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Full-Text Articles in Physical Sciences and Mathematics

Thermal Oxidation Of Silicon In A Home-Made Furnace System, Joshua Koskan Apr 2019

Thermal Oxidation Of Silicon In A Home-Made Furnace System, Joshua Koskan

Physics Capstone Projects

I approached Dr. Shen with a desire for a project in understanding how to manage and expand the capabilities of a laboratory. After some discussion, my senior project was to complete a gas and water chiller system to an existing furnace for chemical vapor deposition. It should be able to handle temperatures up to 1100 ºC, hold a vacuum to mTorr, be easy to move samples in and out of the furnace, and cost effective.


Oxidative Damage Caused By Iron Loading Into Ferritin, Talina Christensen Watts May 2006

Oxidative Damage Caused By Iron Loading Into Ferritin, Talina Christensen Watts

Undergraduate Honors Capstone Projects

Ferritin is the iron storage protein found in humans, animals, plants, fungi and bacteria. We are interested in how iron is loaded and stored in mammalian ferritin. Ferrous iron must be oxidized to ferric iron in order to be stored in ferritin. It is generally believed that ferritin does the loading itself, dependant upon a "ferroxidase activity." Oxidation of iron can result in the production of the hydroxyl radical which can cause oxidative damage to surrounding proteins and other biomolecules. An indicator of oxidative damage to proteins is the formation of carbonyl groups. Using only the H subunit of human …


Nanometer Scale Patterning And Oxidation Of Silicon Surfaces With An Ultrahigh Vacuum Scanning Tunneling Microscope, J. W. Lyding, G. C. Abeln, T. -C. Shen, C. Wang, J. R. Tucker Aug 1994

Nanometer Scale Patterning And Oxidation Of Silicon Surfaces With An Ultrahigh Vacuum Scanning Tunneling Microscope, J. W. Lyding, G. C. Abeln, T. -C. Shen, C. Wang, J. R. Tucker

T. -C. Shen

Nanoscale patterning of the Si(100)‐2×1 monohydride surface has been achieved by using an ultrahigh vacuum (UHV) scanning tunneling microscope(STM) to selectively desorb the hydrogen passivation. Hydrogen passivation on silicon represents one of the simplest possible resist systems for nanolithography experiments. After preparing high quality H‐passivated surfaces in the UHV chamber, patterning is achieved by operating the STM in field emission. The field emitted electrons stimulate the desorption of molecular hydrogen, restoring clean Si(100)‐2×1 in the patterned area. This depassivation mechanism seems to be related to the electron kinetic energy for patterning at higher voltages and the electron current for low …


Reduction Of N-Protected Amino Acids To Amino Alcohols And Subsequent Re-Oxidation To Original N-Protected Amino Acids, Val S. Goodfellow Jan 1981

Reduction Of N-Protected Amino Acids To Amino Alcohols And Subsequent Re-Oxidation To Original N-Protected Amino Acids, Val S. Goodfellow

Undergraduate Honors Capstone Projects

For the synthesis of certain molecules of interest in Dr. Richard Olsen's laboratory it was necessary to produce N-protected a-amino alcohols from N-protected amino acids and subsequently, after further synthesis steps, to oxidize the hydroxyl functionalities of these molecules back to carboxylic acids. A number of methods are known for the reduction of carboxylic acids to alcohols; several methods are also reported in the chemical literature for the oxidation of alcohols to carboxylic acids. The problem in finding a suitable general method, is that the amino acid side chains affect the re activity and chemistry differently in each specific case. …


Oxidation Of Thin Silver Films By Ozone And Atomic Oxygen, Lawrence R. Thorne Jan 1973

Oxidation Of Thin Silver Films By Ozone And Atomic Oxygen, Lawrence R. Thorne

Undergraduate Honors Capstone Projects

Recently, thin silver film detectors have been used to determine atomic oxygen profiles in the 70-100 km region of the upper atmosphere. The detectors' sensitivity to atomic oxygen is the result of the formation of silver oxide(s) which cause their electrical resistance to increase. A common procedure to calibrate and to make these detectors more sensitive is to cycle them through a series of three or more oxidations and reductions. This paper indicates that this cycling makes silver films more sensitive to ozone, causing them to be usable only at heights greater than 38 km. Also reported herein are experimentally …