Physical Sciences and Mathematics Commons^™

Separation Of Organic Acids Through Direct Catalysis From Sugars, Katelyn Robinson

Chemical Engineering Undergraduate Honors Theses

Society relies on plastic products, whether they are single use or durable. A downside of plastic is that the most common type is a product of oil and oil is not only a limited resource but also a climate-damaging resource. Polylactic acid (PLA) is a bio-based, biodegradable plastic. However, the process of converting biomass to polylactic acid polymer has the largest environmental impact of the PLA production process, so alternative methods of conversion are needed (Moretti et al., 2021). The polylactic acid polymer can be made with lactic acid, which can be converted from glucose.

A Consumer's Guide To Greenwashing, Katie Fowler

Marketing Undergraduate Honors Theses

Over the past 37 years since the term greenwashing was coined, there have been sparse attempts to regulate this deceptive environmental marketing. The Federal Trade Commission (FTC) created its Guides for the Use of Environmental Marketing Claims, also known as the Green Guides, in 1992. The Guides have been revised on three separate occasions – 1996, 1998, and 2012 – in an attempt to remain relevant with the proliferation of environmental marketing claims and trends. However, the Guides were created as interpretive rules that do not give the FTC the authority to enforce the regulations unless they can prove that …

Understanding The Operations And Decision-Making Of Cow-Calf Farmers In Northwest Arkansas, Clayton Weyl

Agricultural Economics and Agribusiness Undergraduate Honors Theses

Societal pressure on farmers has become a more central part of the rhetoric surrounding livestock production. This study includes farmers in the discourse on the rhetoric surrounding climate change via interviews and simulations tailored to their operation. Previous research has addressed regenerative agricultural practices and conditions that influence farmer decision-making, but little research has analyzed decision-making in tandem with environmental practices. The literature reveals that cow-calf producer decision-making is influenced by their reliance on cattle as an income source, and farmers overall choose climate-friendly practices based on their perceptions about climate change. The goal of this research was to gather …

Open Source Intelligence For Cybersecurity Events Via Twitter Data, Dakota Dale

Graduate Theses and Dissertations

Open-Source Intelligence (OSINT) is largely regarded as a necessary component for cybersecurity intelligence gathering to secure network systems. With the advancement of artificial intelligence (AI) and increasing usage of social media, like Twitter, we have a unique opportunity to obtain and aggregate information from social media. In this study, we propose an AI-based scheme capable of automatically pulling information from Twitter, filtering out security-irrelevant tweets, performing natural language analysis to correlate the tweets about each cybersecurity event (e.g., a malware campaign), and validating the information. This scheme has many applications, such as providing a means for security operators to gain …

Analysis On High Mass X-Ray Binary Spectral Shape Dependence On Luminosity For Ngc3310, Izabela Pavel

Physics Undergraduate Honors Theses

In most normal galaxies, the most X-ray luminous sources are high-mass X-ray binaries (HMXBs), which are binary star systems that contain compact objects (black holes or neutron stars) accreting from massive (> 8M⊙) companion stars. These HMXBs are thought to have been important sources of ionizing emission within star-forming galaxies that may have contributed to the heating of the intergalatic medium (gas over large cosmic scales) in the early Universe. When studying how HMXBs contribute to interstellar medium feedback, a single spectral shape of an absorbed power-law is typically assumed to be universal. The goal of this thesis is to …

Biochar As A Lake Management Option For Harmful Algal Blooms: Lab Experiments And Bioassays, Brittany Mc Intyre

Graduate Theses and Dissertations

Harmful Algal Blooms (HABs) are an increasing global concern for water management due to their increased frequency, distribution, and toxin production. In freshwaters the growth of cyanobacteria (commonly known as blue-green algae), due to anthropogenic nutrient enrichment is the primary driver of HABS; these are often referred to as cyanoHABs. The management of cyanoHABs should be focused on in the watershed through best management and conservation practices or the physical, chemical and biomanipulation of the lake or reservoir that is experiencing these blooms. In this study, we examine the use of biochar as an option for the management or treatment …

On The Impact Of Inclination-Dependent Attenuation On The Derived Star Formation Histories Of Disk Galaxies, Keith Doore

