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Wright State University

Oxidation

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Full-Text Articles in Physical Sciences and Mathematics

A Lab To Stemulate Undergraduate Students Into Science, Technology, Engineering And Mathematics Majors, Nicole Lynn Speelman Jan 2009

A Lab To Stemulate Undergraduate Students Into Science, Technology, Engineering And Mathematics Majors, Nicole Lynn Speelman

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The central focus is the development and implementation of a research/lab module for first year chemistry courses. Electrochemical techniques are utilized to study oxidation and reduction reactions of neurotransmitters with a poly(2,2'-Bithiophene) modified electrode. The goal is to excite students about chemistry and encourage them to continue studies in Science, Technology, Engineering, and Mathematics (STEM) during their undergraduate education. The lab module was created for Project REEL (Research Experiences to Enhance Learning) and will be illustrated with results typically obtained by students. The experiment is inquiry-based, which includes challenging questions students have to do collaboration and research to answer, as …


Comparison Of The Electrochemical Properties Of Ethanol In Perchloric Acid And Ionic Liquids, Sandra Felix-Balderrama Jan 2009

Comparison Of The Electrochemical Properties Of Ethanol In Perchloric Acid And Ionic Liquids, Sandra Felix-Balderrama

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1-Ethyl-3-Methylimidazolium Tetrafluroborate (EMImBF4) and 1-Ethyl-3-Methylimidazlium Bis(trifluoromethanesulfonyl)imide (EMImTFSI) ionic liquids were synthesized and characterized in order to study the electrochemical oxidation of ethanol in these ionic liquids on a platinum surface electrode.

It was found that pure EMImBF4 exhibits an electrochemical window of 4.4 V,while EMImTFSI exhibits an electrochemical window of 5.0 V.

Electrochemical study of ethanol in perchloric acid showed that the oxidation of ethanol strongly depends on the concentration of ethanol and on the temperature of the solution. The poisoning of the platinum electrode only depends on the concentration of ethanol. At a low concentration of …


Wet Chemical Digital Etching Of Gaas At Room Temperature, Gregory C. Desalvo, Christopher A. Bozada, John L. Ebel, David C. Look, John P. Barrette, Charles L. A. Cerny, Ross W. Dettmer, James K. Gillespie, Charles K. Havasy, Thomas J. Jenkins, Kenichi Nakano, Carl I. Pettiford, Tony K. Quach, James S. Sewell, G. David Via Jan 1996

Wet Chemical Digital Etching Of Gaas At Room Temperature, Gregory C. Desalvo, Christopher A. Bozada, John L. Ebel, David C. Look, John P. Barrette, Charles L. A. Cerny, Ross W. Dettmer, James K. Gillespie, Charles K. Havasy, Thomas J. Jenkins, Kenichi Nakano, Carl I. Pettiford, Tony K. Quach, James S. Sewell, G. David Via

Physics Faculty Publications

A new room temperature wet chemical digital etching technique for GaAs is presented which uses hydrogen peroxide and an acid in a two‐step etching process to remove GaAs in approximately 15 Å increments. In the first step, GaAs is oxidized by 30% hydrogen peroxide to form an oxide layer that is diffusion limited to a thickness of 14 to 17 Å for time periods from 15 to 120 s. The second step removes this oxide layer with an acid that does not attack unoxidized GaAs. These steps are repeated in succession until the desired etch depth is obtained. Experimental results …