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Full-Text Articles in Physical Sciences and Mathematics
Recent Progress On Synthesis, Multi-Scale Structure, And Properties Of Y-Si-O Oxides, Ziqi Sun, M S. Li, Y C. Zhou
Recent Progress On Synthesis, Multi-Scale Structure, And Properties Of Y-Si-O Oxides, Ziqi Sun, M S. Li, Y C. Zhou
Australian Institute for Innovative Materials - Papers
Yttrium silicates (Y-Si-O oxides), including Y2Si2O7, Y2SiO5, and Y4·67(SiO4)3O apatite, have attracted wide attentions from material scientists and engineers, because of their extensive polymorphisms and important roles as grain boundary phases in improving the high-temperature mechanical/thermal properties of Si3N4 and SiC ceramics. Recent interest in these materials has been renewed by their potential applications as high-temperature structural ceramics, oxidation protective coatings, and environmental barrier coatings (EBCs). The salient properties of Y-Si-O oxides are strongly related to their unique chemical bonds and …
Synthesis Of Hollow Geo2 Nanostructures, Transformation Into Geoc, And Lithium Storage Properties, Li Li, Kuok H. Seng, Chuanqi Feng, Hua-Kun Liu, Zaiping Guo
Synthesis Of Hollow Geo2 Nanostructures, Transformation Into Geoc, And Lithium Storage Properties, Li Li, Kuok H. Seng, Chuanqi Feng, Hua-Kun Liu, Zaiping Guo
Australian Institute for Innovative Materials - Papers
In this work, we synthesize mesoporous and hollow germanium@carbon nanostructures through simultaneous carbon coating and reduction of a hollow ellipsoidal GeO2 precursor. The formation mechanism of GeO 2 ellipsoids and the ratio of Ge4+ to Sn4+ as the starting materials are also investigated. Compared to the solid ellipsoidal Ge@carbon (Ge@C-3), the hollow ellipsoidal Ge@C-1 sample exhibits better cycling stability (100% capacity retention after 200 cycles at the 0.2 C rate) and higher rate capability (805 mA h g-1 at 20 C) compared to Ge@C-3 due to its unique hollow structure; therefore, this hollow ellipsoidal Ge@carbon can be considered as a …
Synthesis, Structural Analysis, And Thermal Decomposition Studies Of [(Nh3)2bh2]B3h8, Zhenguo Huang, Hima K. Lingam, Xuenian Chen, Spencer Porter, Aijun Du, Patrick M. Woodard, Sheldon Shore, Ji-Cheng Zhao
Synthesis, Structural Analysis, And Thermal Decomposition Studies Of [(Nh3)2bh2]B3h8, Zhenguo Huang, Hima K. Lingam, Xuenian Chen, Spencer Porter, Aijun Du, Patrick M. Woodard, Sheldon Shore, Ji-Cheng Zhao
Australian Institute for Innovative Materials - Papers
Boron–nitrogen containing compounds with high hydrogen contents as represented by ammonia borane (NH3BH3) have recently attracted intense interest for potential hydrogen storage applications. One such compound is [(NH3)2BH2]B3H8 with a capacity of 18.2 wt% H. Two safe and efficient synthetic routes to [(NH3)2BH2]B3H8 have been developed for the first time since it was discovered 50 years ago. The new synthetic routes avoid a dangerous starting chemical, tetraborane (B4H10), and afford a high yield. Single crystal X-ray diffraction analysis reveals N–Hd+…Hd2–B dihydrogen interactions in the [(NH3)2BH2]B3H8?18- crown-6 adduct. Extended strong dihydrogen bonds were observed in pure [(NH3)2BH2]B3H8 through crystal structure solution …
One-Pot Green Synthesis Of Ag Nanoparticles-Decorated Reduced Graphene Oxide For Efficient Nonenzymatic H2o2 Biosensor, Mingyan Wang, Tao Shen, Meng Wang, Dongen Zhang, Jun Chen
One-Pot Green Synthesis Of Ag Nanoparticles-Decorated Reduced Graphene Oxide For Efficient Nonenzymatic H2o2 Biosensor, Mingyan Wang, Tao Shen, Meng Wang, Dongen Zhang, Jun Chen
Australian Institute for Innovative Materials - Papers
Ag nanoparticles (AgNP) with an average size of 12 nm are successfully decorated on the reduced graphene oxide (rGO) sheets through a simple one-pot hydrothermal method using gallic acid as the reducing agent. This AgNP/rGO hybrid has been successfully applied in the catalytic performance toward the reduction of H2O2. The nonenzymatic sensor demonstrates a linear relationship in a wide concentration range of 0.05-5 mM (R=0.999), and a high sensitivity of 255 μA cm-2 mM-1 to the detection of H2O2.