Graduate Theses and Dissertations

The physical properties of a galaxy (e.g., its star-formation history and dust content) regulate the distribution of light that is emitted by stars and attenuated by the interstellar gas and dust. This attenuation by dust can have a significant impact on the observed spectral energy distribution (SED) of a disk galaxy, especially when taking into account its viewing angle (i.e., inclination). For example, as the inclination angle of a galactic disk changes from face-on to edge-on (i.e., i = 0 deg to i = 90 deg), the proportion of light that is attenuated along the line of sight increases, due …

Linux Malware Obfuscation, Brian Roden

Computer Science and Computer Engineering Undergraduate Honors Theses

Many forms of malicious software use techniques and tools that make it harder for their functionality to be parsed, both by antivirus software and reverse-engineering methods. Historically, the vast majority of malware has been written for the Windows operating system due to its large user base. As such, most efforts made for malware detection and analysis have been performed on that platform. However, in recent years, we have seen an increase in malware targeting servers running Linux and other Unix-like operating systems resulting in more emphasis of malware research on these platforms. In this work, several obfuscation techniques for Linux …

Fabrication Of Black Phosphorus Terahertz Photoconductive Antennas, Nathan Tanner Sawyers

Physics Undergraduate Honors Theses

Terahertz (THz) photoconductive antennas (PCAs) using 40nm thin-film flakes of black phosphorus (BP) and hexagonal boron nitride (hBN) have been shown computationally to be capable of THz emission comparable to those based on GaAs [2]. In this paper, I briefly describe the scientific and practical interest in THz emissions and explain what warrants research into black phosphorus as a photoconductive semiconductor in THz devices. Furthermore, I outline the basic principle of how these antennas work and mention alternative designs produced by other researchers in the past. Finally, I summarize the fabrication process of these antennas, as well as the measurements …

Design Of A Hyperstable Endocrine Acting Fibroblast Growth Factot, Sara Armstrong

Chemistry & Biochemistry Undergraduate Honors Theses

A novel chimera protein, consisting of the C-terminus of Fibroblast Growth Factor (FGF) 21 and super FGF1, a mutant of the wild-type FGF1, was studied. The protein retained the stability of sFGF1 and the endocrine acting behaviors and binding efficiency of FGF21, so that it could be more practical for therapeutic uses as a wound healing and angiogenic agent. sFGF1- FGF21 was expressed and purified before utilizing various biophysical techniques to measure its stability, secondary and tertiary characteristics, and metabolic activity.

Detection Of Nitrogen Dioxide Via Graphene-Enhanced Raman Scattering, Spencer Hazeslip

Chemistry & Biochemistry Undergraduate Honors Theses

This paper presents the development of a nitrogen dioxide (NO₂) sensor that utilizes the phenomenon of graphene-enhanced Raman scattering (GERS). The sensor consists of monolayer graphene on a silicon wafer, functionalized noncovalently with Copper(II) 2,9,16,23-tetra-tert-butyl-29H,31H-phthalocyanine (CuTTPc) via the solution soaking method. A custom sensing chamber was constructed to enable Raman spectra to be collected during NO₂ exposure. The response of the sensor was found to be linear between 10 and 100 ppm NO₂, indicating that it could be used for both detection and quantification. Furthermore, the sensor was shown to be reusable after …

Framing How We Think About Curves, Megan Sattler

Mathematical Sciences Undergraduate Honors Theses

A frame defines a basis at a point in R^n, and we can frame a curve by placing one at every point along it. This thesis investigates adapted framed curves in R^2 and R^3 in which they are used to provide information about how a curve twists and turns. We derive differential information from the frames that describe how they change and consequently how the curve changes. We also deduce special properties of each framing and discuss how the differential information suffices to describe the shape of curves.

