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Articles 1 - 30 of 67
Full-Text Articles in Physical Sciences and Mathematics
Raman Spectroscopy For Forensic Identification Of Body Fluid Traces: Method Validation For Potential False Negatives Caused By Blood-Affecting Diseases, Niara Nichols
Chemistry
Two critical issues in forensic science are identifying body fluid traces found at crime scenes and preserving them for DNA analysis. However, the majority of current biochemical tests for body fluid identification, which are applicable at the crime scene, are presumptive and destructive to the sample. Raman Spectroscopy provides a suitable alternative to current methods as a nondestructive, confirmatory, and potentially in field method. Our laboratory has developed a chemometric model for the identification of five main body fluids using Raman spectroscopy. This model was developed using samples obtained from healthy donors. Thus, it is of most importance for the …
Development Of Bioaffinity Based Assays For Forensic Applications, Juliana Maria Agudelo Cano
Development Of Bioaffinity Based Assays For Forensic Applications, Juliana Maria Agudelo Cano
Legacy Theses & Dissertations (2009 - 2024)
In the field of forensic science, body fluids are a major contributor of evidence in investigations. However, body fluids are usually used only for their genetic content, overlooking its unique composition of proteins and low-molecular-weight compounds that often serve as biomarkers in clinical diagnostics. This investigation aimed to develop simple, effective, and economical models that can be used to identify different attributes of the originator. The focus of this research was to develop biocatalytic cascades that could analyze body fluids by using UV-Vis spectroscopy. These models could be implemented in forensic settings, as well as in biometric authentications. The central …
Reliability Characterization Of A Low-K Dielectric Using Its Magnetoresistance As A Diagnostic Tool, Philip Alister Williams
Reliability Characterization Of A Low-K Dielectric Using Its Magnetoresistance As A Diagnostic Tool, Philip Alister Williams
Legacy Theses & Dissertations (2009 - 2024)
The introduction of low dielectric constant materials within the integrated circuit (IC) chip technology industry was a concerted effort to decrease the resistance-capacitance (RC) time delay inherent within the dielectric materials used as insulators. This stems from a demand for greater device density per IC chip and decreased feature sizes but is fast becoming a reliability issue. Concomitant with the demand for decreased feature sizes, also in adherence with Moore’s Law (which states that the number of devices on a die doubles every two years), is a reduction in device speed and performance due to device intra-level interconnection signal delays. …
Entropic Density Functional Theory : Entropic Inference And The Equilibrium State Of Inhomogeneous Fluids, Ahmad Yousefi
Entropic Density Functional Theory : Entropic Inference And The Equilibrium State Of Inhomogeneous Fluids, Ahmad Yousefi
Legacy Theses & Dissertations (2009 - 2024)
A unified formulation of the density functional theory is constructed on the foundations of entropic inference in both the classical and the quantum regimes. The theory is introduced as an application of entropic inference for inhomogeneous fluids in thermal equilibrium. It is shown that entropic inference reproduces the variational principle of DFT when informationabout expected density of particles is imposed. In the classical regime, this process introduces a family of trial density-parametrized probability distributions, and consequently a trial entropy, from which the preferred one is found using the method of Maximum Entropy (MaxEnt). In the quantum regime, similarly, the process …
The Contributions Of Dynamical And Diabatic Processes Preceding And Accompanying Major Greenland Ice-Melt Events, Scott Feldman
The Contributions Of Dynamical And Diabatic Processes Preceding And Accompanying Major Greenland Ice-Melt Events, Scott Feldman
Legacy Theses & Dissertations (2009 - 2024)
