Once this state of equilibrium was reached, various structural properties of the protein were measured including the radius of gyration and the radial distribution function. The goal of the project was …
Applying Deep Learning For Cell Detection In Time-Lapse Microscopic Images, Jay Patel
Applying Deep Learning For Cell Detection In Time-Lapse Microscopic Images, Jay Patel
Honors Theses
The budding yeast Saccharomyces cerevisiae is an effective model for studying cellular aging. We can measure the lifespan of yeast cells in two ways: replicative and chronological lifespans. Chronological focuses on the time that a cell can survive. The replicative lifespan (RLS) is the number of cell divisions that a single mother cell can go through before ceases to be dividing. RLS is a measurement of individual cells and is more informative on the aging process than in chronological lifespan. Many genes that influence yeast RLS have been shown to be highly conserved and have a similar effect on aging …
Meta-Analysis Of Biological Research Literature, Evan Suggs
Meta-Analysis Of Biological Research Literature, Evan Suggs
Honors Theses
Comparative studies have been powerful tools in generating a broad understanding about the evolution of animal social systems but they currently rely on the slow, manual process of reading thousands of abstracts and papers from research databases. A web application was created for researchers conducting a comparative survey, in order to speed up their research. This web application automates the retrieval of research papers and their selection process. Using previously obtained data sets on the orders Artiodacytla and Lagomorph, a machine learning application was created to classify the papers. These techniques and tools should greatly increase the speed at which …
Hplc Detection Of Organic Gunshot Residues With Silicone Wristbands, Yelyzaveta Zuy
Hplc Detection Of Organic Gunshot Residues With Silicone Wristbands, Yelyzaveta Zuy
Honors Theses
The analysis of gunshot residue (GSR) is frequently used to aid in investigating firearm-related crimes. Typically, Scanning Electron Microscopy (SEM) is applied for inorganic analysis of elements such as lead, barium, and antimony to study GSR. However, heavy metal-free ammunition creates the need for a different type of approach. This research focuses on studying the potential of detecting organic gunshot residue (OGSR) collected with silicone wristbands through passive sampling. This study has been directed towards the development of an optimal High Performance Liquid Chromatography (HPLC) procedure for the detection and separation of five selected compounds typically found in OGSR. The …
Molecular Dynamics Simulations Of Apolipoprotein A1 In Ionic Liquids, Benjamin Smith
Molecular Dynamics Simulations Of Apolipoprotein A1 In Ionic Liquids, Benjamin Smith
Honors Theses
High-density lipoprotein function is essential for the healthy processing of fats in the blood. The function of these proteins is determined by their conformational structure of chains of amino acids. Certain ionic liquids have been shown to interact with individual amino acids to affect the tertiary shape of the protein. These interactions can disrupt the native hydrogen bonds between amino acids which can either promote folding or denaturing of the protein. Our work focused on apoA-1, a high-density lipoprotein that binds to cholesterol for efflux from the body. We studied this protein in different ion-based liquids with sodium, chloride, and …
Boundary, Costs And Trade-Offs In Reserve Design Systems, Justus Hurd
Boundary, Costs And Trade-Offs In Reserve Design Systems, Justus Hurd
Honors Theses
Due to limitations in funding and natural resources, it is infeasible to construct perfect reserve systems for large populations of critical species. For this project, our objective is to formulate a reserve design model that minimizes the distance between reserve sites meeting a threshold of biodiversity features subject to a species coverage constraints. Coupled with other spatial characteristics including reserve size and configuration, the boundary of a reserve system is of key importance. While positive area effects are gained when selecting additional sites, negative boundary length effects are also experienced. For example, it is costly to implement and maintain boundary …
Predictive Modeling Of Iphone 7 Charge Rates Using Least Squares Curve Fitting, Grace Cahill
Predictive Modeling Of Iphone 7 Charge Rates Using Least Squares Curve Fitting, Grace Cahill
Honors Theses
In a time where individuals depend on their cell phones, the need for a long lasting and quick charging battery life is imperative. As information regarding how long a battery can remained charged is highly advertised, there is no information regarding how long it would take for a dead phone battery to completely charge. This study determined the amount of time it will take an iPhone 7 to charge from 0% to 100% using the standard charging cable under four different charging conditions. The charge percentage was recorded every two minutes until it was fully charged with this process being …
Mathematical Modeling Of A Variable Mass Rocket’S Dynamics Using The Differential Transform Method, Ashwyn Sam
Mathematical Modeling Of A Variable Mass Rocket’S Dynamics Using The Differential Transform Method, Ashwyn Sam
Honors Theses
In this paper, the mathematical modelling of a rocket with varying mass is investigated to construct a function that can describe the velocity and position of the rocket as a function of time. This research is geared more towards small scale rockets where the nonlinear drag term is of great interest to the underlying dynamics of the rocket. A simple force balance on the rocket using Newton’s second law of motion yields a Riccati differential equation for which the solution yields the velocity of the rocket at any given time. This solution can then be integrated with respect to time …
Edge Effects And Diversity Of Understory And Canopy Cloud Forest Beetles, Mallory Barbier
Edge Effects And Diversity Of Understory And Canopy Cloud Forest Beetles, Mallory Barbier
Honors Theses
Habitat fragmentation results in edge effects— changes in diversity and community composition along high-contrast forest edges. To date, a study of edge effects on beetle diversity has not been performed in tropical cloud forests, and few studies compare communities at both understory and canopy levels. Using bottle traps, I sampled canopy and understory beetle communities in a tropical lower montane cloud forest of Monteverde, Costa Rica across three distances (edge- 15 m, middle- 100 m, far- 205 m) along an edge-to-interior transect into the forest. According to the Shannon-Weiner diversity index, the site with the most diversity was the middle …
Preparation Of Organometallic Cobalt(Iii) Complexes Containing Bidentate Chiral Amine Ligands As Potential Transfer Hydrogenation Catalysts, Luccas C. Do Carmo
Preparation Of Organometallic Cobalt(Iii) Complexes Containing Bidentate Chiral Amine Ligands As Potential Transfer Hydrogenation Catalysts, Luccas C. Do Carmo
Honors Theses
Mixed coordination sphere cobalt(III) complexes containing a chiral bidentate amine ligand and an organic carbocyclic ligand have been prepared and characterized. The integration of this mixed ligand environment involving an organometallic and Werner-type ligand along with the earth abundant metal in a high oxidation state has the potential for interesting reactivity. Complexes of the type [Co(CpR)(X-DPEN)(I)](I), where CpR = cyclopentadienyl (Cp, R = H) or pentamethylcyclopentadienyl (Cp*, R = Me) and X = meso-1,2-, 1R,2R-, and 1S,2S-, have been prepared by ligand substitution from [Co(CpR)(I)2(CO)] with 1,2-diphenyletheylenediamine (DPEN). The outer sphere iodide is readily exchangeable with sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (NaBArF) or …