Physical Sciences and Mathematics Commons^™

Past Ice-Ocean Interactions On The Sabrina Coast Shelf, East Antarctica: Deglacial To Recent Paleoenvironmental Insights From Marine Sediments, Kara J. Vadman

USF Tampa Graduate Theses and Dissertations

The East Antarctic Ice Sheet (EAIS) contains ~53 meters of sea level equivalent (SLE) ice, and observations suggest it is sensitive to ongoing and past climate change. The EAIS has traditionally been considered insensitive to climate perturbations because it is largely grounded above sea level. However, aerogeophysical surveys, oceanographic observations, and models indicate that large areas of the EAIS are grounded below sea level and contain 19.2 m SLE. Marine-based parts of the EAIS are thought to be located on inland-sloping beds that drain through marine terminating outlet glaciers, indicating large areas of the EAIS may be more sensitive to …

Plio-Pleistocene Antarctic Ice-Ocean Interactions In The Ross Sea, Catherine Prunella

USF Tampa Graduate Theses and Dissertations

Warm, intermediate-depth Southern Ocean waters are implicated in recent Antarctic ice mass loss. Direct observations of Antarctic Ice Sheet (AIS) retreat are temporally limited, necessitating paleoceanographic records of ocean-ice interactions during past warm climate intervals. Deepsea and ice-proximal sediments record orbitally-paced glacial-interglacial fluctuations in AIS volume during the Plio-Pleistocene (last 5 million years; Ma), but the total contribution of the AIS and the role of ocean heat in these fluctuations remain unresolved. To address the response of Antarctica’s ice sheets to changing ocean temperatures during the Plio-Pleistocene, International Ocean Discovery Program (IODP) Expedition 374 recovered sediments from the Ross Sea …

Effects Of Reservoir Conditions And Trace Co-Contaminant Gases On Geological Carbon Sequestration, Ram Kumar

USF Tampa Graduate Theses and Dissertations

Geological carbon sequestration in a saline formation is a promising technology for large-scale carbon dioxide (CO2) mitigation. Several factors such as temperature, pressure, salinity, hydraulic conductivity, and mineralogy of a formation affect the CO2 sequestration in saline formations. These factors can vary widely depending upon the type of formation or the degree of heterogeneity within a formation. In addition to these properties of the repositories, the CO2-rich flue gas streams captured from point sources often contains small amounts of impurities such as sulfur oxides (SOx) and nitrogen oxides (NOx), which may have serious implications on the chemistry of the repositories …

Replacement Times Of A Spectrum Of Elements In The North Atlantic Based On Thorium Supply, Christopher T. Hayes, Robert F. Anderson, Hai Cheng, Tim M. Conway, R. L. Edwards, Martin Q. Fleisher, Peng Ho, Kuo-Fang Huang, Seth G. John, William M. Landing

School of Geosciences Faculty and Staff Publications

The measurable supply of ²³²Th to the ocean can be used to derive the supply of other elements, which is more difficult to quantify directly. The measured inventory of an element divided by the derived supply yields a replacement time estimate, which in special circumstances is related to a residence time. As a proof of concept, Th‐based supply rates imply a range in the replacement times of the rare earth elements in the North Atlantic that is consistent with the chemical reactivity of rare earth elements related to their ionic charge density. Similar estimates of replacement times for the …

Geochemistry Of Upper Cretaceous Sediments Of Bozeş Formation (Apuseni Mts., Romania) – Provenance Implications, Luminiţa Zaharia, Romona Bălc, Cosmin C. Stremţan, Adriana Socaciu

School of Geosciences Faculty and Staff Publications

A whole-rock geochemical study was carried out on sandstones from the Upper Cretaceous Bozeş Formation in the southeastern part of the Apuseni Mountains (Romania) in order to constrain their provenance and depositional setting. The geochemical results were compared and integrated with previously reported provenance indicators, such as framework composition and heavy mineral assemblages. The chemical composition is similar for all samples investigated, with limited ranges for both major oxides and trace elements. The sandstones are potassic (Na₂O/K₂O < 1) and can be classified mainly as arenites with a few greywackes. Their immature to relatively mature character is revealed by the SiO₂/Al₂O₃ ratios, ranging between 3.90 and 11.25, as well as their high Sr/Rb ratios. The …

