Physical Sciences and Mathematics Commons^™

Achieving Reliable Generation \& Delivery Of Energy Through Robust Optimization, Anna Danandeh

USF Tampa Graduate Theses and Dissertations

In this dissertation, we elaborate on the inherent risks and uncertainties in power systems and associated industries, and develop practical solution methods to eliminate their adverse effects.

our research agenda consists of practice-driven problems in different stages of power generation as follows. (1) Affordable fuel procurement through developing a comprehensive fuel supply chain design and operations planning system for electricity generation companies, (2) reliable electricity generation through incorporating dynamic asset rating concept in the unit commitment problem, and (3) efficient demand management through proposing a job scheduling model for effective local generation consumption.

Since reliability cannot be compromised in energy …

Experimental Investigation Of Encapsulated Phase Change Materials For Thermal Energy Storage, Tanvir E. Alam

USF Tampa Graduate Theses and Dissertations

Thermal energy storage (TES) is one of the most attractive and cost effective solutions to the intermittent generation systems like solar, wind and other renewable sources, compared to alternatives. It creates a bridge between the power supply and demand during peak hours or at times of emergency to ensure the continuous supply of energy. Among all the TES systems, latent heat thermal energy storage (LHTES) draws lots of interests as it has high energy density and can store or retrieve energy isothermally. Two major technical challenges associated with the LHTES are low thermal conductivity of the phase change materials (PCMs), …

Sustainability Planning, Environmental Justice And Climate Change: Applications Of The Long Island Markal Model, David S. Friedman, Yehuda Klein, Jose Pillich, Michael T. Sullivan

Suburban Sustainability

As pointed out by many authors, sustainability is often vague and amorphous (See, for example, Dovers, 1989; Faber, et al, 2005; Glavič, et al. 2007). There is a clear need to make analytical and data-driven analyses of established and or proposed plans. MARKAL (MARKet ALlocation model) is an analytical tool that can be used characterize the impacts of sustainability plans at multiple spatial scales: global, national, regional, and local. In this study we apply the Long Island MARKAL model to answer three interrelated issues: 1, the development and incremental improvement of local and regional sustainability plans; 2, the impact of …

Organic Fluids And Passive Cooling In A Supercritical Rankine Cycle For Power Generation From Low Grade Heat Sources, Rachana Vidhi

USF Tampa Graduate Theses and Dissertations

Low grade heat sources have a large amount of thermal energy content. Due to low temperature, the conventional power generation technologies result in lower efficiency and hence cannot be used. In order to efficiently generate power, alternate methods need to be used. In this study, a supercritical organic Rankine cycle was used for heat source temperatures varying from 125°C to 200°C. Organic refrigerants with zero ozone depletion potential and their mixtures were selected as working fluid for this study while the cooling water temperature was changed from 10-25°C. Operating pressure of the cycle has been optimized for each fluid at …

A Multi-Period Mixed Integer Linear Programming Model For Desalination And Electricity Co-Generation In Kuwait, Nael Abdulhameed Alqattan

USF Tampa Graduate Theses and Dissertations

Water is the root of life and the engine that drives agriculture, industry, economy and services. The demand for water often necessitates desalination, particularly in arid coastal environments where there are several desalination technologies in use today such as Multi-Effect Distillation (MED) and Reverse Osmosis (RO). The key utility requirement for technologies such as desalination and population in general include energy in one form or another. Therefore, desalination and co-generation are often integrated. Another key utility is electricity which is generated from either renewable or non-renewable sources. The demands for water and electricity change over time and are subject to …

Algae: Opportunities For Biomass Feedstock Production, Wastewater Treatment And Educational Outreach, Trina Cassandra Halfhide

USF Tampa Graduate Theses and Dissertations

Algae are a diverse group of simple organisms that lack roots, stems or leaves and are able to use sunlight, carbon dioxide, and nutrients to produce complex compounds, such as carbohydrates, proteins and lipids. These compounds, especially lipids, are highly sought-after by agricultural, nutraceutical and energy interests. Although there is great potential for algae derived biofuels, there are technical and economic challenges associated with their cultivation. Relevant to this dissertation, the environmental impacts associated with algae cultivation can be reduced by using municipal and agricultural wastewaters as a water and nutrient source. This research was divided into three sections to …