Simple Synthesis Of Yolk-Shelled Znco2o4 Microspheres Towards Enhancing The Electrochemical Performance Of Lithium-Ion Batteries In Conjunction With A Sodium Carboxymethyl Cellulose Binder, Jingfa Li, Jiazhao Wang, David Wexler, Dongqi Shi, Jianwen Liang, Hua-Kun Liu, Shenglin Xiong, Yitai Qian
Simple Synthesis Of Yolk-Shelled Znco2o4 Microspheres Towards Enhancing The Electrochemical Performance Of Lithium-Ion Batteries In Conjunction With A Sodium Carboxymethyl Cellulose Binder, Jingfa Li, Jiazhao Wang, David Wexler, Dongqi Shi, Jianwen Liang, Hua-Kun Liu, Shenglin Xiong, Yitai Qian
Australian Institute for Innovative Materials - Papers
Mixed metal oxides have been attracting more and more attention recently because of their advantages and superiorities, which can improve the electrochemical performance of single metal oxides. These advantages include structural stability, good electronic conductivity, and reversible capacity. In this work, uniform yolk-shelled ZnCo2O4 microspheres were synthesized by pyrolysis of ZnCo-glycolate microsphere precursors which were prepared via a simple refluxing route without any precipitant or surfactant. The formation process of the yolk-shelled microsphere structure during the thermal decomposition of ZnCo-glycolate is discussed, which is mainly based on the heterogeneous contraction caused by non-equilibrium heat treatment. The performances of the as-prepared …
'Laser Chemistry' Synthesis, Physicochemical Properties, And Chemical Processing Of Nanostructured Carbon Foams, Andres Seral-Ascaso, Rosa Garriga, Maria Luisa Sanjuan, Joselito M. Razal, Ruth Lahoz, Mariano Laguna, German F. De La Fuente, Edgar Munoz
'Laser Chemistry' Synthesis, Physicochemical Properties, And Chemical Processing Of Nanostructured Carbon Foams, Andres Seral-Ascaso, Rosa Garriga, Maria Luisa Sanjuan, Joselito M. Razal, Ruth Lahoz, Mariano Laguna, German F. De La Fuente, Edgar Munoz
Australian Institute for Innovative Materials - Papers
Laser ablation of selected coordination complexes can lead to the production of metal-carbon hybrid materials, whose composition and structure can be tailored by suitably choosing the chemical composition of the irradiated targets. This 'laser chemistry' approach, initially applied by our group to the synthesis of P-containing nanostructured carbon foams (NCFs) from triphenylphosphine-based Au and Cu compounds, is broadened in this study to the production of other metal-NCFs and P-free NCFs. Thus, our results show that P-free coordination compounds and commercial organic precursors can act as efficient carbon source for the growth of NCFs. Physicochemical characterization reveals that NCFs are low-density …
Facile Synthesis Of Reduced Graphene Oxide/Mwnts Nanocomposite Supercapacitor Materials Tested As Electrophoretically Deposited Films On Glassy Carbon Electrodes, Widsanusan Chartarrayawadee, Simon E. Moulton, Chee O. Too, Byung C. Kim, Rao Yepuri, Anthony C. Romeo, Gordon G. Wallace
Facile Synthesis Of Reduced Graphene Oxide/Mwnts Nanocomposite Supercapacitor Materials Tested As Electrophoretically Deposited Films On Glassy Carbon Electrodes, Widsanusan Chartarrayawadee, Simon E. Moulton, Chee O. Too, Byung C. Kim, Rao Yepuri, Anthony C. Romeo, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