Extratropical cyclones and/or short-wave disturbances can reinforce Greenland blocking through upper-level flow amplification and can increase poleward heat and moisture transport into the Arctic. Increased poleward heat and moisture transport into the Arctic may enhance Greenland ice melt during the spring, summer, and fall months. The need to better understand the underlying dynamical and diabatic processes that may contribute to Greenland ice melt motivates this thesis. The purpose of this thesis is to investigate: 1) the role of advective warming due to poleward heat and moisture transport into the Arctic in facilitating Greenland ice melt, 2) the role of adiabatic …
The Impacts Of Transported Wildfire Smoke Aerosol On Surface Air Quality In New York State, Wei-Ting Hung
The Impacts Of Transported Wildfire Smoke Aerosol On Surface Air Quality In New York State, Wei-Ting Hung
Legacy Theses & Dissertations (2009 - 2024)
In New York State (NYS), summertime long-range transported smoke plumes and high fine mode particulate matter (PM2.5) concentration during the smoke episodes have been reported. Since the frequency, intensity, and burned area of wildfires over Northern America have increased in recent years, the contribution of transported smoke aerosols to local air quality could become more significant. This study aimed to characterize the transport of smoke aerosols and quantify their impacts on the local air quality over NYS. A case study of a transported smoke event in mid-August of 2018 and multi-year analysis of the smoke cases during the summer seasons …
Image Data Analysis And Design Optimization Of The Snowball Chamber, Yujia Huang
Image Data Analysis And Design Optimization Of The Snowball Chamber, Yujia Huang
Legacy Theses & Dissertations (2009 - 2024)
Dark Matter is the invisible massive particle that makes up over 26.8 percent of the mass-energy content of the universe. Weakly Interacting Massive Particles, or WIMPs, are one of the candidates of dark matter particles. Many scientists around the world are trying to figure out how to detect detect dark matter using either indirect search, direct production or direct detection experiments. However, due to the lack of evidence of finding WIMPs in direct detection experiments at a large mass scale, a call for investigating WIMPs at a lower mass range is attracting more attention.
Development Of Visible-Light-Mediated Photoredox Catalysis, Sarbjeet Kaur
Development Of Visible-Light-Mediated Photoredox Catalysis, Sarbjeet Kaur
Legacy Theses & Dissertations (2009 - 2024)
ABSTRACT
Preliminary Results Of Measurements Of Potentially Cancerogenic 1,4-Dioxane In Surface Water Of Twin Lakes Preserve, Wantagh, Ny, Lijo Jose Varghese
Preliminary Results Of Measurements Of Potentially Cancerogenic 1,4-Dioxane In Surface Water Of Twin Lakes Preserve, Wantagh, Ny, Lijo Jose Varghese
Legacy Theses & Dissertations (2009 - 2024)
1,4-dioxane is a volatile organic compound categorized by the United States Environmental Protection agency (EPA, 2017) as a possible human carcinogen potent to cause tumors in humans. Even though this compound poses significant environmental danger when it contaminates water sources, it is surprisingly less studied, and how it behaves in surface water is less understood. The biggest 1,4-dioxane plume in the United States is located in Long Island region of New York. The purpose of this study was to investigate the presence of 1,4-dioxane in surface water and document the influence of existing 1,4-dioxane plume to Twin Lakes Preserve. To …
Molecular And Supramolecular Structures Of Triiodides And Polyiodobismuthates Of Phenylenediammonium And Its N,N-Dimethyl Derivative, Evgeny V. Dikarev, Zheng Wei, Tatiana A. Shestimerova, Nikita A. Golubev, Mikhail A. Bykov, Andrei V. Mironov, Sergey A. Fateev, Alexey B. Tarasov, Ivan Turkevych, Andrei V. Shevelkov
Molecular And Supramolecular Structures Of Triiodides And Polyiodobismuthates Of Phenylenediammonium And Its N,N-Dimethyl Derivative, Evgeny V. Dikarev, Zheng Wei, Tatiana A. Shestimerova, Nikita A. Golubev, Mikhail A. Bykov, Andrei V. Mironov, Sergey A. Fateev, Alexey B. Tarasov, Ivan Turkevych, Andrei V. Shevelkov
Chemistry Department Faculty Scholarship
Despite remarkable progress in photoconversion efficiency, the toxicity of lead-based hybrid perovskites remains an important issue hindering their applications in consumer optoelectronic devices, such as solar cells, LED displays, and photodetectors. For that reason, lead-free metal halide complexes have attracted great attention as alternative optoelectronic materials. In this work, we demonstrate that reactions of two aromatic diamines with iodine in hydroiodic acid produced phenylenediammonium (PDA) and N,N-dimethyl-phenylenediammonium (DMPDA) triiodides, PDA(I3)2⋅2H2O and DMPDA(I3)I, respectively. If the source of bismuth was added, they were converted into previously reported PDA(BiI4)2⋅I2 …
