Physical Sciences and Mathematics Commons^™

Contaminant Transport Mechanisms And Source Tracking In Karst Groundwater Systems Under Agricultural Land Use, Shreya Pandey

Masters Theses & Specialist Projects

Karst areas in general face severe groundwater contamination problems that can degrade their water quality. In comparison to other landscapes, groundwater within karst regions is more susceptible to contamination. The situation gets worse when agriculture is practiced in these karst regions, because the nutrients and bacteria like nitrates and E. coli (Escherichia coli) are released into the groundwater systems which contaminate the water quality of those karst groundwater systems. This research aims to study the impacts of these contaminants, specifically nitrates and E. coli., by identifying the contaminant transport mechanisms and source tracking of these contaminants in the groundwater under …

Polygenetic Cave Sedimentation And Speleogenesis In The Mccloud Limestone Of Northern California, Niles Lathrop

Masters Theses & Specialist Projects

Caves in the Permian-aged, McCloud Limestone of the Klamath Mountains of Northern California preserve a diverse range of clastic sediments that represent broad-scale variations in paleo-hydrologic conditions and transport mechanisms that hint at varied modes of speleogenesis through local landscape development. Caves in the McCloud Limestone exhibit a range of cave passage geometries and arrangements that suggests periods of both hypogene and epigene cave development through temporal and spatial scales. This study evaluates the variability in the distribution, mineralogy, and transport mechanisms of clastic-cave sediments in seven hydrologically-distinct caves in the McCloud Limestone to establish relationships between clastic-cave sedimentation and …

Comprehensive Climate Vulnerability Assessment Of A Regional Karst Landscape For Hazard Mitigation Planning, Kara Brunot

Masters Theses & Specialist Projects

Climate change is the global phenomena affecting all sectors of society by creating conditions more conducive for the occurrence of extreme weather events. It is projected that the intensity and frequency of events will increase. Flooding, in particular, is projected to increase in frequency due to more intense precipitation events. Karst landscapes are especially vulnerable to climate change impacts because of their unique hydrology and geology. Karst flooding is most likely to occur from prolonged or intense rain events, which climate change will likely make more feasible. Areas are disproportionately affected by climate change due to population demographics and environmental …

Development And Application Of The Sinkhole Hazard Risk Index To Inform Karst Policy And Mitigation Planning, Meghan Puente

Masters Theses & Specialist Projects

Sinkholes are geologic hazards that occur in karst landscapes and can be highly destructive and costly. Sinkhole mitigation plans and development policies are nonexistent at the federal level within the United States and vary significantly at the state level. The lack of a unified standard for sinkhole mitigation planning is partly due to a lack of available data and resources needed to assess sinkhole risk. While there are established sinkhole assessments within the literature, they focus more on the detection and prediction of sinkholes rather than a holistic approach to risk assessment. The goal of this study is to create …

Perceptions And Visual Awareness Of Urban Karst Flooding To Inform Preparedness Planning And Management Actions, Grace Hermann

Masters Theses & Specialist Projects

Awareness and perception of flooding can heavily affect how an individual or community prepares for flooding. Flood awareness can be affected by factors like past flood experience and demographics. Flood experience and demographics can affect flood awareness differently based on factors including the types and cause of flooding. Flooding in karst landscapes can vary from other types of flooding and neither perception nor awareness of karst flooding has been directly studied before. This study explored both expert and non-expert flood awareness and perception and flood policies in a karst landscape through interviews with experts, surveys, and cognitive mapping activities. The …

Two New Baseball Performance Statistics, Charles H. Smith

Faculty/Staff Personal Papers

Ever since I was a small child I have been interested in both statistics and baseball, so I guess it was inevitable I would eventually find a way to put the two together. In this short note I'd like to suggest a pair of measures that I feel might be useful in interpreting quality of play: one focusing more on hitting, the other on pitching. Let's start with the one concerning hitting.

