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Full-Text Articles in Physical Sciences and Mathematics
The Formation Of Prenucleation Clusters For Calcium Fluoride, Taylor M. Muterspaw
The Formation Of Prenucleation Clusters For Calcium Fluoride, Taylor M. Muterspaw
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There have been limited studies on the analysis of the nucleation and precipitation behind calcium fluoride. Earlier studies support a nucleation mechanism in agreement to classical nucleation theory (CNT) in which a surface nucleation mechanism is required for calcium fluoride. This experiment devised using the ISE method to calcium fluoride to find evidence of a nucleation mechanism like that of calcium carbonate (prenucleation cluster pathway). The potential and pH were recorded versus time and the potential data was converted to nCa2+ data of free calcium ions. It was determined that there was evidence of a similar nucleation mechanism for calcium …
Internal Loading Of Nitrogen (N) And Phosphorus (P), Reduced N Forms, And Periodic Mixing Support Cyanobacterial Harmful Algal Blooms (Habs) In Shallow, Eutrophic Honeoye Lake (New York, Usa), Justin Adam Myers
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Cyanobacteria are important primary producers, but large cyanobacterial harmful algal blooms (HABs) have many negative ecological and health impacts and are becoming increasingly common. Honeoye Lake (New York, USA) is a shallow, eutrophic lake characterized by increasingly frequent HABs. Nitrogen (N) and phosphorus (P) loads often drive HABs in lakes, and sediment processes can contribute to N removal (e.g., denitrification) or loading (e.g., N fixation, remineralization). Sediment cores and lake water were collected during May–October (2016–2018) at two sites and incubated with no amendments (controls) or 15N stable isotopes to measure sediment nutrient fluxes and N cycling dynamics in Honeoye …
Removal Of Select Chlorinated Hydrocarbons By Nanoscale Zero-Valent Iron Supported On Powdered Activated Charcoal, Md Abu Raihan Chowdhury
Removal Of Select Chlorinated Hydrocarbons By Nanoscale Zero-Valent Iron Supported On Powdered Activated Charcoal, Md Abu Raihan Chowdhury
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Nanoscale Zero Valent Iron (NZVI) has shown limited effectiveness in degrading chlorinated hydrocarbons (CHCs), like 1,1,1-Trichloroethane (1,1,1-TCA) and Trichloroethene (TCE), in aqueous solution. A rapid agglomeration behavior of NZVI particles due to van der waals and magnetic forces can negatively impact its overall effectiveness due to increase in particle size, and decline in CHC degradation kinetics. Different support materials, such as clays and activated carbon, have been used to stabilize NZVI particle and reduce agglomeration in aqueous solution. In this bench-scale study, NZVI supported on Powdered Activated Charcoal (PAC) was selected to prepare a composite, called PAC/NZVI, for a more …
Hydrothermal Atomic Force Microscopy Investigation Of Barite Growth: The Role Of Spectator Ions In Elementary Step Edge Growth Kinetics And Hillock Morphology, Sarah A. Jindra
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To better understand the role of spectator ions in barite growth, the kinetics of step edge growth on barite (001) surfaces were studied under various salt solutions. Hydrothermal Atomic Force Microscopy (HAFM) was used to investigate the effect of background electrolytes (NaCl, NaBr and NaNO3) as a function of saturation index and ionic strength (I) on barite growth sourced at dislocations at 108 oC. Results show that hillock morphology is affected by I, as well as type of anion, where the prevalence of steps aligned on the [010] direction is highest under Cl- …
Hydrothermal Atomic Force Microscopy Investigation Of Barite Growth: The Role Of Spectator Ions In Elementary Step Edge Growth Kinetics And Hillock Morphology, Sarah A. Jindra
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To better understand the role of spectator ions in barite growth, the kinetics of step edge growth on barite (001) surfaces were studied under various salt solutions. Hydrothermal Atomic Force Microscopy (HAFM) was used to investigate the effect of background electrolytes (NaCl, NaBr and NaNO3) as a function of saturation index and ionic strength (I) on barite growth sourced at dislocations at 108 oC. Results show that hillock morphology is affected by I, as well as type of anion, where the prevalence of steps aligned on the [010] direction is highest under Cl- There is a modest increase in kinetic …
Accelerated Degradation Of Chlorinated Solvents By Copper-Modified Nanoscale Zero Valent Iron (Cu-Nzvi) Stabilized With Carboxymethyl Cellulose, Andrew Franze
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Nanoscale zero valent iron (nZVI) is a remediation technology that can be used to treat chlorinated hydrocarbons (CHCs) in contaminated aquifers. Nanoparticles remain mobile in water and can be transported with groundwater flow to contaminated zones. However, due to magnetic and van der Waals forces, unstabilized nZVI agglomerates. Carboxymethylcellulose (CMC) was used as a polyelectrolyte stabilizer in this study. nZVI serves as an electron donor and can dechlorinate CHCs. nZVI reactivity with CHCs can be enhanced by addition of a secondary metal catalyst. This study evaluates the potential of copper amended nZVI (Cu-nZVI) to degrade select CHCs. The objective of …
Hydrogeochemistry And Water Quality Of Echo Hills, Joel M. Kimball
Hydrogeochemistry And Water Quality Of Echo Hills, Joel M. Kimball
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Ground water of the Echo Hills area in Clark County, Ohio was investigated for common water contaminants such as nitrate and coliform bacteria. Thirty-four water samples were collected from locations including private wells, streams and a spring. Nine of those samples were selected for nitrogen isotope analysis. Three locations were chosen for a tracer test. Additionally, well log data, historical water quality data, and GIS data were obtained from the Clark County Health Department in Springfield, Ohio. Results show that local agriculture likely has the greatest impact on ground water quality in Echo Hills especially the north-eastern portion, with local …