Impedance Extraction By Matlab/Simulink And Labview/Multisim, Jen-Pin Lin

USF Tampa Graduate Theses and Dissertations

This thesis studies the techniques of small-signal impedance measurement in three-phase power systems. Stability issue has become critically important since power electronics are highly applied in power distribution and conversion systems. Controlled output systems cause the risk of instability. In order to obtain the impedance model, an impedance extraction in D-Q reference frame algorithm is developed. This paper also applied Interpolated Fast Fourier Transform to increase accuracy of impedance model. Based on the voltage injection, Phase-Locked Loop, Park Transform, D-Q reference frame, and IPFFT. Three-phase system has been realigned on D-Q coordinate and impedance model is extracted in this form. …

Calculating The Solar Energy Of A Flat Plate Collector, Ariane Rosario

Undergraduate Journal of Mathematical Modeling: One + Two

The amount of solar energy that could be obtained by a flat plate solar collector of one square meter dimension is calculated in three different locations: Tampa FL, Fairbanks AL, and Pontianak Indonesia, considering the varying sunset time for each day of the year. The results show that if the collectors are placed near the equator, more total energy could be obtained. In fact, by placing a solar collector in Pontianak, Indonesia 12.42% more solar energy can be obtained than by placing it in Tampa and 96.9% more solar energy than Alaska.

A Study On The Optimization Of Dye-Sensitized Solar Cells, Md Imran Khan

USF Tampa Graduate Theses and Dissertations

Considering biocompatibility, the Dye Sensitized Solar Cell (DSC) based on titanium dioxide should play a major role in the future of solar energy. In this ongoing study, different components and ambient process conditions for the fabrication of were investigated. Titanium dioxide substrate thickness and morphology was found to have a direct impact on the cell efficiency. Scanning Electron Microscopy (SEM) was used to investigate the TiO2 nanostructure. Different chemical treatments and electrolytes were also explored towards optimizing the cell performance. A group of porphyrin based organic dyes were synthesized and evaluated. Standard solar cell characterization techniques such as current-voltage and …

Synthesis And Investigations Of Type I And Ii Clathrates Of Group 14, Michael Blosser

USF Tampa Graduate Theses and Dissertations

Clathrates are a class of new materials that have an open-framework structure that allows guest atoms or molecules to be enclosed inside of their polyhedral framework. Varying the number, weight, and size of the guest species in a particular framework allows one to alter the physical properties of the clathrate. This relationship enables one to further the fundamental understanding of the physics and chemistry of the clathrate structure and use this knowledge to "tune" certain properties. This "tunability" of inorganic clathrates is of great interest as it allows one to optimize their physical properties; making them promising candidates for a …

Novel Models And Algorithms For Uncertainty Management In Power Systems, Long Zhao

USF Tampa Graduate Theses and Dissertations

This dissertation is a collection of previously-published manuscript and conference papers. In this dissertation, we will deal with a stochastic unit commitment problem with cooling systems for gas generators, a robust unit commitment problem with demand response and uncertain wind generation, and a power grid vulnerability analysis with transmission line switching. The latter two problems correspond to our theoretical contributions in two-stage robust optimization, i.e., how to efficiently solve a two-stage robust optimization, and how to deal with mixed-integer recourse in robust optimization. Due to copyright issue, this dissertation does not include any methodology papers written by the author during …

Control Of Smart Building Using Advanced Scada, Vivin Thomas Samuel

USF Tampa Graduate Theses and Dissertations

ABSTRACT

For complete control of the building, a proper SCADA implementation and the optimization strategy has to be build. For better communication and efficiency a proper channel between the Communication protocol and SCADA has to be designed.