Synthesis And Characterization Of A Zirconium (Zr) Thin Film On Si(100) Via Pulsed Laser Deposition, Zikrulloh Khuzhakulov

Masters Theses & Specialist Projects

This study investigates the synthesis and characterization of zirconium (Zr) thin films deposited on Si(100) substrates using pulsed laser deposition (PLD). The effects of two laser wavelengths (1064 nm and 532 nm), various substrate temperatures (25 °C, 300 °C, and 500 °C), and different laser fluences (0.25, 0.5, 1.0 J/cm²) on the properties of the Zr films were examined. Results indicated that smoother films were achieved with the 1064 nm wavelength, while surface roughness increased with higher fluences. Optimal crystalline films were obtained at a substrate temperature of 300 °C for both wavelengths. X-ray diffraction (XRD), scanning electron microscopy (SEM), …

Surface Patterning On Zirconia Dental Implants Via Laser-Induced Shockwave Imprinting, Inomjon Majidov

Masters Theses & Specialist Projects

Zirconia is rapidly becoming a preferred alternative to titanium in dental applications, primarily due to its aesthetic resemblance to natural teeth. This material’s tooth-like color avoids the aesthetic issues associated with the grey metal tint of titanium implants. Additionally, zirconia is hypoallergenic, making it an ideal choice for patients with metal sensitivities or allergies. Despite these advantages, zirconia generally exhibits lower biocompatibility and osseointegration compared to titanium implants. This study investigates laser-assisted, controlled imprinting technique on zirconia surfaces to enhance these properties. Our research used zirconia pellets, produced from powdered monoclinic zirconia pressed in a pellet press machine. Two methods …

Landuse And Microplastic Transport In Karst Groundwater Of South-Central Kentucky, Katie Norman

Masters Theses & Specialist Projects

Groundwater in karst areas is susceptible to contamination from various sources of pollution. Microplastics are a prevalent source of pollution entering groundwater. This study examines karst groundwater in three areas of investigation. One point of interest is an area that is impacted by urban activities, the Lost River Groundwater Basin, which includes water drainage from the City of Bowling Green, Kentucky. Another study location is Great Onyx (GO) Spring, which is a part of the Great Onyx Groundwater Basin located in Mammoth Cave National Park, Kentucky, and that is relatively unimpacted by urban activities. The third point of interest is …

Evaluating Stormwater Erosion Prevention And Sediment Control Best Management Practices Using High-Resolution Rainfall Monitoring And Field-Based Assessment Tools, Brittany Pekara

Masters Theses & Specialist Projects

Advancing stormwater management methods and technology is critical as runoff from impermeable surfaces increases with urbanization and development. Stormwater runoff is highly susceptible to contamination from non-point source pollution and causing flood impacts following rain events, which varies spatially and temporally in an urban landscape. To counteract the impacts of contamination and drainage issues, Best Management Practices (BMPs) are implemented to reduce the effects of stormwater runoff; however, the unpredictable nature of storm events can make methods for effectively monitoring impacts difficult in trying to capture first flush inputs, flood threats, and sedimentation sources. This research utilizes a highresolution rainfall …

A Flood Of Consequences In Louisville, Kentucky: Using Hgis To Track Refugees Impacted By The 1937 Ohio River Flood, Trevor Harry

Masters Theses & Specialist Projects

The Ohio River flood of 1937 was the most devastating flood in the recorded history of the Ohio River Valley and is commonly referred to as the “Great Flood of 1937”. In January 1937, after nearly two months of continuous precipitation, over 60% of the city of Louisville, Kentucky, was flooded and at least 23,000 residents were displaced. The purpose of this research was to document, map, and compare the pre-flood residential locations, evacuation destinations, and post-flood residential locations of African American and White Louisville refugees from the 1937 Ohio River flood. Socioeconomic information from the manuscript versions of the …

The Role Of Efflux Pump Inhibitor In Enhancing Antimicrobial Efficiency Of Silver Nanoparticles And Methylene Blue As An Effective Photodynamic Therapy Agent, Yaran Allamyradov

Masters Theses & Specialist Projects

Efflux pumps are critical active transport systems utilized by cells to expel toxic substances, including antibiotics and photosensitizer complexes, thereby contributing to antimicrobial resistance. Efflux pump inhibitors (EPIs), which are compounds that obstruct the transport of molecules through these pumps, play a pivotal role in enhancing the effectiveness of antimicrobial therapies against pathogens. This study investigates the effects of the EPI reserpine on the photodeactivation rate of pathogens when used in conjunction with silver nanoparticles (Ag NPs) and methylene blue (MB), a common photosensitizer.

