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University of South Florida

2016

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Articles 1 - 30 of 239

Full-Text Articles in Physical Sciences and Mathematics

The Ribbed Drapery Of The Puerto Princesa Underground River (Palawan, Philippines): Morphology And Genesis, Paolo Forti, Giovanni Badino, Jose Maria Calaforra, Jo De Waele Dec 2016

The Ribbed Drapery Of The Puerto Princesa Underground River (Palawan, Philippines): Morphology And Genesis, Paolo Forti, Giovanni Badino, Jose Maria Calaforra, Jo De Waele

International Journal of Speleology

During the 2011 speleological expedition to the Puerto Princesa Underground River (Palawan, Philippines) a drapery characterized by several close-to-horizontal ribs has been noticed. Even without sampling and analyzing its internal growth layers, a detailed morphological study allowed to present a possible genetic model. The presented model helps to explain its evolution, which is mainly controlled by variation in water flow as a consequence of the Palawan climate. When validated by further analyses, the same genetic mechanism could define also the evolution of the very common but still unexplained complex flowstones, which exhibit several close-to-horizontal steps, widenings and narrowings along their …


Evaluating Machine Learning Classifiers For Defensive Cyber Operations, Michael D. Rich, Robert F. Mills, Thomas E. Dube, Steven K. Rogers Dec 2016

Evaluating Machine Learning Classifiers For Defensive Cyber Operations, Michael D. Rich, Robert F. Mills, Thomas E. Dube, Steven K. Rogers

Military Cyber Affairs

Today’s defensive cyber sensors are dominated by signature-based analytical methods that require continuous maintenance and lack the ability to detect unknown threats. Anomaly detection offers the ability to detect unknown threats, but despite over 15 years of active research, the operationalization of anomaly detection and machine learning for Defensive Cyber Operations (DCO) is lagging. This article provides an introduction to machine learning concepts with a focus on the unique challenges to using machine learning for DCO. Traditional machine learning evaluation methods are challenged in favor of a value-focused evaluation method that incorporates evaluator-specific weights for classifier and sensitivity threshold selection …


Military Cyber Professionals Have An Important Part To Play In The Obama-Trump Transition, Michael V. Hayden Dec 2016

Military Cyber Professionals Have An Important Part To Play In The Obama-Trump Transition, Michael V. Hayden

Military Cyber Affairs

Over the course of decades in service, I have experienced multiple presidential transitions. Each new Commander in Chief updates policies, personnel, and priorities…especially when the transition involves a new political party. In this respect, the current transition from the Obama to the Trump administration is no different. While this periodic exercise of our democracy may seem disruptive to some, it is a true opportunity for military cyber professionals to help shape our future national security posture.


Anomaly Detection From Hyperspectral Remote Sensing Imagery, Qiandong Guo, Ruiliang Pu, Jun Cheng Dec 2016

Anomaly Detection From Hyperspectral Remote Sensing Imagery, Qiandong Guo, Ruiliang Pu, Jun Cheng

School of Geosciences Faculty and Staff Publications

Hyperspectral remote sensing imagery contains much more information in the spectral domain than does multispectral imagery. The consecutive and abundant spectral signals provide a great potential for classification and anomaly detection. In this study, two real hyperspectral data sets were used for anomaly detection. One data set was an Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data covering the post-attack World Trade Center (WTC) and anomalies are fire spots. The other data set called SpecTIR contained fabric panels as anomalies compared to their background. Existing anomaly detection algorithms including the Reed–Xiaoli detector (RXD), the blocked adaptive computation efficient outlier nominator (BACON), the …


Lilliput Effect Dynamics Across The Cretaceous-Paleogene Mass Extinction: Approaches, Prevalence, And Mechanisms, Matthew Brett Jarrett Dec 2016

Lilliput Effect Dynamics Across The Cretaceous-Paleogene Mass Extinction: Approaches, Prevalence, And Mechanisms, Matthew Brett Jarrett

USF Tampa Graduate Theses and Dissertations

An organism's body size entails both physiological and ecological costs. Furthermore, as a parameter in analyzing organisms, it represents a fundamental and essential morphometric character. Reductions in size following mass extinction is a commonly observed phenomenon in the fossil record. This study examines the evolutionary significance of this phenomenon termed the: 'Lilliput Effect' by proposing that it represents a rapid evolutionary response to altered selection pressures during a mass extinction. This primary hypothesis is evaluated against two additional hypotheses of size reduction: 1) stunted growth as a response to stressed ecosystems, and/or 2) mass extinctions are size selective.