The Foundations Of Inference And Its Application To Fundamental Physics, Nicholas Matthew Carrara
The Foundations Of Inference And Its Application To Fundamental Physics, Nicholas Matthew Carrara
Legacy Theses & Dissertations (2009 - 2024)
This thesis concerns the foundations of inference – probability theory,entropic inference, information geometry, etc. – and its application to the Entropic Dynamics (ED) approach to Quantum Mechanics (QM) [21, 22, 41, 53, 56–61, 150–153, 165, 195, 196, 268]. The first half of this thesis, chapters 2-6, concern the development of the inference framework. We begin in chapter 2 by discussing de- ductive inference, which involves formal logic and it’s role in access- ing the truth of propositions. We eventually discover that deductive inference is incomplete, in that it can’t address situations in which we have incomplete information. This necessitates a …
Understanding Complex Human Activities In Videos : The Study Of Concurrent Activity Detection And Group Activity Recognition, Yi Wei
Legacy Theses & Dissertations (2009 - 2024)
Human activity understanding, as one of the most important task in video analysis, has been studied for decades. Great efforts have been made to push the activity recognition models towards effective and efficient representation learning. However, it is difficult to define an explicit semantic organization of activities, even for human. Current activity recognition benchmarks only organize the activity labels with shallow hierarchies, which hinders the development of activity recognition system.
Impact Of Inconsistent Imputation Models In Mediation Analysis, Bo Ye
Impact Of Inconsistent Imputation Models In Mediation Analysis, Bo Ye
Legacy Theses & Dissertations (2009 - 2024)
In this dissertation, we study the impact of inconsistent imputation methods in mediation analysis and its application. We present the study in three papers.
The Effect Of Differential Friction On Tropical Cyclone Development Close To Land, Minghao Zhou
The Effect Of Differential Friction On Tropical Cyclone Development Close To Land, Minghao Zhou
Legacy Theses & Dissertations (2009 - 2024)
Hurricane Karl (2010) underwent unexpected rapid intensification in the Bay of Campeche while remaining in close proximity (within 150 km) to land. It is hypothesized that the frictionally-enhanced inflow contributed positively to this evolution, despite reduced surface fluxes and increased momentum loss over land. In this study, the role of differential friction in the development of a tropical cyclone (TC) tracking parallel to a coastline is examined based on this prototype.A series of high-resolution, semi-idealized numerical simulations with full physics were conducted on a β-plane with curvature effects of the Earth. After initializing a TC from a synoptic-scale thermal perturbation, …
Molecular Simulation Of Rna Conformational Dynamics : An Example Of Micro-Rna Targeting Messenger Rna : Mir-34a-Msirt1, Parisa Ebrahimi
Molecular Simulation Of Rna Conformational Dynamics : An Example Of Micro-Rna Targeting Messenger Rna : Mir-34a-Msirt1, Parisa Ebrahimi
Legacy Theses & Dissertations (2009 - 2024)
MicroRNA (miRNA), as a distinct class of biological regulators and a ”guide” member of non-coding RNA-protein complexes (RNPs), regulates more than 60% of protein-coding genes expression through base-pairing with targeted messenger RNA (mRNA) in the RNA-Induced Silencing Complex (RISC). Most of miRNAs identified in human, are conserved in other animals, which have preferentially conserved interaction sites particularly in 3’ untranslated regions (3’UTRs) of many human messenger mRNAs.The capability of a single miRNA to target more than hundreds of mRNAs, suggests that miRNAs influence essentially all developmental process and diseases, which also makes them interesting candidates as therapeutics agents. The primary …
Molecular Simulation Of Rna Conformational Dynamics : An Example Of Micro-Rna Targeting Messenger Rna : Mir-34a-Msirt1, Parisa Ebrahimi
Molecular Simulation Of Rna Conformational Dynamics : An Example Of Micro-Rna Targeting Messenger Rna : Mir-34a-Msirt1, Parisa Ebrahimi
Legacy Theses & Dissertations (2009 - 2024)