Our research reveals that the application of reserpine, in combination with Ag NPs and MB, leads …

Catalytic Hydrogenation Of Co2 In Water And Ionic Liquids Using Platinum On Carbon, Kristin Collins

Masters Theses & Specialist Projects

Platinum-on-carbon (Pt/C) is a commercially-available catalyst that has been used in the literature to benchmark the performance of catalysts produced using platinum/cobalt alloy nanoparticles. Initially, we intended to build upon this example by synthesizing shape-controlled platinum/cobalt alloy nanoparticles in ionic liquids and compare their ability to catalyze the hydrogenation of CO₂ to methanol against Pt/C as a benchmark, with the idea that ionic liquids may improve catalysis. However, we found that Pt/C was unable to catalyze the hydrogenation of CO₂ to methanol. In an attempt to track the source of this discrepancy, Pt/C was characterized using thermogravimetric analysis …

Western Kentucky University Stormwater Utility Survey 2024, Warren Campbell

SEAS Faculty Publications

The main goal of this survey is to identify as many U.S. Stormwater Utilities (SWUs) as possible. Because many stormwater professionals do not have the time to respond to questionnaires, our primary method of identification was Internet searches. We searched key terms such as “stormwater utility,” “stormwater fee,” and “drainage fee.” We scoured online municipal codes such as Municode, AmLegal, Sterling, LexisNexis, General Code, and others. We searched through many city web websites to find utilities. We have also had many people contact me to update fees and identify new utilities. However, the data primarily comes from Internet sources and …

Grey Relational Analysis And Canonical Correlation Analysis Of Air Pollution In Three Kentucky Counties, Sarah Hartman

Masters Theses & Specialist Projects

Air pollution is a crucial factor that affects both the environment and public health. Various methods are available for assessing air quality and pollution levels, such as regression models, principal component analysis, and factor analysis tools. However, some of these methods present issues in multicollinearity and the nature of collected data. It is important to recognize that air pollution data is often uncertain, incomplete, and contains limited valid data points. Weather conditions and economic activities are also factors that can affect air pollution. With growing communities in Kentucky (KY), it is essential to address these factors as the state has …

Exploring The Role Of Gender, Race, First-Year College Gpa And Passing Stem Advanced Placement Exams And The Likelihood Of Graduating With A Stem Degree: A Multiple Logistic Regression Analysis, Amar Patel

Masters Theses & Specialist Projects

Science, Technology, Engineering, and Mathematics (STEM) careers are projected to grow beyond the normal pace of job growth (Bureau of Labor Statistics, 2021). Many of these careers will require degrees in STEM fields, but, currently, there is a significant underrepresentation of Blacks and females in both STEM degree programs and careers. The purpose of the current quantitative study was to explore the strength of the association between AP Exams, first-year GPA, race, and gender in science achievement. Research Question 1 investigated the relationship between taking AP Exams and the time taken to graduate. For students who took an AP Exam, …

Development Of An Enhanced Sampling Workflow To Accelerate Molecular Docking With Sparse Biophysical Information, Zachary Stichter

Masters Theses & Specialist Projects

Rapid docking of flexible biological macromolecules remains a significant open challenge in protein structure determination. While rigid docking is relatively simple with toolkits such as TagDock, a key obstacle to rapid flexible docking is the complexity and roughness of the free energy surface associated with protein conformational motion (often termed the many-minima problem), meaning conventional molecular dynamics methods do not effectively sample protein conformations near the interaction complex in accessible timescales. Methods such as metadynamics and replica exchange molecular dynamics exist to ameliorate this obstacle, yet these methods use nonphysical biases or random swaps to enhance sampling. In contrast, high …

Synthesis Of Gold Nanoparticles Via Pulsed Liquid Ablation For Use In The Photodynamic Therapy Of Bacteria, Justice Ben Yosef

Masters Theses & Specialist Projects

With the ever-increasing threat of antibiotic resistant bacteria, alternative treatment methods have been developed including photodynamic therapy (PDT). Within the PDT process, photosensitizers are used to generate reactive oxygen species (ROS) and facilitate the cell termination process. This work lays the conceptual foundation for the functionalization of the photosensitizer methylene blue (MB) with gold nanoparticles (AuNPs) and INF-55 as a potential inhibitor of the AcrAB-TolC efflux pump to enhance the effectivity of the PDT process.