These hypotheses …


Recurring Patterns Among Scrambled Genes In The Encrypted Genome Of The Ciliate Oxytricha Trifallax, Jonathan Burns, Denys Kukushkin, Xiao Chen, Laura F Landweber, Masahico Saito, Nataša Jonoska Dec 2016

Recurring Patterns Among Scrambled Genes In The Encrypted Genome Of The Ciliate Oxytricha Trifallax, Jonathan Burns, Denys Kukushkin, Xiao Chen, Laura F Landweber, Masahico Saito, Nataša Jonoska

Mathematics and Statistics Faculty Publications

Some genera of ciliates, such as Oxytricha and Stylonychia, undergo massive genome reorganization during development and provide model organisms to study DNA rearrangement. A common feature of these ciliates is the presence of two types of nuclei: a germline micronucleus and a transcriptionally-active somatic macronucleus containing over 16,000 gene sized "nano-chromosomes". During conjugation the old parental macronucleus disintegrates and a new macronucleus forms from a copy of the zygotic micronucleus. During this process, macronuclear chromosomes assemble through DNA processing events that delete 90-98% of the DNA content of the micronucleus. This includes the deletion of noncoding DNA segments that interrupt …


Secondary Structure Adopted By The Gly-Gly-X Repetitive Regions Of Dragline Spider Silk, Geoffrey M Gray, Arjan Van Der Vaart, Chengchen Guo, Justin Jones, David Onofrei, Brian R Cherry, Randolph V Lewis, Jeffery L Yarger, Gregory P Holland Dec 2016

Secondary Structure Adopted By The Gly-Gly-X Repetitive Regions Of Dragline Spider Silk, Geoffrey M Gray, Arjan Van Der Vaart, Chengchen Guo, Justin Jones, David Onofrei, Brian R Cherry, Randolph V Lewis, Jeffery L Yarger, Gregory P Holland

Chemistry Faculty Publications

Solid-state NMR and molecular dynamics (MD) simulations are presented to help elucidate the molecular secondary structure of poly(Gly-Gly-X), which is one of the most common structural repetitive motifs found in orb-weaving dragline spider silk proteins. The combination of NMR and computational experiments provides insight into the molecular secondary structure of poly(Gly-Gly-X) segments and provides further support that these regions are disordered and primarily non-β-sheet. Furthermore, the combination of NMR and MD simulations illustrate the possibility for several secondary structural elements in the poly(Gly-Gly-X) regions of dragline silks, including β-turns, 3


What’S Scale Got To Do With It? Models For Urban Tree Canopy, Dexter H. Locke, Shawn M. Landry, J. M. Grove, Rinku R. Chowdhury Dec 2016

What’S Scale Got To Do With It? Models For Urban Tree Canopy, Dexter H. Locke, Shawn M. Landry, J. M. Grove, Rinku R. Chowdhury

School of Geosciences Faculty and Staff Publications

The uneven provisioning of ecosystem services has important policy implications; yet the spatial heterogeneity of tree canopy remains understudied. Private residential lands are important to the future of Philadelphia’s urban forest because a majority of the existing and possible tree canopy is located on residential land uses. This article examines the spatial distribution of tree canopy in Philadelphia, PA and its social correlates. How are existing tree canopy and opportunities for additional tree canopy distributed across the city of Philadelphia and with respect to three explanations: (i) population density, (ii) the social stratification luxury effect, and 3) lifestyle characteristics of …


Dielectric Analysis Of Aqueous Poly(L-Glutamic Acid) And Poly-L-(Glutamic Acid4, Tyrosine1) Solutions At High Frequencies From Capacitance Measurements, Jorge Monreal, Tatiana Eggers, Manh-Huong Phan Dec 2016

Dielectric Analysis Of Aqueous Poly(L-Glutamic Acid) And Poly-L-(Glutamic Acid4, Tyrosine1) Solutions At High Frequencies From Capacitance Measurements, Jorge Monreal, Tatiana Eggers, Manh-Huong Phan