This paper reports on a facile synthesis method for reduced graphene oxide (rGO)/multi-walled carbon nanotubes (MWNTs) nanocomposites. The initial step involves the use of graphene oxide to disperse the MWNTs, with subsequent reduction of the resultant graphene oxide/MWNTs composites using l-ascorbic acid (LAA) as a mild reductant. Reduction by LAA preserves the interaction between the rGO sheets and MWNTs. The dispersion-containing rGO/MWNTs composites was characterized and electrophoretically deposited anodically onto glassy carbon electrodes to form high surface area films for capacitance testing. Pseudo capacitance peaks were observed in the rGO/MWNTs composite electrodes, resulting in superior performance with capacitance values up …
High-Yield Cell-Free Protein Synthesis For Site-Specific Incorporation Of Unnatural Amino Acids At Two Sites, Kiyoshi Ozawa, Karin V. Loscha, Kekini V. Kuppan, Choy Theng Loh, Nicholas E. Dixon, Gottfried Otting
High-Yield Cell-Free Protein Synthesis For Site-Specific Incorporation Of Unnatural Amino Acids At Two Sites, Kiyoshi Ozawa, Karin V. Loscha, Kekini V. Kuppan, Choy Theng Loh, Nicholas E. Dixon, Gottfried Otting
Faculty of Science - Papers (Archive)
Using aminoacyl-tRNA synthetase/suppressor tRNA pairs derived from Methanocaldococcus jannaschii, an Escherichia coli cell-free protein production system affords proteins with site-specifically incorporated unnatural amino acids (UAAs) in high yields through the use of optimized amber suppressor tRNACUA opt and optimization of reagent concentrations. The efficiency of the cell-free system allows the incorporation of trifluoromethyl-phenylalanine using a polyspecific synthetase evolved previously for p-cyanophenylalanine, and the incorporation of UAAs at two different sites of the same protein without any re-engineering of the E. coli cells used to make the cell-free extract.
Large Scale Synthesis Of V-Shaped Rutile Twinned Nanorods, Weigang Lu, Britain Bruner, Gilberto Casillas, Jibao He, Miguel Jose-Yacaman, Patrick J. Farmer
Large Scale Synthesis Of V-Shaped Rutile Twinned Nanorods, Weigang Lu, Britain Bruner, Gilberto Casillas, Jibao He, Miguel Jose-Yacaman, Patrick J. Farmer
Australian Institute for Innovative Materials - Papers
V-shaped rutile twinned nanorods (VRTNs) with different aspect ratios were synthesized on large scale using a one-pot organic solvothermal method. Although several different types of VRTNs were produced, (101) twinned nanorods were the major product with minor amounts of (301) twins and straight nanorods. STEM, TEM and XRD characterizations show that [001] is the growth direction of VRTNs, with surfaces dominated by {110} facets. Intermediate formation of both brookite and anatase nanorods provides dual pathways to VRTNs’ growth: one path in which anatase seeds trigger and promote brookite nanorod growth; and a second path in which anatase nanorods are formed …
The Synthesis, Structures And Reactions Of Zinc And Cobalt Metal-Organic Frameworks Incorporating An Alkyne-Based Dicarboxylate Linker, Andrew D. Burrows, L C. Fisher, David M. Hodgson, Mary F. Mahon, Naomi Cessford, Tina Duren, Christopher Richardson, S P. Rigby
The Synthesis, Structures And Reactions Of Zinc And Cobalt Metal-Organic Frameworks Incorporating An Alkyne-Based Dicarboxylate Linker, Andrew D. Burrows, L C. Fisher, David M. Hodgson, Mary F. Mahon, Naomi Cessford, Tina Duren, Christopher Richardson, S P. Rigby
Faculty of Science - Papers (Archive)
The reaction of zinc(II) nitrate and 4,4′-ethynylenedibenzoic acid (H2edb) in DMF at 80 °C gave the metal–organic framework material [Zn4O(edb)3(H2O)2]·6DMF 1 in which edb ligands connect Zn4O centres into a doubly-interpenetrated cubic network with a similar topology to observed with other linear dicarboxylates in the IRMOF series. Analysis of the nitrogen isotherm revealed the material to have a BET surface area of 1088 m2 g−1, which is approximately one-third of the value calculated from GCMC simulations, suggesting incomplete activation or pore blocking in the activated …