MicroRNA (miRNA), as a distinct class of biological regulators and a ”guide” member of non-coding RNA-protein complexes (RNPs), regulates more than 60% of protein-coding genes expression through base-pairing with targeted messenger RNA (mRNA) in the RNA-Induced Silencing Complex (RISC). Most of miRNAs identified in human, are conserved in other animals, which have preferentially conserved interaction sites particularly in 3’ untranslated regions (3’UTRs) of many human messenger mRNAs.The capability of a single miRNA to target more than hundreds of mRNAs, suggests that miRNAs influence essentially all developmental process and diseases, which also makes them interesting candidates as therapeutics agents. The primary …
Exploring Environmental And Methodological Sensitivities Of Forecasted And Observed Surface Winds And Gusts Using Underutilized Datasets, Alex Roslyn Gallagher
Exploring Environmental And Methodological Sensitivities Of Forecasted And Observed Surface Winds And Gusts Using Underutilized Datasets, Alex Roslyn Gallagher
Legacy Theses & Dissertations (2009 - 2024)
Accurate forecasts and reliable observations of surface mean winds and gusts inhabit a vast and essential role in meteorological applications that range from wind energy, atmospheric transport, fire weather, and hazard assessment. This dissertation aims to address and explore known shortfalls in the prediction of mean winds and gusts as well as enhance evaluation and understanding of observed surface wind measurements. A variety of forecasts, methodologies, and observational dataset, many of which have been previously un- or under-utilized, are leveraged to tackle the differing needs of assessing mean winds, gusts, and the surface environment.Detailed verifications of HRRR (version 3 and …
Simulation Analysis Of The Snowball Chamber, Thomas Guile
Simulation Analysis Of The Snowball Chamber, Thomas Guile
Legacy Theses & Dissertations (2009 - 2024)
Dark matter is non-baryonic, weakly interacting matter that makes up nearly 85% of the mass ofour universe, as seen through many different phenomena such as gravitational lensing and flat galactic rotation curves [48]. There are many experiments across the globe that are working to find these dark matter particles, but despite increasing levels of detector sensitivity, dark matter has been difficult to detect. Because of this, it is possible that dark matter has a lower mass than originally predicted. A new detector, the Snowball Chamber, could be used to aid in this search. By using the light molecule of water, …
Conditional And Marginal Imputation Models For Multilevel Data, Gang Liu
Conditional And Marginal Imputation Models For Multilevel Data, Gang Liu
Legacy Theses & Dissertations (2009 - 2024)
This dissertation study extends sequential hierarchical regression imputation (SHRIMP) methods to multilevel datasets with three levels of nesting and proposes a marginal method based on marginalized multilevel model (MMM) framework. Specifically, the proposed model consists of two levels such that the first level relates the marginal mean of responses with covariates through a generalized regression model and the second level includes subject specific random effects within the same generalized regression model. To draw the inference on the population-averaged or subject-specified coefficients, the hierarchical regression and/or MMM is applied as the imputation and estimation models. We employ Markov Chain Monte Carlo …
Objective Methodology To Identify The Sea Breeze Circulation And Associated Low-Level Jet In The New York Bight, Elizabeth J. Mccabe
Objective Methodology To Identify The Sea Breeze Circulation And Associated Low-Level Jet In The New York Bight, Elizabeth J. Mccabe
Legacy Theses & Dissertations (2009 - 2024)
While the sea breeze has been studied for decades, in a complicated mid-latitude coastal region such as the New York Bight (NYB), the general thermodynamic structure and dynamics of the circulation is poorly characterized. The East Coast of the United States has become a critical area for offshore wind farm development, including a generally favorable wind resource, relatively shallow waters on an extensive continental shelf, frequent warm season sea breezes, and proximity to large populated areas. Thus the sea breeze will play a key role in the new energy economy, given the favorable wind speeds and capacity factors during periods …
Two Dimensional Nanoparticles/Nanozymes For Biosensing Augmented By Machine Learning, Nidhi Chintan Nandu