Physics Faculty Publications

A new parallel-plate capacitor fixture has been designed and successfully used to measure dielectric loss of polyelectrolyte solutions with volumes as low as droplets of 13–26 μL. It is particularly useful when studying polypeptides that are either high-cost or can be synthesized only in limited quantities. The ease with which the fixture can be used to obtain preliminary dielectric loss data yields savings in time and cost. In this study capacitance measurements were performed in a wide range of frequencies between 1 and 800 MHz using an Agilent 4191RF Impedance Analyzer. Accuracy of measurements was carefully examined through a comparison …


Quiescent‐Explosive Transitions During Dome‐Forming Volcanic Eruptions: Using Seismicity To Probe The Volcanic Processes Leading To The 29 July 2008 Vulcanian Explosion Of Soufrière Hills Volcano, Montserrat, Mel Rodgers, Patrick J. Smith, Tamsin A. Mather, David M. Pyle Dec 2016

Quiescent‐Explosive Transitions During Dome‐Forming Volcanic Eruptions: Using Seismicity To Probe The Volcanic Processes Leading To The 29 July 2008 Vulcanian Explosion Of Soufrière Hills Volcano, Montserrat, Mel Rodgers, Patrick J. Smith, Tamsin A. Mather, David M. Pyle

School of Geosciences Faculty and Staff Publications

The July 2008 vulcanian explosion at Soufrière Hills Volcano (SHV), Montserrat, was preceded by one of the largest seismic swarms observed since the start of the eruption. We analyze the spectral and waveform properties of the earthquakes in this swarm and compare these observations to models of subsurface volcanic processes. We observe an initial volcano‐tectonic (VT) swarm, followed by a large low‐frequency (LF) swarm. We observe that the spectral content of LF events changes over time to carry more energy at lower frequencies. This shift to a lower frequency spectral content is concurrent with an increase in LF event rates. …


Applying Ahp And Clustering Approaches For Public Transportation Decisionmaking: A Case Study Of Isfahan City, Alireza Salavati, Hossein Haghshenas, Bahador Ghadirifaraz, Jamshid Laghaei, Ghodrat Eftekhari Dec 2016

Applying Ahp And Clustering Approaches For Public Transportation Decisionmaking: A Case Study Of Isfahan City, Alireza Salavati, Hossein Haghshenas, Bahador Ghadirifaraz, Jamshid Laghaei, Ghodrat Eftekhari

Journal of Public Transportation

The main purpose of this paper is to define appropriate criteria for the systematic approach to evaluate and prioritize multiple candidate corridors for public transport investment simultaneously to serve travel demand, regarding supply of current public transportation system and road network conditions of Isfahan, Iran. To optimize resource allocation, policymakers need to identify proper corridors to implement a public transportation system. In fact, the main question is to adopt the best public transportation system for each main corridor of Isfahan. In this regard, 137 questionnaires were completed by experts, directors, and policymakers of Isfahan to identify goals and objectives in …


Random Walks In A Sparse Random Environment, Anastasios Matzavinos, Alexander Roitershtein, Youngsoo Seol Dec 2016

Random Walks In A Sparse Random Environment, Anastasios Matzavinos, Alexander Roitershtein, Youngsoo Seol

Mathematics and Statistics Faculty Publications

We introduce random walks in a sparse random environment on ℤ and investigate basic asymptotic properties of this model, such as recurrence-transience, asymptotic speed, and limit theorems in both the transient and recurrent regimes. The new model combines features of several existing models of random motion in random media and admits a transparent physical interpretation. More specifically, a random walk in a sparse random environment can be characterized as a “locally strong” perturbation of a simple random walk by a random potential induced by “rare impurities,” which are randomly distributed over the integer lattice. Interestingly, in the critical (recurrent) regime, …


Predicting Malignant Nodules From Screening Ct Scans, Samuel Hawkins, Hua Wang, Ying Liu, Alberto Garcia, Olya Stringfield, Henry Krewer, Qiang Li, Dmitry Cherezov, Matthew Schabath, Lawrence O. Hall, Robert J. Gillies Dec 2016

Predicting Malignant Nodules From Screening Ct Scans, Samuel Hawkins, Hua Wang, Ying Liu, Alberto Garcia, Olya Stringfield, Henry Krewer, Qiang Li, Dmitry Cherezov, Matthew Schabath, Lawrence O. Hall, Robert J. Gillies

Computer Science and Engineering Faculty Publications

Objectives

The aim of this study was to determine whether quantitative analyses (“radiomics”) of low-dose computed tomography lung cancer screening images at baseline can predict subsequent emergence of cancer.