Evaluation Of Pgaa Data For Provenance Of Lithic Artifacts, Otis N. Crandell

Studia UBB Geologia

The objectives of the study were to determine whether Prompt Gamma Activation Analyses (PGAA) could be successfully used to trace the source(s) of various Neolithic artifacts made of microcrystaline quartz. Two macroscopically identical sources of jasper from central and western Romania were analyzed by PGAA along with five Neolithic artifacts from the Limba site (Alba County). Due to the limited number of trace elements, which can be measured by PGAA, this method when used alone might produce inconclusive results for discriminating between jaspers from different sources. The interpretation of the data may be used for general assessments of provenance involving …

Effects Of Sediment Mineralogy To High-Iron Content In The Groundwater Of Rrogozhina Aquifer (Western Albania), Arjan Beqiraj, Enkeleida Beqiraj

Studia UBB Geologia

The groundwater of Rrogozhina aquifer (western Albania) is generally characterized by high iron contents. Its water-bearing medium consists of soft to hard sandstone and conglomerate with intercalations of impermeable clay layers. The groundwater of Rrogozhina aquifer, that extends over a surface of 2100 km² in the pre-Adriatic depression of Albania, occurs under typically artesian conditions. The iron content in ground water ranges from 0.2% up to 2.5%, but most of them fall within the interval 0.5-1.0 %. In groundwater iron occurs as reduced divalent ferrous iron (Fe⁺²) which is conditioned by the lack of water exposure to …

The Present Day Genesis And Evolution Of Cave Minerals Inside The Ojo De La Reina Cave (Naica Mine, Mexico), Giovanni Badino, José Maria Calaforra, Paolo Forti, Paolo Garofalo, Laura Sanna

International Journal of Speleology

Ojo de la Reina is the first and the smallest cave intersected at the -290 level in the Naica Mine (Mexico), therefore it was the first cavity in which the lowering of temperature induced by mine ventilation caused condensation over crystals’ surface since 2005. The consequent dissolution of the gypsum crystals and subsequent condensed water evaporation lead to the deposition of several new minerals, among which some highly soluble Mg/Na compounds (bloedite, epsomite, halite, hexahydrite, kieserite, starkeyite). The single available source of Mg and Na ions in this minerogenetic environment is represented by the huge fluid inclusions widespread within the …

Geochemical Systematics Among Amphibolitic Rocks In The Central Blue Ridge Province Of Southwestern North Carolina, Nathan Collins

USF Tampa Graduate Theses and Dissertations

The Central Blue Ridge sub-province of the southern Appalachian Mountains preserves an unique and complex geologic history. The Cartoogechaye terrane is the westernmost terrane of the Central Blue Ridge sub-province, and is characterized by extensive olistostromal sequences, including mafic-ultramafic massifs, isolated mafic units, and block-in-matrix structures of varying scales. This study investigates the genetic and tectonic relationships, and regional chemical and metamorphic trends of the amphibolitic rocks entrained within units of the Cartoogechaye and nearby terranes, toward constraining the origins of these regional sequences, and examining the rationale for the current Blue Ridge terrane designations.

A distinct compositional variation exists …

Towards Mineralogical And Geochemical Reference Groups For Some Bronze Age Ceramics 
From Transylvania (Romania), Volker Hoeck, Corina Ionescu, Lucretia Ghergari, Carmen Precup

Studia UBB Geologia

Based on their chemical composition ceramic shards from three Bronze Age sites in Transylvania, i.e., Copăceni, Derşida and Palatca respectively, were distinguished by major, trace, and RE elements. Within the Copăceni samples, two subgroups (A and B) showing different chemistry and mineralogy were additionally separated out. The link between chemistry and mineralogy showed clearly the important contribution of the temper to the overall chemistry of the ceramic shards. In turn, the chemistry facilitated the provenance study of the raw materials, which were collected in the vicinity of the sites. In combination with the mineralogy of the ceramics, the chemical analyses …

Petrology And Geochemistry Of The Muntele Mare Granitoid (Northern Apuseni Mountains), Romania, Lucretia Ghergari, Cristina Maris

Studia UBB Geologia

The paper brings new data on the petrography and geochemistry of the Muntele Mare Granitoid (MMG), from its northernmost outcropping area (Mănăstireni-Bedeci area, Gilău Massif, Apuseni Mountains), where MM\G is are actively quarried for quartz and feldspar that are used in the ceramics industry. The MMG mined in the Bedeci quarry has a pegmatitic hypidiomorphous – inequigranular fabric, and a low melanocratic index (ca. 7%). It consists of quartz, plagioclase (two generations: acidic andesine-basic oligoclase (34-35% An), and albite (9-11% An)), orthoclase ± perthite in various substitution stages by microcline (intermediary), as well as microcline maximum, muscovite and biotite. Accessories …