An Experimental Study Into Tholin's Solubility With Liquid Hydrocarbons On Titan, Katherine Dzurilla

Graduate Theses and Dissertations

Titan’s production of organics in its atmosphere and the liquid hydrocarbon lakes present on its surface make it a prime target for astrobiologists. Many previous studies on laboratory analogs of these organics, called "tholins", have found amino acids, nitriles, and other building blocks necessary for life. The potential solubility of tholins in the lakes of Titan presents an opportunity to create physical and chemical changes within the organics. While the lakes of Titan are primarily comprised of nonpolar compounds (methane and ethane), many predict that very small amounts of polar hydrocarbons are also present. To better understand these processes, researchers …

Exploring Ferroelectric Phenomena In Batio3, Linbo3, And Liznsb: From Extended Oxygen Vacancies To Tri-Stable Polarization And Giant Hyperferroelectricity, Shaohui Qiu

Graduate Theses and Dissertations

This dissertation presents three projects that investigate the complex phenomena of ferroelectricity under different conditions in BaTiO3, LiNbO3, and LiZnSb using first-principles density functional calculations. Extended defects in ferroelectric solids play a crucial role in reducing the lifetime and performance of ferroelectric devices by causing fatigue, domain pinning, and aging. Thus, understanding their impact is of critical importance for the development of reliable and high-performance ferroelectric devices. In addition, hyperferroelectricity is an intriguing phenomenon that has attracted much attention in recent years. Despite the existence of depolarization field, spontaneous polarization persists under an open-circuit boundary condition (OCBC), making hyperferroelectric materials …

Insights Into Star Formation And Agn Activity In Protocluster Environments From Morphological Studies And Sed Fitting, Erik B. Monson

Graduate Theses and Dissertations

In this dissertation I present work done from 2018-2023 to investigate the growth of galaxies and supermassive black holes (SMBH) in high redshift overdensities (protoclusters) by studying the star-forming galaxy and active galactic nucleus (AGN) population in the SSA22 protocluster. I examined possible environmental sources of the enhanced star formation and AGN activity in the z = 3.09 SSA22 protocluster using Hubble WFC3 ∼ 1.6 μm observations of the SSA22 field, including new observations centered on eight X-ray selected protocluster AGN. To investigate the role of mergers in the observed AGN and star formation enhancement, quantitative and visual morphological classifications …

Understanding And Tuning Magnetism In Van Der Waals Magnetic Compounds, Rabindra Basnet

Graduate Theses and Dissertations

The recently discovered two-dimensional (2D) magnetism has attracted intensive attention due to possible magnetic phenomenon arising from 2D magnetism and their promising potential for spintronics applications. The advances in 2D magnetism have motivated the study of layered magnetic materials, and further enhanced our ability to tune their magnetic properties. Among various layered magnets, tunable magnetism has been widely investigated in metal thiophosphates MPX3. It is a class of magnetic van der Waals (vdW) materials with antiferromagnetic ordering persisting down to atomically thin limit. Their magnetism originates from the localized moments due to 3d electrons in transition metal ions. So, their …

Improving Classification In Single And Multi-View Images, Hadi Kanaan Hadi Salman

Graduate Theses and Dissertations

Image classification is a sub-field of computer vision that focuses on identifying objects within digital images. In order to improve image classification we must address the following areas of improvement: 1) Single and Multi-View data quality using data pre-processing techniques. 2) Enhancing deep feature learning to extract alternative representation of the data. 3) Improving decision or prediction of labels. This dissertation presents a series of four published papers that explore different improvements of image classification. In our first paper, we explore the Siamese network architecture to create a Convolution Neural Network based similarity metric. We learn the priority features that …

First-Principal Investigations Of The Electronic, Magnetic, And Thermoelectric Properties Of Crtirhal Quaternary Heusler Alloy, Shuruq Alsayegh

Graduate Theses and Dissertations

Density functional theory calculations are performed to investigate the electrical electronic, magnetic, and thermoelectric properties of CrTiRhAl quaternary Heusler alloy (QHA). The type-I atomic configuration is found to be the most stable structure of this alloy. The CrTiRhAl QHA exhibits a half-metallic ferromagnetic structure with a narrow band gap at one spin channel (semiconductor), and a metallic behavior at the other spin channel. This corresponds to a 100% spin-polarization, making it ideal for potential spintronic applications. Applying the semi-classical Boltzmann theory, the Seebeck coefficient, electrical conductivity, and electronic thermal conductivity of CrTiRhAl alloy were calculated. The predicted figure of merit …