Methods

Public data from the National Lung Screening Trial (ACRIN 6684) were assembled into two cohorts of 104 and 92 patients with screen-detected lung cancer and then matched with cohorts of 208 and 196 screening subjects with benign pulmonary nodules. Image features were extracted from each nodule and used to predict the subsequent emergence of cancer.

Results

The best models used 23 stable features in a random forests classifier and could …


Deep Feature Transfer Learning In Combination With Traditional Features Predicts Survival Among Patients With Lung Adenocarcinoma, Rahul Paul, Samuel H. Hawkings, Matthew B. Schabath, Robert J. Gilies, Lawrence O. Hall, Dmitry Goldgof Dec 2016

Deep Feature Transfer Learning In Combination With Traditional Features Predicts Survival Among Patients With Lung Adenocarcinoma, Rahul Paul, Samuel H. Hawkings, Matthew B. Schabath, Robert J. Gilies, Lawrence O. Hall, Dmitry Goldgof

Computer Science and Engineering Faculty Publications

Lung cancer is the most common cause of cancer-related deaths in the USA. It can be detected and diagnosed using computed tomography images. For an automated classifier, identifying predictive features from medical images is a key concern. Deep feature extraction using pretrained convolutional neural networks (CNNs) has recently been successfully applied in some image domains. Here, we applied a pretrained CNN to extract deep features from 40 computed tomography images, with contrast, of non-small cell adenocarcinoma lung cancer, and combined deep features with traditional image features and trained classifiers to predict short- and long-term survivors. We experimented with several pretrained …


Precursor Motion To Iceberg Calving At Jakobshavn Isbræ, Greenland, Observed With Terrestrial Radar Interferometry, Surui Xie, Timothy H. Dixon, Denis Voytenko, David M. Holland, Tiantian Zheng Dec 2016

Precursor Motion To Iceberg Calving At Jakobshavn Isbræ, Greenland, Observed With Terrestrial Radar Interferometry, Surui Xie, Timothy H. Dixon, Denis Voytenko, David M. Holland, Tiantian Zheng

School of Geosciences Faculty and Staff Publications

Time-varying elevations near the calving front of Jakobshavn Isbræ, Greenland were observed with a terrestrial radar interferometer (TRI) in June 2015. An ice block with surface dimensions of 1370 m × 290 m calved on 10 June. TRI-generated time series show that ice elevation near the calving front began to increase 65 h prior to the event, and can be fit with a simple block rotation model. We hypothesize that subsurface melting at the base of the floating terminus breaks the gravity-buoyancy equilibrium, leading to slow subsidence and rotation of the block, and its eventual failure.


Greenland Subglacial Drainage Evolution Regulated By Weakly Connected Regions Of The Bed, Matthew J. Hoffman, Lauren C. Andrews, Stephen F. Price, Ginny A. Catania, Thomas A. Neumann, Martin P. Lüthi, Jason Gulley, Claudia Ryser, Robert L. Hawley, Blaine Morriss Dec 2016

Greenland Subglacial Drainage Evolution Regulated By Weakly Connected Regions Of The Bed, Matthew J. Hoffman, Lauren C. Andrews, Stephen F. Price, Ginny A. Catania, Thomas A. Neumann, Martin P. Lüthi, Jason Gulley, Claudia Ryser, Robert L. Hawley, Blaine Morriss

School of Geosciences Faculty and Staff Publications

Penetration of surface meltwater to the bed of the Greenland Ice Sheet each summer causes an initial increase in ice speed due to elevated basal water pressure, followed by slowdown in late summer that continues into fall and winter. While this seasonal pattern is commonly explained by an evolution of the subglacial drainage system from an inefficient distributed to efficient channelized configuration, mounting evidence indicates that subglacial channels are unable to explain important aspects of hydrodynamic coupling in late summer and fall. Here we use numerical models of subglacial drainage and ice flow to show that limited, gradual leakage of …


