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Full-Text Articles in Physical Sciences and Mathematics

Exploring The Association Of Brownfield Remediation Status With Socioeconomic Conditions In Wayne County, Mi, Brendan F. O'Leary, Alex B. Hill, Colleen Linn, Mei Lu, Carol J. Miller, Andrew Newman, F. Gianluca Sperone, Qiong Zhang Apr 2023

Exploring The Association Of Brownfield Remediation Status With Socioeconomic Conditions In Wayne County, Mi, Brendan F. O'Leary, Alex B. Hill, Colleen Linn, Mei Lu, Carol J. Miller, Andrew Newman, F. Gianluca Sperone, Qiong Zhang

Urban Studies and Planning Faculty Research Publications

Urban neighborhoods with locations of environmental contamination, known as brownfields, impact entire neighborhoods, but corrective environmental remedial action on brownfields is often tracked on an individual property basis, neglecting the larger neighborhood-level impact. This study addresses this impact by examining spatial differences between brownfields with unmitigated environmental concerns (open site) and sites that are considered fully mitigated or closed in urban neighborhoods (closed site) on the US census tract scale in Wayne County, MI. Michigan’s Department of Environment, Great Lakes, and Energy’s leaking underground storage tank (LUST) database provided brownfield information for Wayne County. Local indicators of spatial association (LISA) …


Combination Of High Specific Activity Carbon-14 Labeling And High Resolution Mass Spectrometry To Study Pesticide Metabolism In Crops: Metabolism Of Cycloxaprid In Rice, Dahang Shen, Zhijiang Lu, Jiayin Zhong, Sufen Zhang, Qingfu Ye, Wei Wang, Jay Gan Sep 2021

Combination Of High Specific Activity Carbon-14 Labeling And High Resolution Mass Spectrometry To Study Pesticide Metabolism In Crops: Metabolism Of Cycloxaprid In Rice, Dahang Shen, Zhijiang Lu, Jiayin Zhong, Sufen Zhang, Qingfu Ye, Wei Wang, Jay Gan

Environmental Science and Geology Faculty Research Publications

The study of pesticide metabolism in crops is critical for assessing the mode of action and environmental risks of pesticides. However, the study of pesticide metabolism in crops is usually complicated and it is often a daunting challenge to accurately screen the metabolites of novel pesticides in complex matrices. This study demonstrated a combined use of high-specific activity carbon-14 labeling and high-resolution mass spectrometry (HSA-14C-HRMS) for metabolism profiling of a novel neonicotinoid cycloxaprid in rice. By generating the characteristic radioactive peaks on the liquid chromatogram, the use of 14C can eliminate the severe interference of complex matrices …


Depositional Fluxes And Concentrations Of 7Be And 210Pb In Bulk Precipitation And Aerosols At The Interface Of Atlantic And Mediterranean Coasts In Spain, R. L. Lozano, E. G. San Miguel, J. P. Bolívar, M. Baskaran Sep 2011

Depositional Fluxes And Concentrations Of 7Be And 210Pb In Bulk Precipitation And Aerosols At The Interface Of Atlantic And Mediterranean Coasts In Spain, R. L. Lozano, E. G. San Miguel, J. P. Bolívar, M. Baskaran

Environmental Science and Geology Faculty Research Publications

Bulk depositional fluxes of 7Be and 210Pb in precipitation measured over a period of 16 months (April 2009–July 2010) in Huelva, Spain varied between 5.6 and 186 Bq m−2 month−1 (annual mean: 834 Bq m−2 year−1) and 0.8 and 8.1 Bq m−2 month−1 (annual mean: 59 Bq m−2 year−1), respectively, with the lowest depositional fluxes occurring during dry summer months. Quantitative evaluation of the precipitation-normalized seasonal depositional fluxes of 7Be and 210Pb indicates that the enrichment factor in winter is < 1.0 while in 2010 spring, it is significantly higher than 1, possibly indicating input of air from the stratosphere-troposphere exchange (for 7Be). The specific activities of …


Constraints On The Utility Of Mno2 Cartridge Method For The Extraction Of Radionuclides: A Case Study Using 234Th, M. Baskaran, P. W. Swarzenski, B. A. Biddanda Apr 2009

Constraints On The Utility Of Mno2 Cartridge Method For The Extraction Of Radionuclides: A Case Study Using 234Th, M. Baskaran, P. W. Swarzenski, B. A. Biddanda

Environmental Science and Geology Faculty Research Publications

Large volume (102–103 L) seawater samples are routinely processed to investigate the partitioning of particle reactive radionuclides and Ra between solution and size-fractionated suspended particulate matter. One of the most frequently used methods to preconcentrate these nuclides from such large volumes involves extraction onto three filter cartridges (a prefilter for particulate species and two MnO2-coated filters for dissolved species) connected in series. This method assumes that the extraction efficiency is uniform for both MnO2-coated cartridges, that no dissolved species are removed by the prefilter, and that any adsorbed radionuclides are not desorbed from …