This paper concentrate mainly between the communication protocol, and the SCADA implementation, for a better optimization and energy savings is derived to large scale industrial buildings. The communication channel used in order to completely control the building remotely from a distant place. For an efficient result we consider the temperature values and the power ratings of the equipment so that while controlling the …

Development Of Nanostructured Graphene/Conducting Polymer Composite Materials For Supercapacitor Applications, Punya A. Basnayaka

USF Tampa Graduate Theses and Dissertations

The developments in mobile/portable electronics and alternative energy vehicles prompted engineers and researchers to develop electrochemical energy storage devices called supercapacitors, as the third generation type capacitors. Most of the research and development on supercapacitors focus on electrode materials, electrolytes and hybridization. Some attempts have been directed towards increasing the energy density by employing electroactive materials, such as metal oxides and conducting polymers (CPs). However, the high cost and toxicity of applicable metal oxides and poor long term stability of CPs paved the way to alternative electrode materials. The electroactive materials with carbon particles in composites have been used substantially …

Application And Characterization Of Self-Assembled Monolayers In Hybrid Electronic Systems, Michael Enoch Celesin

USF Tampa Graduate Theses and Dissertations

In this study, we explore ultra-thin insulators of organic and inorganic composition and their potential role as high-speed rectifiers. Typical applications for these structures include IR sensing, chemical detection, high speed logic circuits, and MEMS enhancements. While there are many elements in the functional group required to create a rectifying antenna (rectenna), the primary thrust of this work is on the rectifier element itself.

To achieve these research goals, a very good understanding of quantum tunneling was required to model the underlying phenomenon of charge conduction. The development of a multi-variable optimization routine for tunneling prediction was required. MATLAB was …

Hydrogen Storage In Hypercrosslinked Polystyrene And Li-Mg-N-H Complex Hydride, Dervis Emre Demirocak

USF Tampa Graduate Theses and Dissertations

In this dissertation, hydrogen storage enhancement in hypercrosslinked polystyrene, effects of single walled carbon nanotubes (SWCNTs) supported ruthenium (Ru) catalyst on the kinetics and ammonia suppression in the LiNH2-MgH2 complex hydride system and the accuracy of hydrogen storage measurements are investigated in detail.

High surface area physisorption materials are of interest for room temperature hydrogen storage enhancement by spillover. Six different commercially available hypercrosslinked polystyrenes are screened by considering the specific surface area, average pore size, pore volume, and adsorption enthalpy. MN270 is selected mainly due to its high surface area and narrow pores for investigation of the spillover enhancement …

Effect Of Solids Retention Time On The Denitrification Potential Of Anaerobically Digested Swine Waste, Maureen Njoki Kinyua

USF Tampa Graduate Theses and Dissertations

Three continuously stirred tank reactors (CSTR) were operated in semi continuous mode treating swine waste using anaerobic digestion. The reactors were used to test the effect of solid retention time (SRT) on CH4 yield, total ammonia nitrogen (TAN) concentrations, % volatile solids (VS), chemical oxygen demand (COD) and volatile fatty acids (VFA) removal, readily biodegradable COD concentration and the denitrification potential for the effluent in a biological nutrient removal (BNR) system. During Phase I of the study, the three reactors were operated at the same 28 day SRT for 16 weeks. SRTs were then changed during the 12 week Phase …

Innovative Desalination Systems Using Low-Grade Heat, Chennan Li

USF Tampa Graduate Theses and Dissertations

Water and energy crises have forced researchers to seek alternative water and energy sources. Seawater desalination can contribute towards meeting the increasing demand for fresh water using alternative energy sources like low-grade heat. Industrial waste heat, geothermal, solar thermal, could help to ease the energy crisis.

Unfortunately, the efficiency of the conventional power cycle becomes

uneconomically low with low-grade heat sources, while, at the same time, seawater desalination requires more energy than a conventional water treatment process. However, heat discarded from low-grade heat power cycles could be used as part of desalination energy sources with seawater being used as coolant …

Synthesis And Characterization Of Nanocomposites For Electrochemical Capacitors, Farah Alvi

USF Tampa Graduate Theses and Dissertations

Presently there are deep concerns over the environmental consequences and the consumption of non-renewable energy sources, with the accelerated greenhouse effect, triggered enormous interest in the use of renewable energy sources e.g., solar, hydropower, wind and geothermal. However the intermittent nature of harvesting renewable energy sources has recently gained considerable attention in the alternative reliable, cost effective, and environmentally friendly energy storage devices. The supercapacitor and lithium ion batteries are considered more efficient electrical energy storage devices than conventional energy storage systems.