Exchange Bias Effects In Iron Oxide-Based Nanoparticle Systems, Manh-Huong Phan, Javier Alsonso, Hafsa Khurshid, Paula Lampen-Kelley, Sayan Chandra, Kristen Stojak Repa, Zohreh Nemati, Raja Das, Óscar Iglesias, Hariharan Srikanth Nov 2016

Exchange Bias Effects In Iron Oxide-Based Nanoparticle Systems, Manh-Huong Phan, Javier Alsonso, Hafsa Khurshid, Paula Lampen-Kelley, Sayan Chandra, Kristen Stojak Repa, Zohreh Nemati, Raja Das, Óscar Iglesias, Hariharan Srikanth

Physics Faculty Publications

The exploration of exchange bias (EB) on the nanoscale provides a novel approach to improving the anisotropic properties of magnetic nanoparticles for prospective applications in nanospintronics and nanomedicine. However, the physical origin of EB is not fully understood. Recent advances in chemical synthesis provide a unique opportunity to explore EB in a variety of iron oxide-based nanostructures ranging from core/shell to hollow and hybrid composite nanoparticles. Experimental and atomistic Monte Carlo studies have shed light on the roles of interface and surface spins in these nanosystems. This review paper aims to provide a thorough understanding of the EB and related …


Storm Induced Beach Profile Changes Along The Coast Of Treasure Island, West-Central Florida, U.S.A., Zhaoxu Zhu Nov 2016

Storm Induced Beach Profile Changes Along The Coast Of Treasure Island, West-Central Florida, U.S.A., Zhaoxu Zhu

USF Tampa Graduate Theses and Dissertations

Storms play a significant role in beach morphodynamics. Storm-induced beach-profile changes and their longshore variations are investigated in this study. The impacts of four summer tropical storms and two series of winter storms over the last 10 years along the coast of Treasure Island were documented. Tropical storms Alberto in 2006, Fay in 2008, Debby in 2012, Hermine in 2016 and winter storms in winter seasons of 2014 and 2015 are discussed in this study. In general, the Treasure Island beach experienced more erosion generated by tropical storms with greater intensity, but shorter duration, as compared to winter storms due …


Photocatalytic Reduction Of Co2 With Tunable Bandgap And Bandedge Materials, Thuhuong T. Ngo Nov 2016

Photocatalytic Reduction Of Co2 With Tunable Bandgap And Bandedge Materials, Thuhuong T. Ngo

USF Tampa Graduate Theses and Dissertations

Solar energy is a sustainable resource which has substantial potential to meet the increasing demand for renewable energy. Though there has been some success in harvesting solar energy for electricity production, converting solar energy to chemical energy as fuels is still a challenge due to low efficiency.

Since the discovery of TiO2 photocatalysts for splitting water (4) and reducing CO2 (5) to form useful chemical feedstock such as H2, CO and CH4, much research has been done to increase the efficiency of photocatalysts. However, the current conversion efficiency of photocatalysts remains low (~5%) (6, …


Reduced Dimensionality Effects In Gd-Based Magnetocaloric Materials, Hillary Faith Belliveau Nov 2016

Reduced Dimensionality Effects In Gd-Based Magnetocaloric Materials, Hillary Faith Belliveau

USF Tampa Graduate Theses and Dissertations

Magnetic refrigeration based on the magnetocaloric effect (MCE) is a promising alternative to conventional gas compression based cooling techniques. Understanding impacts of reduced dimensionality on the magnetocaloric response of a material such as Gadolinium (Gd) or its alloys is essential in optimizing the performance of cooling devices, which is also the overall goal of this thesis. We have determined, in the first part of the thesis, that laminate structures of pure Gd produced by magnetron sputtering have several disadvantages. The target material (pure Gd), ultra-high vacuum components, and the electrical energy it takes to run the manufacturing process are all …


Resonant Light Scattering From Semiconductor Quantum Dots, Kumarasiri Konthasinghe Nov 2016

Resonant Light Scattering From Semiconductor Quantum Dots, Kumarasiri Konthasinghe