AuNPs were synthesized using pulsed laser ablation in an aqueous citrate solution. Both nanosecond and picosecond pulse durations, as well as both 532 nm and …

Alfred Russel Wallace Notes 29. Extraterrestrial Entertainment: Are We Being Monitored By Alien Beings?, Charles H. Smith

Faculty/Staff Personal Papers

Alfred Russel Wallace (1823−1913) was an early advocate for the rational assessment of likelihood of extraterrestrial life. Current efforts to evaluate the situation have ranged from the heavily self-indulgent to the more objective, and it is still often difficult to decide just how much of the information we are receiving on the subject is dependable. An attempt is made here to cut through the haze and reduce the matter to elementals.

Dice Are Blessed Or Cursed, Warren Campbell, Cameron Miller

SEAS Faculty Publications

Dice are cursed or blessed; that is, they roll low or high, but they are never fair. They cannot be manufactured with uniform density and geometric precision. This is particularly true of 20-sided dice or D20s. Faces are smaller than 6-sided dice, and manufacturing tolerances are similar. However, some dice are fairer than others. In our studies of plastic-mold dice about 1 in 4 test fair in 3000 rolls. We have used different statistical tests, including chi-square, modified Kolmogorov Smirnov, and double binomial tests. Of these, the method that consistently performed better is the chi-square goodness of fit test. The …

The Effect Of Ions On The Adsorption Of So2 On A Water Nanoparticle, Nathaniel W. Gillispie

Mahurin Honors College Capstone Experience/Thesis Projects

Secondary Organic Aerosols (SOAs) have been of interest to atmospheric chemists for their harmful effects on human health and implications for climate change. Here, we explore a likely system from the early stages of SOA formation. Using compu- tational methods, water nanoparticles with and without ions were simulated. We observe the effects of ions on the adsorption of SO2 on this system. SO2 in the at- mosphere is associated with greater production of SOAs, so its study is important to SOA formation. We find that the overall structure of water is the most important observable affecting the location of SO2 …

Groundwater Vulnerability Assessment And Dye Trace Of War Fork River In Daniel Boone National Forest, Will Hemenover

Mahurin Honors College Capstone Experience/Thesis Projects

Daniel Boone National Forest plays a key role in preserving much of Kentucky’s karst regions, natural resources including timber, mineral deposits, and biodiversity, including over 300 species of concern. The health of these environments is determined by surface and groundwater streams in the forest, and karst systems are an integral environment where these systems are active. War Fork, a tributary to the Kentucky River in Jackson County, Kentucky, is a remote and understudied hydrologic system in the Daniel Boone National Forest that contains recreational and logging land uses. Due to karst areas being susceptible to contamination because of rapid water …

The Socialization Of Social Media: Examining The Impact Of Social Media Use On Interpersonal Skills During Face-To-Face Interaction, Tenille Thomas

Masters Theses & Specialist Projects

Research has well established that the use of social networking sites (SNS) has increased accessibility and connectivity to people with limitless boundaries. SNS have progressively become the preferred source of communication. However, often overlooked is the impact SNS use has on face-to-face interactions, specifically on interpersonal skills. The purpose of this study was to examine the relationship between SNS use and face-to-face interaction. Specifically, this study examines the participant’s ability to recognize and interpret nonverbal cues with increased SNS use. This was a correlational study utilizing a quantitative design of self-reported questionnaires. A total of 178 participants, ranging in age …

Pollutant Forecasting Using Neural Network-Based Temporal Models, Richard Pike

Masters Theses & Specialist Projects

The Jing-Jin-Ji region of China is a highly industrialized and populated area of the country. Its periodic high pollution and smog includes particles smaller than 2.5 μm, known as PM2.5, linked to many respiratory and cardiovascular illnesses. PM2.5 concentration around Jing-Jin-Ji has exceeded China’s urban air quality safety threshold for over 20% of all days in 2017 through 2020.