Both devices have many useful and important applications; they could be an excellent source for high power and …

Design Of Colloidal Composite Catalysts For Co2 Photoreduction And For Co Oxidation, Bijith D. Mankidy

USF Tampa Graduate Theses and Dissertations

In this doctoral dissertation, novel colloidal routes were used to synthesize nanomaterials with unique features. We have studied the impact of nanoparticle size of catalyst, role of high surface area of a photocatalyst, and the effect of varying elemental composition of co-catalytic nanoparticles in combination with core-shell plasmonic nanoparticles. We have demonstrated how physical and chemical characteristics of nanomaterials with these unique features play a role in catalytic reactions, specifically the oxidation of CO and the photoreduction of CO2. The first objective of this doctoral dissertation involved the preparation of CoO nanoparticles with discrete nanoparticles sizes (1-14 nm) using a …

Encapsulation Of High Temperature Phase Change Materials For Thermal Energy Storage, Rupa Nath

USF Tampa Graduate Theses and Dissertations

Thermal energy storage is a major contributor to bridge the gap between energy demand (consumption) and energy production (supply) by concentrating solar power. The utilization of high latent heat storage capability of phase change materials is one of the keys to an efficient way to store thermal energy. However, some of the limitations of the existing technology are the high volumetric expansion and low thermal conductivity of phase change materials (PCMs), low energy density, low operation temperatures and high cost. The present work deals with encapsulated PCM system, which operates at temperatures above 500°C and takes advantage of the heat …

Novel Blends Of Sulfur-Tolerant Water-Gas Shift Catalysts For Biofuel Applications, Timothy Michael Roberge

USF Tampa Graduate Theses and Dissertations

As traditional sources of energy become depleted, significant research interest has gone into conversion of biomass into renewable fuels. Biomass-derived synthesis gas typically contains concentrations of approximately 30 to 600 ppm H2S in stream. H2S is a catalyst poison which adversely affects downstream processing of hydrogen for gas to liquid plants. The water-gas shift reaction is an integral part of converting CO and steam to H2 and CO2. Currently, all known water-gas shift catalysts deactivate in sulfur concentrations typical of biomass-derived synthesis gas. Novel catalysts are needed to remain active in the presence of sulfur concentrations in order to boost …

Catalytic Tri-Reforming Of Biomass-Derived Syngas To Produce Desired H2:Co Ratios For Fuel Applications, Devin Mason Walker

USF Tampa Graduate Theses and Dissertations

This study focuses on upgrading biomass derived syngas for the synthesis of liquid fuels using Fischer-Tropsch synthesis (FTS). The process includes novel gasification of biomass via a tri-reforming process which involves a synergetic combination of CO2 reforming, steam reforming, and partial oxidation of methane. Typical biomass-derived syngas H2:CO is 1:1 and contains tars that deactivate FT catalyst. This innovation allows for cost-effective one-step production of syngas in the required H2:CO of 2:1 with reduction of tars for use in the FTS. To maximize the performance of the tri-reforming catalyst, an attempt to control oxygen mobility, thermal stability, dispersion of metal, …

Crack Analysis In Silicon Solar Cells, Maria Ines Echeverria Molina

USF Tampa Graduate Theses and Dissertations

Solar cell business has been very critical and challenging since more efficient and low costs materials are required to decrease the costs and to increase the production yield for the amount of electrical energy converted from the Sun's energy. The silicon-based solar cell has proven to be the most efficient and cost-effective photovoltaic industrial device. However, the production cost of the solar cell increases due to the presence of cracks (internal as well as external) in the silicon wafer. The cracks of the wafer are monitored while fabricating the solar cell but the present monitoring techniques are not sufficient when …

Assessment Of Methods To Manipulate Thermal Emission And Evaluate The Quality Of Thermal Radiation For Direct Energy Conversion, Samantha Wijewardane

USF Tampa Graduate Theses and Dissertations

ABSTRACT

Control of spectral thermal emission from surfaces may be desirable in some energy related applications, such as nano-scale antenna energy conversion and thermophotovoltaic conversion. There are a number of methods, from commercially available paints to advanced surface gratings that can be used to modify the thermal emission from a surface. To find out the proper emission controlling technique for a given energy conversion method all the surface emission controlling methods are comprehensively reviewed regarding the emission control capabilities and the range of possible applications. Radiation with high degree of coherence can be emitted using advanced surface emission controlling techniques. …