Synthesis And Anti-Leukaemic Activity Of Pyrrolo[3,2,1-Hi]Indole-1,2- Diones, Pyrrolo[3,2,1-Ij]Quinoline-1,2-Diones And Other Polycyclic Isatin Derivatives, Lidia Matesic, Julie M. Locke, Kara Vine, Marie Ranson, John B. Bremner, Danielle Skropeta
Synthesis And Anti-Leukaemic Activity Of Pyrrolo[3,2,1-Hi]Indole-1,2- Diones, Pyrrolo[3,2,1-Ij]Quinoline-1,2-Diones And Other Polycyclic Isatin Derivatives, Lidia Matesic, Julie M. Locke, Kara Vine, Marie Ranson, John B. Bremner, Danielle Skropeta
Faculty of Science - Papers (Archive)
To further expand the structure–cytotoxic activity relationships of isatin derivatives and to reduce flexibility in substituent groups at nitrogen, 20 analogues incorporating a ring system between the N1 and C7 atoms of isatin were prepared using a variety of synthetic strategies. This yielded pyrroloindole-, pyrroloquinoline-, pyrroloacridine-, pyrrolophenanthridine- and benzopyrrolophenanthridine-based systems with embedded isatin moieties, the latter possessing a novel carbon skeleton. These compounds were subsequently assessed for their in vitro cytotoxicity against human U937 lymphoma cells, with the brominated pyrroloacridine dione 27 showing the most promising activity (IC50 3.01 μM) after 24 h.
Synthesis, Properties And Water Permeability Of Swnt Buckypapers, L J. Sweetman, L Nghiem, I Chironi, G Triani, Marc In Het Panhuis, St F. Ralph
Synthesis, Properties And Water Permeability Of Swnt Buckypapers, L J. Sweetman, L Nghiem, I Chironi, G Triani, Marc In Het Panhuis, St F. Ralph
Faculty of Science - Papers (Archive)
The ability of macrocyclic ligands to facilitate formation of dispersions of single-walled carbon nanotubes (SWNTs) was investigated using a combination of absorption spectrophotometry and optical microscopy. Vacuum filtration of aqueous dispersions containing SWNTs and various macrocyclic ligands (derivatised porphyrin, phthalocyanine, cyclodextrin and calixarene) afforded self-supporting membranes known as buckypapers. Microanalytical data and energy dispersive X-ray spectra were obtained for these buckypapers and provided evidence for retention of the macrocyclic ligands within the structure of the membranes. The electrical conductivities of the membranes varied between 30 ± 20 and 220 ± 60 S cm−1, while contact angle analysis revealed they all …
The Synthesis Of Lamellar Nano Mgb2 Grains With Nanoimpurities, Flux Pinning Centers And Their Significantly Improved Critical Current Density, Zongqing Ma, Yongchang Liu, Qi Cai
The Synthesis Of Lamellar Nano Mgb2 Grains With Nanoimpurities, Flux Pinning Centers And Their Significantly Improved Critical Current Density, Zongqing Ma, Yongchang Liu, Qi Cai
Australian Institute for Innovative Materials - Papers
MgB2 superconductors with unique microstructures were rapidly fabricated at low temperatures, and exhibited significantly improved critical current density (Jc). According to the microstructure observations, the prepared samples consisted of lamellar nano MgB2 grains with many embedded nanoimpurities (about 10 nm). The formation of these lamellar nano MgB2 grains is associated with the presence of a local Mg-Cu liquid at sintering temperatures as low as 575°C. The ball milling treatment of the original powders also plays a positive role in the growth of lamellar grains. Based on an analysis of the relationship between resistivity and temperature, the lamellar nano MgB2 grains …
Ferroelectric And Ferromagnetic Nanofibers: Synthesis, Properties And Applications, A Jalalian, A M. Grishin, S X. Dou
Ferroelectric And Ferromagnetic Nanofibers: Synthesis, Properties And Applications, A Jalalian, A M. Grishin, S X. Dou