An Age, Size, And Climate Response Study Of Old Growth Shortleaf Pine In The Mccurtain County Wilderness Area, Oklahoma, Nicholas Cancalosi-Dean

Graduate Theses and Dissertations

Increment cores were extracted from 483 trees distributed over 21 semi-randomly sampled 0.1-hectare plots on three distinct landscape positions in the McCurtain County Wilderness Area (MCWA), a 57 square kilometer tract of uncut shortleaf pine in southeastern Oklahoma. Forty additional cores were taken off plot from older-appearing trees. All sampled trees were shortleaf pine (Pinus echinata) with a diameter at breast height (DBH) of at least 10 cm. Hardwoods were not included in the size and age analyses. The study site chosen for the sampling was made up of four parallel east-west trending ridges near North Linson Creek, making up …

Effects Of Land Use On Soil Microbial Communities In Tropical Montane Forests Of Malaysian Borneo, Yang Kai Tang

Graduate Theses and Dissertations

Land use, such as logging and forest conversion to agriculture, can modify soil physicochemical and biological properties, and affect soil health. To understand how land use change can impact soil properties and canopy structure, we used a land use gradient in Malaysian Borneo consisting of six sites, including old growth forests, mixed forests, and agriculture fields. Specifically, we aimed to answer the following questions: (1) How do soil physicochemical properties vary across land use types? (2) Does bacterial diversity and composition vary across different land use types? (3) Does fungal diversity and composition vary across different land use types? We …

The Terroir Of Swiss Cheese: A Temporal And Geomorphological Investigation Of The Martian Co2 Sublimation Pits, Racine D. Cleveland

Graduate Theses and Dissertations

Observations by NASA Mars Global Surveyor showed evidence of rough topography on the South Pole of Mars. The topography is the result of CO2 sublimation processes that occur through the changing seasons on the red planet. These sublimation areas are known to scientists as Swiss Cheese Features (SCF). SCF are erosional degradation pits that have been studied for over two decades. Studies show that these SCF increase in area over time, but these values are collected by hand on a per feature basis. Models for the pit evolution have also played a part in understanding these SCF. This work is …

Achieving Causal Fairness In Recommendation, Wen Huang

Graduate Theses and Dissertations

Recommender systems provide personalized services for users seeking information and play an increasingly important role in online applications. While most research papers focus on inventing machine learning algorithms to fit user behavior data and maximizing predictive performance in recommendation, it is also very important to develop fairness-aware machine learning algorithms such that the decisions made by them are not only accurate but also meet desired fairness requirements. In personalized recommendation, although there are many works focusing on fairness and discrimination, how to achieve user-side fairness in bandit recommendation from a causal perspective still remains a challenging task. Besides, the deployed …

Asymptotic Properties And Separation Rates For Navier-Stokes Flows, Patrick Michael Phelps

Graduate Theses and Dissertations

In this dissertation, we investigate asymptotic properties of local energy solutions to the Navier-Stokes equations and develop an application which controls the separation of non-unique solutions in this class. Specifically, we quantify the rate at which two, possibly unique solutions evolving from the same data may separate pointwise away from a singularity. This is motivated by recent results on non-uniqueness for forced and unforced Navier-Stokes and analytical and numerical evidence suggesting non-uniqueness in the Leray class. Our investigation begins with discretely self-similar solutions known to exist globally in time and to be regular outside a space-time paraboloid. We prove decay …

Subterraneans: A Regional Earth Dwelling For Comfort And Beauty, Isaak Benchoff

Architecture Undergraduate Honors Theses

Subterraneans is a study of an affordable, self-sufficient, sustainable, and dignified housing prototype for the region of Northwest Arkansas. It is a design process investigation based on the ideas of turning a local, sustainable material into affordable homes that can be built within a community of people sharing land and resources. The homes would utilize as many natural materials as possible to minimize the impact on the Earth and the cost to the owners.