Two Dimensional Nanoparticles/Nanozymes For Biosensing Augmented By Machine Learning, Nidhi Chintan Nandu
Legacy Theses & Dissertations (2009 - 2024)
Biosensing is an ever-evolving field with many resources devoted towards new approaches in sensing and refining the existing methods. For a long time, such approaches involved use of state-of-the-art instruments and were often proved to be time consuming and expensive. Nanoparticles with their unique properties, inexpensive synthesis and ease of manipulation have found purpose in myriad fields including biosensing. Different nanoparticles based on their composition, morphology, dimensionality, and surface modifications have already gained foot hold in the biosensor ranks. The unique opto-electric properties due to the quantum effect in the nanoparticles have also made them one of the leading alternatives …
It Takes Two To Tango : Understanding The Processes That Lead To Simultaneous Changes In Tropical Cyclone Intensity And Size And Communicating The Associated Hazards To Emergency Managers, Emily A. Paltz
Legacy Theses & Dissertations (2009 - 2024)
The severity of tropical cyclone (TC) hazards is modulated by both TC intensity and size. More intense TCs produce stronger storm surges and increase wind damage. Larger TCs potentially impact more people, increase the duration of TC hazards, produce stronger storm surges and increase the amount of rainfall and flooding. Thus, accurately forecasting both TC intensity and size and effectively communicating those forecasts are critical to properly preparing communities for TC impacts. Forecast accuracy can be improved by enhancing our understanding about the processes that cause changes in TC intensity and size. This research divides the Extended Best Track dataset …
Theoretical And Observational Analysis Of Ice Particles For Improvement Of Ice Microphysical Models, Vanessa Przybylo
Theoretical And Observational Analysis Of Ice Particles For Improvement Of Ice Microphysical Models, Vanessa Przybylo
Legacy Theses & Dissertations (2009 - 2024)
Frozen hydrometeors can grow to acquire a multitude of shapes and sizes, which influence the distribution of mass within cloud systems. Aggregates have a variety of formations based on initial ice particle size, shape, falling orientation, and the number of particles that collect. This work employs the theoretical Ice Particle and Aggregate Simulator (IPAS) as a statistical tool to repetitively collect ice crystals to derive bulk aggregate characteristics.
Predictability Issues Associated With Near-Freezing Precipitation Type In Complex Terrain, Matthew Seymour
Predictability Issues Associated With Near-Freezing Precipitation Type In Complex Terrain, Matthew Seymour
Legacy Theses & Dissertations (2009 - 2024)
Predictability challenges are heightened in winter weather forecasting when the environment for high-impact weather is marginal or varies over short distances. High-resolution numerical weather prediction (NWP), such as the High-Resolution Rapid Refresh (HRRR), and ensemble forecast systems, such as the Global Ensemble Forecast System (GEFS), are useful for constraining forecasts. However, their use can be challenging in marginal, near-freezing, situations when precipitation type is uncertain. Uncertainties in planetary boundary layer (PBL) and microphysics (MP) parameterizations and subtle synoptic-scale model errors brought on by differences in initial and lateral boundary conditions (IC/BCs) complicate the p-type forecast. Further, complex terrain, such as …
A Mechanism For Upscale Growth Of Convection In The Complex Terrain Of The Northeast U.S, Brennan Joseph Stutsrim
A Mechanism For Upscale Growth Of Convection In The Complex Terrain Of The Northeast U.S, Brennan Joseph Stutsrim
Legacy Theses & Dissertations (2009 - 2024)
Upstate New York has a variety of complex terrain that can interact with the background flow to create mesoscale heterogeneities in the lower troposphere. The major valleys of Upstate New York, the Hudson and Mohawk Valleys, often have increased moisture content and stronger surface winds than the higher terrain surrounding them. These features can have a profound effect on the evolution of convective storms, especially in cases characterized by low-to-moderate shear, which tends to favor pulse-like or multicellular convection. Analysis of composite radar imagery has indicated that convective storms often change mode while descending from the Catskills Mountains into the …