Australian Institute for Innovative Materials - Papers
As first time, ferroelectric (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 (BCTZ), biocompatible (Na0.5K0.5)NbO3 (NKN), and ferromagnetic Y3Fe5O12 (YIG) nanofibers were synthesized by sol-gel assisted electrospining technique. Non-woven, bead-free 100 μm long fiber mat was formed from close-packed nanocrystals after calcination in air at 800°C (BCTZ and NKN) and 1100°C (YIG). BCTZ fibers are 200 nm in width whereas NKN and YIG fibers have smaller 50-100 nm diameter. X-ray diffraction and Raman spectroscopy show that BCTZ and NKN crystallized in tetragonal and rhombohedral polar phases in the vicinity of morphotropic phase boundary. …
Synthesis And Electrochemical Characterization Of Lifepo4/C-Polypyrrole Composite Prepared By A Simple Chemical Vapor Deposition Method, Qiang Gong, Yu-Shi He, Yang Yang, Xiao Zhen Liao, Zi-Feng Ma
Synthesis And Electrochemical Characterization Of Lifepo4/C-Polypyrrole Composite Prepared By A Simple Chemical Vapor Deposition Method, Qiang Gong, Yu-Shi He, Yang Yang, Xiao Zhen Liao, Zi-Feng Ma
Australian Institute for Innovative Materials - Papers
A LiFePO4/C-polypyrrole (LiFePO4/C-PPy) composite as a high-performance cathode material is successfully prepared through a simple chemical vapor deposition (CVD) method. According to the transmission electron microscope (TEM) analysis, the surface of the LiFePO4/C is surrounded with PPy in the LiFePO4/C-PPy composite. The as-prepared LiFePO4/C-PPy material shows outstanding rate capability at 20°C and good cycle performance at 55°C in comparison with those of the bare LiFePO4/C material against Li anode. After 700 cycles, the discharge capacity of LiFePO4/C-PPy could still remain 110 mA h g−1 with …
One-Pot Synthesis Of Colloidal Silicon Quantum Dots And Surface Functionalization Via Thiol-Ene Click Chemistry, Xiaoyu Cheng, Richard Gondosiswanto, Simone Ciampi, Peter J. Reece, J Justin Gooding
One-Pot Synthesis Of Colloidal Silicon Quantum Dots And Surface Functionalization Via Thiol-Ene Click Chemistry, Xiaoyu Cheng, Richard Gondosiswanto, Simone Ciampi, Peter J. Reece, J Justin Gooding
Australian Institute for Innovative Materials - Papers
A solution method for preparing surface functionalized colloidal silicon quantum dots (SiQDs) is presented. SiQDs prepared by this method are reasonably monodispersed and can be further functionalized via thiol-ene click reactions to introduce specific functionalities (i.e. -NH2, -COOH, -SO 3 -, alkane, alkene).
Synthesis And Structural Characterization Of 1-[2-(5-Nitro-1h-Indol-2-Yl)Phenyl]Methylpyridinium Chloride, John B. Bremner, Siritron Samosorn, Brian W. Skelton, Allan White
Synthesis And Structural Characterization Of 1-[2-(5-Nitro-1h-Indol-2-Yl)Phenyl]Methylpyridinium Chloride, John B. Bremner, Siritron Samosorn, Brian W. Skelton, Allan White
Faculty of Science - Papers (Archive)
In the course of studies on hybrid antibacterials incorporating 2-aryl-5-nitro-1Hindolemoieties as potential bacterial NorA efflux pump inhibitors, the compound 1-[2-(5-nitro-1H-indol-2-yl)phenyl]methylpyridinium chloride (2) was synthesized and structurallycharacterized. This pyridinium chloride salt crystallized in the monoclinic space groupP21/c with the following unit cell dimensions: a 10.274(3) A, b 13.101(4) A, c 13.439(4)A, B 107.702(7)deg, V 1723.2(9) A3, Z (f.u.) = 4; R1 = 0.048, and wR2 = 0.13. Of interest inthe single crystal X-ray structure is the (intramolecular) disposition of the pyridinium planeover the indole heterocyclic residue [interplanar dihedral angle 17.91(4)deg].