Research looked at many different vernacular building precedents as well as the work done by contemporary design firms in the area of economical, low-impact, and passively …

Low-Cost Microstereolithography 3d Printing With Microfluidic Microsampling Applications, Lauren Twombly

Chemistry & Biochemistry Undergraduate Honors Theses

The growing field of stereolithography 3D printing has welcomed a new age ofmicrofluidic device fabrication techniques. When compared to previous planar fabrication techniques such as soft-lithography, stereolithography 3D printing offers highly automated procedures, reduced fabrication times, and greater complexity of device features. To date, the greatest tradeoff for 3D printing in microfluidic device fabrication is poorer resolution when compared to soft-lithography which can produce feature sizes on the nanometer scale. The poorer resolution of 3D printing limits the feasible size of features. While highly sophisticated 3D printers are capable of achieving sub 10 μm resolution, these instruments are incredibly expensive …

Internship Thesis - Happy Egg Co., Annelise Koster

Data Science Undergraduate Honors Theses

This paper outlines a data science internship at Happy Egg Co, a producer of free-range eggs committed to sustainable agriculture practices. The internship focused on analyzing customer data to uncover characteristics of Happy Egg Co's target market and identify potential new markets for expansion.

The internship spanned a period of 10 weeks and involved working with the company's marketing and data science teams to gain practical experience in data cleaning, analysis, and visualization. The focus was on uncovering patterns and trends in customer behavior, preferences, and demographics to inform marketing strategies.

The internship began with an introduction to Happy Egg …

Evaluating Snow And Ice Cover In Tierra Del Fuego, Argentina, Zoe Pitman

Geosciences Undergraduate Honors Theses

Evaluating changes in snow and ice cover is an important field for studying climate change and its impacts. This evaluation is commonly done using remote sensing because of its ability to evaluate large areas. The purpose of this study is to determine the reliability of one remote sensing technology, the Moderate Resolution Imaging Spectroradiometer (MODIS), by comparing it to in-situ snow and climate data from the weather station at the Austral Center for Scientific Research (CADIC). Data was converted from daily to monthly averages and was sorted into a series of graphs to compare the two data sets. Correlations were …

Geochemical Analysis And Numerical Modeling Of Central And East Tennessee Mississippi Valley-Type Ore Districts: Constraints On Ore Genesis, Jackson Price Copeland

Geosciences Undergraduate Honors Theses

A simple two-way stochastic mixing model is presented for analysis of the lead (Pb) isotope compositions of the North American Mississippi Valley-Type (MVT) districts of East Tennessee, Central Tennessee, and Central Kentucky. Four distinct mixing scenarios were run to critically evaluate the stochastic model and examine different hypotheses regarding the genesis of Central Tennessee and Central Kentucky MVT deposits. Additionally, Pb isotope analysis was conducted on sphalerite samples from the Central and East Tennessee MVT districts. Model and sampling results suggest that Central Tennessee and Central Kentucky ores likely formed by mixing of three fluids. In contrast to conclusions from …

Developing A Multi-Platform Application To Facilitate Internal Campus Hiring, Carissa Patton

Computer Science and Computer Engineering Undergraduate Honors Theses

Undergraduate research has proven to be highly beneficial to students, yet there are many students who do not know how to get involved or who are too timid to approach professors to inquire about potential research opportunities. Our hypothesis is that a cross-platform application has the potential to bridge the gap and help more students get involved in undergraduate research by providing them information about open positions and the faculty or staff members who are mentoring the projects. The key focus of this thesis is to develop an application that provides details about participating faculty or staff including their research …

Realtime In-Network Cyberattack Detection In Power Grid Systems Using A Programmable Network, Luke Waind

Computer Science and Computer Engineering Undergraduate Honors Theses

Power grid communication networks are important systems to detect intrusions from an attacker due to them being necessary to maintain critical infrastructure. This thesis applies recent advancements in P4 technology to detect cyberattacks in SCADA systems. In previous work, a list has been compiled of potential attacks that exploit one of the most common protocols in SCADA systems, DNP3. Solutions for detecting these attacks can be categorized by the broad methods that they use. The two methods that are focused on are single-packet inspection and multiple-packet inspection. For each of these, a specific attack is chosen and a detection algorithm …