The quantity of ground weather stations that measure the concentrations of these pollutants, and their valuable data, is unfortunately small. By employing many machine learning strategies, many researchers have focused on interpolating finer spatial grids of PM2.5, or hindcasting PM2.5. However, …

Index Bucketing: A Novel Approach To Manipulating Data Structures, Jeffrey Myers

Masters Theses & Specialist Projects

Handling nested data collections in large-scale distributed systems poses considerable challenges in query processing, often resulting in substantial costs and error susceptibility. While substantial efforts have been directed toward overcoming computation hurdles in querying vast data collections within relational databases, scant attention has been devoted to the manipulation and flattening procedures necessary for unnesting these data collections. Flattening operations, integral to unnesting, frequently yield copious duplicate data and entail a loss of information, devoid of mechanisms for reconstructing the original structure. These challenges exacerbate in scenarios involving skewed, nested data with irregular inner data collections. Processing such data demands an …

Landscape/Atmosphere Interactions And Carbon-Dioxide Dynamics In The Great Onyx Groundwater Basin, Mammoth Cave National Park, Kentucky, Meghan Raines

Masters Theses & Specialist Projects

An increase in atmospheric CO2 since the Industrial Revolution has altered rates of global climate change and has motivated a need to better quantify the flux of carbon between Earth’s reservoirs. Attempts to quantify the exchange of atmospheric carbon between sources and sinks have led to an increasing interest in the terrestrial landscape, including the continental carbon sink associated with carbonate-mineral dissolution. This research sought to better inform an understanding of karst landscapes and their relationship with global climate change through carbon cycling. The study utilized high-resolution data collection of pH, temperature, and specific conductance of waters in the Cascade …

Liquid Chromatography Mass Spectrometry Method Development For The Determination Of Β–Defensins In Bovine Milk, Elisha Ogbebor

Masters Theses & Specialist Projects

Bovine mastitis is caused by a wide range of pathogens which results in a substantial economic loss for the dairy cattle livestock industry. β-defensins are a part of the innate immune system and act as the first line of defense against mastitis in bovine. β-defensins (~6- 10kDa) are antimicrobial peptides that contain about 28 to 67 amino acids, the presence of six cysteine residues results in their three disulfide bonds and a β-sheet structure. A few β- defensins have been identified in cows based on the site of occurrence and time of expression in tissue, but not in milk. A …

Towards The Quantification Of Estrone And 17Β-Estradiol Conjugates In Dairy Cattle Urine Sorptive Stir Bar Extraction And Gas Chromatography-Mass Spectometry, S.M. Istiak Ahmed

Masters Theses & Specialist Projects

The global concern regarding the presence of compounds with estrogenic properties in the environment has grown significantly. Endocrine-disrupting compounds (EDCs) are environmental pollutants that disrupt the endocrine systems of both wildlife and humans. Estrogens, with their potent estrogenic effects, are particularly noteworthy among the various substances with endocrine-disrupting properties. They are of concern due to their prevalence in the environment, especially due to dairy waste contamination. These lipophilic compounds can accumulate in livestock fat tissues, potentially entering the human food chain. Sulfated forms of estrone and β- estriol, which exhibit a higher degree of saturation than their non-conjugated counterparts, have …

Bioactivity And Structural Properties Of Hydroxyapatite On Ti6a|4v And Si(100) Surfaces By Pulsed Laser Deposition, Salizhan Kylchbekov

Masters Theses & Specialist Projects

Although biomedical implant technology is very advanced, there are still caveats in terms of biocompatibility properties because metals are inert to biological processes such as osseointegration, cell growth, and cell adhesion. This results in statistically significant complications and opens rooms for improvements. Among many techniques to improve this problem, coating the metal surface with biologically functional materials has resulted in the best performances. Hydroxyapatite (HAP), Ca_₁₀(PO_₄)_₆(OH)_₂, is the most stable form of calcium phosphates in human body environment and is functional in key processes such as ion exchange, osteoblast (bone cells) formation, …

Adaptable Object And Animation System For Game Development, Isaiah Turner

Masters Theses & Specialist Projects

In contemporary times, video games have swiftly evolved into a prominent medium, excelling in both entertainment and narrative delivery, positioning themselves as significant rivals to traditional forms such as film and theater. The burgeoning popularity of gaming has led to a surge in aspiring game developers seeking to craft their own creations, driven by both commercial aspirations and personal passion. However, a common challenge faced by these individuals involves the considerable time investment required to acquire essential skills and establish a foundational framework for their projects. Accessible game development engines that offer a diverse range of fundamental features play a …