Synthesis And Preliminary Evaluation Of Amiloride Analogs As Inhibitors Of The Urokinase-Type Plasminogen Activator (Upa), Hayden Matthews, Marie Ranson, Joel Tyndall, Michael J. Kelso
Synthesis And Preliminary Evaluation Of Amiloride Analogs As Inhibitors Of The Urokinase-Type Plasminogen Activator (Upa), Hayden Matthews, Marie Ranson, Joel Tyndall, Michael J. Kelso
Faculty of Science - Papers (Archive)
A known side-activity of the oral potassium-sparing diuretic drug amiloride is inhibition of the enzyme urokinase-type plasminogen activator (uPA, Ki = 7 mu M), a promising anticancer target. Several studies have demonstrated significant antitumor/metastasis properties for amiloride in animal cancer models and it would appear that these arise, at least in part, through inhibition of uPA. Selective optimization of amiloride’s structure for more potent inhibition of uPA and loss of diuretic effects would thus appear as an attractive strategy towards novel anticancer agents. The following report is a preliminary structure-activity exploration of amiloride analogs as inhibitors of uPA. A …
Stereoselective Synthesis Of Two New Trihydroxylated Pyrrolidines Using A Meyer-Schuster Rearrangement, Nalivela K. Swamy, Stephen G. Pyne
Stereoselective Synthesis Of Two New Trihydroxylated Pyrrolidines Using A Meyer-Schuster Rearrangement, Nalivela K. Swamy, Stephen G. Pyne
Faculty of Science - Papers (Archive)
The synthesis of two new trihydroxylated pyrrolidines, in a highly diastereoselective manner, has been developed using the Meyer-Schuster rearrangement as a key step. C 2011 Taylor & Francis Group, LLC.
Synthesis Of 3-Halo-2,5-Disubstituted Furans Via Cux Mediated Cyclization-Halogenation Reactions, Arife Yazici, Stephen G. Pyne
Synthesis Of 3-Halo-2,5-Disubstituted Furans Via Cux Mediated Cyclization-Halogenation Reactions, Arife Yazici, Stephen G. Pyne
Faculty of Science - Papers (Archive)
The Cu(I) halide (X = I, Br, Cl) mediated reactions of Cbz-protected cis-2-phenylethenyl-3-hydroxypyrrolidine gave novel 3-halo-2,5-trisubstituted furans in good yields, via a cyclization-halogenation, ring-opening reaction sequence. In contrast, the reactions with CuCN gave mainly the corresponding 3-cyanofuro[3,2-b]pyrrole formed from a cyclization-cyanation reaction.
Synthesis Of Novel Sugar Diamino Acids, M Thillakan, A Katsifis, D Skropeta
Synthesis Of Novel Sugar Diamino Acids, M Thillakan, A Katsifis, D Skropeta
Faculty of Science - Papers (Archive)
Sugar amino acids (SAAs) are found in nature as good construction elements for the preparation of peptide mimetics and oiigosaccharides in drug design and development. The synthesis of SAAs is readily accomplished in few steps and more than 40 SAAs have been synthesised to date.2 Sugar amino acids with an additional amino group, the sugar diamino acid (SDAs) would represent a useful expansion to the library of SAAs available because one of the amino group and carboxylic acid is available for peptide coupling and the another amino/azide group allow to do further derivatisation via peptide or click chemistry such as …
Ammonium Octahydrotriborate (Nh4b3h8): New Synthesis, Structure, And Hydrolytic Hydrogen Release, Zhenguo Huang, Xuenian Chen, Teshome Yisgedu, Edward A. Meyers, Sheldon Shore, J C. Zhao
Ammonium Octahydrotriborate (Nh4b3h8): New Synthesis, Structure, And Hydrolytic Hydrogen Release, Zhenguo Huang, Xuenian Chen, Teshome Yisgedu, Edward A. Meyers, Sheldon Shore, J C. Zhao
Australian Institute for Innovative Materials - Papers
A metathesis reaction between unsolvated NaB3H8 and NH4Cl provides a simple and high-yield synthesis of NH4B3H8. Structure determination through X-ray single crystal diffraction analysis reveals weak N—Hδ+- - -Hδ-—B interaction in NH4B3H8 and strong N—Hδ+—Hδ-—B interaction in NH4B3H8·18-crown-6·THF adduct. Pyrolysis of NH4B3H8 leads to the formation of hydrogen gas with appreciable amounts of other volatile boranes below 160°C. Hydrolysis experiments show that …