An Investigation Of Meromixis In Cave Pools, Lechuguilla Cave, New Mexico, David B. Levy

International Journal of Speleology

Chemical characteristics of permanent stratification in cave pools (meromixis) may provide insight into the geochemical origin and evolution of cave pool waters. The objective of this study was to test the hypothesis that some pools in Lechuguilla Cave may be subject to ectogenic meromixis, where permanent chemical stratification is induced by input of relatively saline or fresh water from an external source. However, because organic C concentrations in Lechuguilla waters are low (typically < 1 mg L^-1), biogenic meromixis resulting in O₂(g)-depleted subsurface waters is not expected. Four pools at various depths below ground surface (0 m) were studied: (1) …

Shallow Slab Fluid Release Across And Along The Mariana Arc-Basin System: Insights From Geochemistry Of Serpentinized Peridotites From The Mariana Fore Arc, Ivan P. Savov, Jeffrey G. Ryan, Massimo D'Antonio, Patricia Fryer

Geology Faculty Publications

Shallow slab devolatilization is not only witnessed through fluid expulsion at accretionary prisms, but is also evidenced by active serpentinite seamounts in the shallow fore-arc region of the Mariana convergent margin. Ocean Drilling Program (ODP) Leg 195 recovered serpentinized peridotites that present a unique opportunity to study the products of shallow level exchanges between the upper mantle and slab-derived fluids. Similar to samples recovered during ODP Leg 125, the protoliths of these fore-arc serpentinized peridotites are mantle harzburgites that have suffered large volume melt extraction (up to 25%) prior to interactions with fluids released from the downgoing Pacific Plate. Samples …

Bette And Will White Oral History Interview With Spencer Fleury And Todd Chavez, July 25, 2007, Elizabeth L. White (Interviewee), William B. White (Interviewee), Spencer Fleury (Interviewer), Todd Chavez (Interviewer)

Environmental Sustainability Oral Histories

The Drs. White take turns discussing how they became interested in karst science. They reflect on the days when public opinion marginalized karst science and offer what they perceive as the historical factors which have allowed it to become established as a stand-alone scientific discipline. They then discuss students who have worked with them on various karst projects. Dr. Will White tells the story of the haunted telephone from Crystal Cave in Kentucky. The interviewees then discuss the relationship between professional karst scientists and the amateur, recreational caving community. They also discuss the future of karst science specifically with relation …

The Impact Of Host Rock Geochemistry On Bacterial Community Structure In Oligotrophic Cave Environments, Hazel A. Barton, Nicholas M. Taylor, Michael P. Kreate, Austin C. Springer, Stuart A. Oehrle, Janet L. Bertog

International Journal of Speleology

Despite extremely starved conditions, caves contain surprisingly diverse microbial communities. Our research is geared toward understanding what ecosystems drivers are responsible for this high diversity. To asses the effect of rock fabric and mineralogy, we carried out a comparative geomicrobiology study within Carlsbad Cavern, New Mexico, USA. Samples were collected from two different geologic locations within the cave: WF1 in the Massive Member of the Capitan Formation and sF88 in the calcareous siltstones of the Yates Formation. We examined the organic content at each location using liquid chromatography mass spectroscopy and analyzed microbial community structure using molecular phylogenetic analyses. In …

Geochemistry Of Serpentinized Peridotites From The Mariana Forearc Conical Seamount, Odp Leg 125: Implications For The Elemental Recycling At Subduction Zones, Ivan P. Savov, Jeffrey G. Ryan, Massimo D'Antonio, Katherine Kelley, Patrick Mattie

Geology Faculty Publications

Recent examinations of the chemical fluxes through convergent plate margins suggest the existence of significant mass imbalances for many key species: only 20–30% of the to-the-trench inventory of large-ion lithophile elements (LILE) can be accounted for by the magmatic outputs of volcanic arcs. Active serpentinite mud volcanism in the shallow forearc region of the Mariana convergent margin presents a unique opportunity to study a new outflux: the products of shallow-level exchanges between the upper mantle and slab-derived fluids. ODP Leg 125 recovered serpentinized harzburgites and dunites from three sites on the crests and flanks of the active Conical Seamount. These …