Comparison Of Raman Spectra Of Smokeless Powders For Cartridge Differentiation, Nathan Bartlett
Comparison Of Raman Spectra Of Smokeless Powders For Cartridge Differentiation, Nathan Bartlett
Chemistry
As crimes involving firearms continue to be prevalent, forensic methods processing firearms evidence must keep pace with the changes in said evidence. Scanning Electron Microscopy with Energy Dispersive Spectroscopy, or SEM-EDS, is a method that targets the inorganic portions of gunshot residue (GSR) evidence, namely lead, barium, and antimony, to characterize a cartridge used at a crime scene, and was the most often used analysis method for characterizing ammunition cartridges. The rise of lead-free ammunition has made it so that SEM-EDS alone is not sufficient for the characterization of inorganic gunshot residue (IGSR), and studies have shifted towards being able …
The Business Of Chemistry: The Effect Of Chemical Innovation On The U.S. Cosmetics Market, Tania Gonzalez
The Business Of Chemistry: The Effect Of Chemical Innovation On The U.S. Cosmetics Market, Tania Gonzalez
Chemistry
This study discusses the relationship between two distinct fields of study: chemistry and economics. Chemistry is a business in itself and has major effects on the US economy. Examining the U.S cosmetics market and the recent development of organic products will show the effect on market growth and the growing importance of organic cosmetics in the United States. The recent awareness and concern for eco-friendly and safer ingredients fueled by millennials is discussed. The average annual expenditure in the U.S. cosmetics market is examined and inflation is taken into account. The purpose is to show the importance of research in …
Statistical And Variational Modeling And Analysis Of Passive Integrated Photonic Devices, Norbert Dinyi Agbodo
Statistical And Variational Modeling And Analysis Of Passive Integrated Photonic Devices, Norbert Dinyi Agbodo
Legacy Theses & Dissertations (2009 - 2024)
The success of Si as a platform for photonic devices and the associated availabilityof wafer-scale, ultra-high resolution lithography for Si CMOS has helped lead to the rapid advance of Si-based integrated photonics manufacturing over the past decade. This evolution is nearing the point of integration of Si-based photonics together with Si-CMOS for compact, high speed, high bandwidth, and cost-effective devices. However, due to the sensitive nature of passive and active photonic devices, variations inherent in wafer-based fabrication processes can lead to unacceptable levels of performance variation both within a give die and across a given wafer. Fully understanding the role …
Examining The Benefits Of A Sustained Balance And Fall Prevention Programming For Independent Older Adults Living In A Community Setting, Noah Davis
Legacy Theses & Dissertations (2009 - 2024)
Falls have been an identified public health and social problem since the 1980’s and now recognized as a global health problem in many of the developed nations. The National Council on Aging and the Centers for Disease Control and Prevention acknowledge many evidence-based fall prevention programs. However, there are identified concerns to the programs; for example, a lack of sustained programming for older adults in the community setting. The literature review on fall prevention interventions identifies that few programs are sustained after two years, primarily due to a lack of funding and a lack of interest by older adults. However, …
Diagnosing High Sinuosity Regimes Associated With Anomalous Greenland Ice-Melt Events Using Self-Organizing Maps, Mansour El Riachy
Diagnosing High Sinuosity Regimes Associated With Anomalous Greenland Ice-Melt Events Using Self-Organizing Maps, Mansour El Riachy
Legacy Theses & Dissertations (2009 - 2024)
Sinuosity, a metric that describes the waviness of the circumpolar flow, is adapted to quantify modification of the tropospheric polar vortex within longitudinal sectors by localized incursions of warm, moist air from middle latitudes associated with Arctic cyclones (ACs). In this thesis, we identify four corridors of high AC track frequency, on which we center 90° longitudinal sectors comprising the following regions: Pacific, West of Greenland, Atlantic, and Asian. Sectorial sinuosity is calculated for the West of Greenland sector and is used to quantify the amplitude of the 300-hPa flow associated with anomalous Greenland ice-melt events.