Dithienothiophene (Dtt)-Based Dyes For Dye-Sensitized Solar Cells: Synthesis Of 2,6-Dibromo-Dtt, Tae-Hyuk Kwon, Vanessa Armel, Andrew Nattestad, Douglas R. Macfarlane, Udo Bach, Samuel J. Lind, Keith C. Gordon, Weihua Tang, David J. Jones, Andrew Holmes
Dithienothiophene (Dtt)-Based Dyes For Dye-Sensitized Solar Cells: Synthesis Of 2,6-Dibromo-Dtt, Tae-Hyuk Kwon, Vanessa Armel, Andrew Nattestad, Douglas R. Macfarlane, Udo Bach, Samuel J. Lind, Keith C. Gordon, Weihua Tang, David J. Jones, Andrew Holmes
Australian Institute for Innovative Materials - Papers
A one-pot synthesis of 2,6-dibromodithieno[3,2-b;2′,3′-d]thiophene (dibromo-DTT, 4) was developed. A key step was bromodecarboxylation of DTT-2,6-dicarboxylic acid, obtained by saponification of the diester 1. The donor-acceptor dye DAHTDTT (13), based on a central 2,6-bis[2′-(3′-hexylthienyl)]dithieno[3,2-b;2′,3′-d]thiophene core (9), was prepared and incorporated in a dye-sensitized solar cell (DSC), which exhibited an energy conversion efficiency of 7.3% with Voc of 697 mV, Jsc of 14.4 mA/cm2, and ff of 0.73 at 1 sun.
Synthesis Of Hyacinthacine B-3 And Purported Hyacinthacine B-7, Christopher W.G. Au, Robert J. Nash, Stephen G. Pyne
Synthesis Of Hyacinthacine B-3 And Purported Hyacinthacine B-7, Christopher W.G. Au, Robert J. Nash, Stephen G. Pyne
Faculty of Science - Papers (Archive)
The synthesis of hyacinthacines B-3 and B-7 has confirmed the structure of the former alkaloid and shown that the structure of the latter is incorrect.
Synthesis Of Reaction-Ready 6,6 '-Biindole And 6,6 '-Biisatin Via Palladium(Ii)-Catalysed Intramolecular C-H Functionalisation, Allan B. Gamble, Paul A. Keller
Synthesis Of Reaction-Ready 6,6 '-Biindole And 6,6 '-Biisatin Via Palladium(Ii)-Catalysed Intramolecular C-H Functionalisation, Allan B. Gamble, Paul A. Keller
Faculty of Science - Papers (Archive)
The first synthesis of a 6,6'-biindole and 6,6'-biisatin scaffold is reported with the penultimate step being the formation of the di-heterocyclic ring by Pd(II)-catalysed intramolecular C-H functionalisation and Sandmeyer cyclisation, respectively.
Myriocin-Mediated Up-Regulation Of Hepatocyte Apoa-I Synthesis Is Associated With Erk Inhibition, Elias N. Glaros, Woojin Scott Kim, Brett Garner
Myriocin-Mediated Up-Regulation Of Hepatocyte Apoa-I Synthesis Is Associated With Erk Inhibition, Elias N. Glaros, Woojin Scott Kim, Brett Garner
Faculty of Science - Papers (Archive)
Sphingolipids including sphingomyelin have been implicated as potential atherogenic lipids. Studies in apoE (apolipoprotein E)-null mice have revealed that the serine palmitoyltransferase inhibitor myriocin reduces plasma levels of sphingomyelin, ceramide, sphingosine-I-phosphate and glycosphingolipids and that this is associated with potent inhibition of atherosclerosis. Interestingly, hepatic apoA-I (apolipoprotein A-I) synthesis and plasma HDL (high-density lipoprotein)cholesterol levels were also increased in apoE-null mice treated with myriocin. Since myriocin is a known inhibitor of ERK (extracellular-signal-related kinase) phosphorylation, we assessed the possibility that myriocin may be acting to increase hepatic apoA-I production via this pathway. To address this, HepG2 cells and primary mouse …
Total Synthesis Of Uniflorine A, Casuarine, Australine, 3-Epi-Australine, And 3,7-Di-Epi-Australine From A Common Precursor, Thunwadee Ritthiwigrom, Anthony C. Willis, Stephen G. Pyne
Total Synthesis Of Uniflorine A, Casuarine, Australine, 3-Epi-Australine, And 3,7-Di-Epi-Australine From A Common Precursor, Thunwadee Ritthiwigrom, Anthony C. Willis, Stephen G. Pyne
Faculty of Science - Papers (Archive)
A flexible method for the diastereoselective total synthesis of the pyrrolizidine alkaloids Uniflorine A, casuarine, australine, and 3-epi-australine and the unnatural epimer 3,7-di-epi-australine from a common chiral 2,5-dihydropyrrole precursor is described.