USF Tampa Graduate Theses and Dissertations

In this work, resonant laser spectroscopy has been utilized in two major projects --resonance fluorescence measurements in solid-state quantum-confined nanostructures and laser-induced fluorescence measurements in gases. The first project focuses on studying resonant light-matter interactions in semiconductor quantum dots "artificial atoms" with potential applications in quantum information science. Of primary interest is the understanding of fundamental processes and how they are affected by the solid-state matrix. Unlike atoms, quantum dots are susceptible to a variety of environmental influences such as phonon scattering and spectral diffusion. These interactions alter the desired properties of the scattered light and hinder uses in certain …


Improved 2d And 3d Resistivity Surveys Using Buried Electrodes And Optimized Arrays: The Multi-Electrode Resistivity Implant Technique (Merit), Henok Gidey Kiflu Nov 2016

Improved 2d And 3d Resistivity Surveys Using Buried Electrodes And Optimized Arrays: The Multi-Electrode Resistivity Implant Technique (Merit), Henok Gidey Kiflu

USF Tampa Graduate Theses and Dissertations

This thesis presents a novel resistivity method called Multi-Electrode resistivity technique (MERIT) that is used for high resolution imaging of complex geologic features at depth and near the edges of survey lines. The MERIT electrodes are especially shaped and designed to be self-driven using a robust-direct push technique. Measurements are taken using optimized arrays that are generated using a modified version of the “Compare-R” optimization algorithm. This work focused on both two-dimensional (MERIT2D) and three-dimensional (MERIT3D) applications of the buried array and show the relevance of the additional information gained by the addition of deep electrodes especially in sites with …


Confinement Effects And Magnetic Interactions In Magnetic Nanostructures, Kristen Lee Stojak Repa Nov 2016

Confinement Effects And Magnetic Interactions In Magnetic Nanostructures, Kristen Lee Stojak Repa

USF Tampa Graduate Theses and Dissertations

Multifunctional nanocomposites are promising for a variety of applications ranging from microwave devices to biomedicine. High demand exists for magnetically tunable nanocomposite materials. My thesis focuses on synthesis and characterization of novel nanomaterials such as polymer nanocomposites (PNCs) and multi-walled carbon nanotubes (MWCNTs) with magnetic nanoparticle (NP) fillers.

Magnetite (Fe3O4) and cobalt ferrite (CoFe2O4) NPs with controlled shape, size, and crystallinity were successfully synthesized and used as PNC fillers in a commercial polymer provided by the Rogers Corporation and poly(vinylidene fluoride). Magnetic and microwave experiments were conducted under frequencies of 1-6 GHz in the presence of …


Mattes J., 2015. Reisen Ins Unterirdische. Eine Kulturgeschichte Der Höhlenforschung In Österreich Bis In Die Zwischenkriegszeit. [Travelling Into The Underground. A Cultural History Of Cave Exploration In Austria Through The Interwar Years], Monika Schöner Nov 2016

Mattes J., 2015. Reisen Ins Unterirdische. Eine Kulturgeschichte Der Höhlenforschung In Österreich Bis In Die Zwischenkriegszeit. [Travelling Into The Underground. A Cultural History Of Cave Exploration In Austria Through The Interwar Years], Monika Schöner

International Journal of Speleology

No abstract provided.


Towards Computational Human Behavior Modeling For Just-In-Time Adaptive Interventions, Tylar Murray Nov 2016

Towards Computational Human Behavior Modeling For Just-In-Time Adaptive Interventions, Tylar Murray

USF Tampa Graduate Theses and Dissertations

The advent of powerful wearable devices and smartphones has enabled a new generation of “in-the-wild” user studies, adaptive behavioral intervention strategies, and context measurement. Though numerous proof-of-concept studies continue to push the limitations of what a behavioral scientist can do with these technologies, there remains a major methodological roadblock separating behavioral theory and application. Avatar-user interaction theory, for example, is not well defined in its formulation, and thus guidelines for intervention designers depend on heuristic methods and designer intuition. Computational modeling has been slow to move into behavioral science in general, but a growing population of behavioral scientists recognize this …


Optimal Demand Response Models With Energy Storage Systems In Smart Grids, Mohemmed Masooud Alhaider Nov 2016

Optimal Demand Response Models With Energy Storage Systems In Smart Grids, Mohemmed Masooud Alhaider

USF Tampa Graduate Theses and Dissertations

This research aims to develop solutions to relieve system stress conditions in electric grids. The approach adopted in this research is based on a new concept in the Smart Grid, namely, demand response optimization. A number of demand response programs with energy storage systems are designed to enable a community to achieve optimal demand side energy management.