Residence Times And Temporal Variations Of 210Po In Aerosols And Precipitation From Southeastern Michigan, United States, Daphne Mcneary, Mark Baskaran Feb 2007

Residence Times And Temporal Variations Of 210Po In Aerosols And Precipitation From Southeastern Michigan, United States, Daphne Mcneary, Mark Baskaran

Environmental Science and Geology Faculty Research Publications

Daughter products of 222Rn (such as 210Pb, half-life = 22.1 years, and 210Po, half-life = 138 days) have been widely used as tracers to determine the removal rates of aerosols as well to obtain analog information on the behavior of other chemical species in the lower atmosphere. To establish the first data set on the depositional fluxes of 210Po in bulk precipitation and concentrations in air samples from the midwestern United States, we measured the depositional fluxes of 210Pb and 210Po in the bulk (wet plus dry) and dry fallout by deploying a rain …


Depositional Characteristics Of 7Be And 210Pb In Southeastern Michigan, D. Mcneary, M. Baskaran Apr 2003

Depositional Characteristics Of 7Be And 210Pb In Southeastern Michigan, D. Mcneary, M. Baskaran

Environmental Science and Geology Faculty Research Publications

The depositional fluxes in the bulk and dry fallout as well as the concentrations of 7Be and 210Pb in aerosols were measured for a period of 17 months at Detroit, Michigan. The bulk depositional fluxes of 7Be and 210Pb varied between 3.11 and 63.0 dpm cm−2 yr−1 (mean of 11.4 dpm cm−2 yr−1) and 0.35 and 10.3 dpm cm−2 yr−1 (mean of 1.41 dpm cm−2 yr−1), respectively, and this variability in the depositional fluxes is attributed to the frequency and amount of precipitation and seasonal variations …


A Search For The Seasonal Variability On The Depositional Fluxes Of 7Be And 210Pb, M. Baskaran Feb 1995

A Search For The Seasonal Variability On The Depositional Fluxes Of 7Be And 210Pb, M. Baskaran

Environmental Science and Geology Faculty Research Publications

Investigations of the atmospheric fallout of 7Be and 210Pb in many places around the globe indicate that there are seasonal variations on the depositional fluxes of these nuclides: high in winter in a few places, while in most places the high occurs in spring. However, these earlier studies did not address quantitatively the corresponding seasonal variations of the amount of precipitation during these periods. Data on the depositional fluxes of 7Be and 210Pb in Galveston, Texas, during the years 1989–1991 indicate that the seasonal variation is not uniform from year to year, and the amount of …


Atmospheric Depositional Fluxes Of 7Be And 210Pb At Galveston And College Station, Texas, M. Baskaran, Charles H. Coleman, Peter H. Santschi Nov 1993

Atmospheric Depositional Fluxes Of 7Be And 210Pb At Galveston And College Station, Texas, M. Baskaran, Charles H. Coleman, Peter H. Santschi

Environmental Science and Geology Faculty Research Publications

The bulk depositional fluxes of 210Pb and 7Be were measured at a coastal (Galveston) and an inland (College Station) station for about 3 years, between 1989 and 1991. The annual depositional fluxes of 7Be and 210Pb at Galveston during this period varied by a factor of about 2.5, between 8.9 and 23.2 disintegrations per minute (dpm) cm−2 yr−1, with a mean of 14.7 dpm cm−2 yr−1 for 7Be, and 0.67 and 1.71 dpm cm−2 yr−1, with a mean of 1.03 dpm cm−2 yr−1 for 210 …


Environmental Radiocesium In Subarctic And Arctic Alaska Following Chernobyl, M. Baskaran, J. J. Kelley, A. S. Naidu, D. F. Holleman Dec 1991

Environmental Radiocesium In Subarctic And Arctic Alaska Following Chernobyl, M. Baskaran, J. J. Kelley, A. S. Naidu, D. F. Holleman

Environmental Science and Geology Faculty Research Publications

Radiocesium (¹³⁴ Cs and ¹³⁷ Cs) concentrations were measured in soil, plant and wildlife samples from subarctic to arctic Alaska. Concentrations of ¹³⁷ Cs ranged from below detectable or low levels in whale and fish samples to as high as 242 Bq/kg in lichen. For all potential human food items, the radiocesium concentrations measured in this study were below accepted permissible levels for human consumption. Chernobyl-derived radiocesium concentrations ranged from below detectable or low levels in all arctic samples (soil, sediment, lichen, whale, fish and caribou) to 32 Bq/kg in subarctic moss. Therefore the distribution and subsequent deposition of Chernobyl-derived …