Synthesis And Electrochemical Studies On Li2cusno4 And Li2cusnsio6 As Negative Electrode In Lithium Batteries, Atef Y. Shenouda, Hua-Kun Liu
Synthesis And Electrochemical Studies On Li2cusno4 And Li2cusnsio6 As Negative Electrode In Lithium Batteries, Atef Y. Shenouda, Hua-Kun Liu
Australian Institute for Innovative Materials - Papers
Li2CuSnO4 and Li2CuSnSiO6 were prepared from their precursors compounds using Brij surfactant and a hydrothermal autoclave method. X-ray diffraction characterization revealed that the crystal structures of these compounds were tetragonal. Scanning electron microscope investigation showed the particle size morphology of Li2CuSnSiO6 is larger than that of Li2CuSnO4. Electrochemical impedance spectroscopy (EIS) explained that Li2CuSnO4 cell had higher charge transfer resistance (Rct = 2936Ω) than that of Li2CuSnSiO6 (38Ω). Furthermore, the reversible specific discharge capacity of the Li2CuSnSiO6 …
Synthesis And Physical Properties Of Fese1/2 Te1/2 Superconductor, V P. Awana, Anand Pal, Arpita Vajpayee, Monika Mudgel, H Kishan, Mushahid Husain, Rong Zeng, S Yu, Y F. Guo, Y.G Shi, K Yamaura, E Takayama-Muromachi
Synthesis And Physical Properties Of Fese1/2 Te1/2 Superconductor, V P. Awana, Anand Pal, Arpita Vajpayee, Monika Mudgel, H Kishan, Mushahid Husain, Rong Zeng, S Yu, Y F. Guo, Y.G Shi, K Yamaura, E Takayama-Muromachi
Australian Institute for Innovative Materials - Papers
One of the most important properties of very recently reported FeSe based superconductors is the robustness of their superconductivity under applied magnetic field. The synthesis and control of superconductivity in FeSe based compounds is rather a difficult task. Synthesis and physical property characterization for optimized superconductivity of FeSe1/2Te1/2 at 13 K is reported here. The compound crystallized in a tetragonal structure with lattice parameters a=3.8015(2) and c =6.0280(4) Å. Magnetization measurements indicated bulk superconductivity with lower critical field (Hc1) of around 180 Oe. By applying Ginzburg–Landau theory, the Hc2(0) value is estimated to …
Synthesis And Ph-Responsive Properties Of Pseudo-Peptide Containing Hydrophobic Amino Acid Grafts, Rongjun Chen, Mark E. Eccleston, Zhilian Yue, Nighel K. H Slater
Synthesis And Ph-Responsive Properties Of Pseudo-Peptide Containing Hydrophobic Amino Acid Grafts, Rongjun Chen, Mark E. Eccleston, Zhilian Yue, Nighel K. H Slater
Faculty of Science - Papers (Archive)
Pseudo-peptidic polymers have been synthesised by grafting l-valine (PV), l-leucine (PL) and l-phenylalanine (PP) onto the pendant carboxylic acid moieties of a pH-responsive polyamide, poly(l-lysine isophthalamide). The pH-responsive aqueous solution properties of PV-75, PL-75 and PP-75 with a stoichiometric degree of substitution of 75 mol% have been compared with those of the parent poly(l-lysine isophthalamide) using UV-visible and fluorescence spectroscopy. At low concentrations (≤0.1 mg mL-1), the grafted polymers displayed pH-dependent conformation. The pH at the onset of hydrophobic association (pHh) and the pH range over which association occurred varied significantly between the different amino acid grafts. The pHh values …