The proposed models aim to improve the utilization of the demand side energy through load management programs including peak shaving, load shifting, and valley lling. First, a model is proposed to nd the optimal capacity of the battery energy storage system (BESS) to …


Hydrolytic And Nonhydrolytic Sol-Gel Zirconia-, Titania-, And Niobia-Based Capillary Microextraction Coatings For The Preconcentration And Hplc Analysis Of Catecholamine Neurotransmitters And Phosphorylated Peptides, Abdullah Awadh Alhendal Nov 2016

Hydrolytic And Nonhydrolytic Sol-Gel Zirconia-, Titania-, And Niobia-Based Capillary Microextraction Coatings For The Preconcentration And Hplc Analysis Of Catecholamine Neurotransmitters And Phosphorylated Peptides, Abdullah Awadh Alhendal

USF Tampa Graduate Theses and Dissertations

Sample preparation is the most error-prone step in chemical analysis. A great deal of efforts has been made to develop efficient techniques and protocols for sample preparation to accomplish important goals such as miniaturization and implementation of green analytical methodologies. Solid-phase microextraction (SPME) has successfully eliminated the use of hazardous organic solvents in extraction sampling, sample preparation, preconcentration and sample introduction to the analytical instrument in an effective manner. Ensuring thermal- and solvent-instability of traditional SPME extraction phases represented one of their main drawbacks. This was solved by the introduction of sol-gel SPME phases characterized by enhanced thermal-, solvent-, and …


Surface Properties Of Titanium Dioxide And Its Structural Modifications By Reactions With Transition Metals, Sandamali Halpegamage Nov 2016

Surface Properties Of Titanium Dioxide And Its Structural Modifications By Reactions With Transition Metals, Sandamali Halpegamage

USF Tampa Graduate Theses and Dissertations

Surfaces of metal oxides play a vital role in many technologically important applications. The surfaces of titanium dioxide, in particular, show quite promising properties that can be utilized in solid-state gas sensing and photocatalysis applications. In the first part of this dissertation we investigate these properties of TiO2 surfaces through a vigorous surface scientific approach. In the second part, we investigate the possibilities of modifying the TiO2 surfaces by depositing multi-component transition metal oxide monolayers so that the properties of bare TiO2 surface can be influenced in a beneficial way. For instance, via formation of new surface …


Novel Magnetic Nanostructures For Enhanced Magnetic Hyperthermia Cancer Therapy, Zohreh Nemati Porshokouh Nov 2016

Novel Magnetic Nanostructures For Enhanced Magnetic Hyperthermia Cancer Therapy, Zohreh Nemati Porshokouh

USF Tampa Graduate Theses and Dissertations

In this dissertation, I present the results of a systematic study on novel multifunctional nanostructure systems for magnetic hyperthermia applications. All the samples have been synthesized, structurally/magnetically characterized, and tested for magnetic hyperthermia treatment at the Functional Materials Laboratory of the University South Florida. This work includes studies on four different systems: (i) Core/shell Fe/γ-Fe2O3 nanoparticles; (ii) Spherical and cubic exchange coupled FeO/Fe3O4 nanoparticles; (iii) Fe3O4 nano-octopods with different sizes; (iv) High aspect ratio FeCo nanowires and Fe3O4 nanorods.

In particular, we demonstrated the enhancement of the heating …


Expansion Of The Performance Capabilities Of The Usf Inhalation Challenge Chamber, Laura Riley Nov 2016

Expansion Of The Performance Capabilities Of The Usf Inhalation Challenge Chamber, Laura Riley

USF Tampa Graduate Theses and Dissertations

The purpose of this research was to evaluate the capability and performance of the University of South Florida’s (USF) Human Exposure Chamber (HEC) using aerosols in the thoracic range. The goals of this research were two-fold: to obtain an average particle size of 10 µm (thoracic-size range) inside the chamber during dust production and to test for evenness of dust concentration within the chamber. The USF HEC can be used for studies using gases and/or particulates. The chamber measurements are 4.16 ft x 2.67 ft x 6.75 ft, for a total volume of 75 ft3 or 2.13 m3 …