Water's Dependence On Energy: Analysis Of Embodied Energy In Water And Wastewater Systems, Weiwei Mo

USF Tampa Graduate Theses and Dissertations

Water and wastewater treatment is a critical service provided for protecting human health and the environment. Over the past decade, increasing attention has been placed on energy consumption in water and wastewater systems for the following reasons: (1) Water and energy are two interrelated resources. The nexus between water and energy can intensify the crises of fresh water and fossil fuel shortages; (2) The demand of water/wastewater treatment services is expected to continue to increase with increasing population, economic development and land use change in the foreseeable future; and (3) There is a great potential to mitigate energy use in …

Tracking The Deepwater Horizon Oil Spill: A Modeling Perspective, Yonggang Liu, Robert H. Weisberg, Chuanmin Hu, Lianyuan Zheng

Yonggang Liu

The Deepwater Horizon oil spill was caused by a drilling rig explosion on 20 April 2010 that killed 11 people. It was the largest oil spill in U.S. history and presented an unprecedented threat to Gulf of Mexico marine resources. Although oil gushing to the surface diminished after the well was capped, on 15 July 2010, much remains to be known about the oil and the dispersants beneath the surface, including their trajectories and effects on marine life. A system for tracking the oil, both at the surface and at depth, was needed for mitigation efforts and ship survey guidance. …

Evaluation Of Trajectory Modeling In Different Dynamic Regions Using Normalized Cumulative Lagrangian Separation, Yonggang Liu, Robert H. Weisberg

Yonggang Liu

The Lagrangian separation distance between the endpoints of simulated and observed drifter trajectories is often used to assess the performance of numerical particle trajectory models. However, the separation distance fails to indicate relative model performance in weak and strong current regions, such as a continental shelf and its adjacent deep ocean. A new skill score is proposed based on the cumulative Lagrangian separation distances normalized by the associated cumulative trajectory lengths. This skill score is used to evaluate surface trajectories implied by Global HYCOM hindcast surface currents as gauged against actual satellite-tracked drifter trajectories in the eastern Gulf of Mexico …

Evolution Of The Loop Current System During The Deepwater Horizon Oil Spill Event As Observed With Drifters And Satellites, Yonggang Liu, Robert H. Weisberg, Charles Kovach, Rolf Riethmüller

Yonggang Liu

The ocean circulation patterns of the Gulf of Mexico (GOM) Loop Current (LC) system and their effects on the advection of the oil discharged during the Deepwater Horizon incident are described using in situ surface drifter trajectories and satellite observations from May to August 2010. These observations include altimetry-derived surface geostrophic velocities, sea surface temperature, ocean color, and surface oil locations. The elongated, northwestward penetrating LC retreated back from its northernmost position in late April 2010 and stayed farther away from the surface oil in the north during May 2010. Although the main body of the surface oil slick remained …

Smart Grid Functionality Of A Pv-Energy Storage System, Nenad Damnjanovic

USF Tampa Graduate Theses and Dissertations

Renewable Energy will be the key to preserving the Earth's remaining resources and continuing this surge of technological progress that we have experienced this past century. New philosophies of how/when/where energy should be consumed and produced are attempting to improve upon the current grid infrastructure. The massive advancement in communications, renewable and control systems will allow this new-age electric grid to maximize its efficiency while reducing cost. Renewable, "green" energy is now at the forefront of innovation. As the world population increases, there will be a need to free ourselves from natural resources as much as possible. Advanced Energy Storage …

Simplified Methodology For Designing Parabolic Trough Solar Power Plants, Ricardo Vasquez Padilla

USF Tampa Graduate Theses and Dissertations

The performance of parabolic trough based solar power plants over the last 25 years has proven that this technology is an excellent alternative for the commercial power industry. Compared to conventional power plants, parabolic trough solar power plants produce significantly lower levels of carbon dioxide, although additional research is required to bring the cost of concentrator solar plants to a competitive level. The cost reduction is focused on three areas: thermodynamic efficiency improvements by research and development, scaling up of the unit size, and mass production of the equipment. The optimum design, performance simulation and cost analysis of the parabolic …