Physical Sciences and Mathematics Commons^™

A New Generation Of Functional Polyisobutylenes For Advanced Applications, Corey M. Parada

Dissertations

Polyisobutylene (PIB) is a fully saturated, aliphatic polymer of high commercial importance due to its superior gas barrier properties and high chemical/oxidative stability. One commercial end-use for PIB is in insulated glass windows (IGU), where it acts as a gas/moisture barrier and sealant. Under certain adverse conditions, catastrophic failure of the PIB sealant may result in aesthetic and functional failure of the IGU, which necessitates replacement of the unit. Thus, there exists a need to improve current generations of thermoplastic PIB sealants to be able to withstand the harsh environments found in current real-world applications.

In the first project, we …

Polyhedral Oligomeric Silsesquioxane-Phosphate Glass Matrix Nanocomposites With Additional Chapter On Phosphate Glass-Poly(Ethylene Terephthalate) Matrix Composites, Kyoungtae Kim

Dissertations

Preparation and characterization of tin fluorophosphate glass (Pglass) matrix nanocomposites incorporating polyhedral oligomeric silsesquioxane (POSS) were investigated on the structural, thermal, morphological, mechanical, and rheological properties. Various processes including synthesis, extrusion and sintering processes were applied to prepare the nanocomposite samples. Another application of POSS with hydrophobic functional groups on the well-structured nanoscale silicate cage with three silanol groups was investigated to present the feasibility to use POSS molecule as a coating material on the surface of the hydrophilic inorganic glass. In addition, Poly(ethylene terephthalate) polymer matrix composites incorporating Pglass was studied to present the benefits of the Pglass with …

Predicted Deepwater Bathymetry From Satellite Altimetry: Non-Fourier Transform Alternatives, Maxsimo Salazar

Dissertations

Robert Parker (1972) demonstrated the effectiveness of Fourier Transforms (FT) to compute gravitational potential anomalies caused by uneven, non-uniform layers of material. This important calculation relates the gravitational potential anomaly to sea-floor topography. As outlined by Sandwell and Smith (1997), a six-step procedure, utilizing the FT, then demonstrated how satellite altimetry measurements of marine geoid height are inverted into seafloor topography. However, FTs are not local in space and produce Gibb’s phenomenon around discontinuities. Seafloor features exhibit spatial locality and features such as seamounts and ridges often have sharp inclines. Initial tests compared the windowed-FT to wavelets in reconstruction of …

Effect Of Network Structure On Free Volume And Gas Transport Properties Of Thiol-Ene And Epoxy-Amine Networks, Ramesh Krishnan Ramakrishnan

Dissertations

Network parameters such as cross-link density or intermolecular interactions were used as effective parameters to control polymer chain packing or free volume and thereby control the mass transport properties of networks.

A series of polyethylene glycol (PEG) based thiol-ene elastomeric networks having a broad range of molecular weight between cross-links, M_c, (inverse of cross-link density) was prepared. The specific volume of the networks was studied as a function of temperature and pressure using high pressure dilatometry, and the obtained PVT data was fit using Simha-Somcynsky equation of state (S-S eos) analysis. Fractional free volume, quantified through S-S eos …

Structure-Property Relationships Of Solvent-Cast Organic Thin Films For Model Corrosion Control Coatings, Austin Maples

Dissertations

This dissertation aimed at answering several fundamental questions, specifically: 1) What is the effect of scribing parameters on visual corrosion assessments? 2) What role do molecular weight, residual solvent, and polymer composition have on morphological changes in organic thin films? 3) What alternatives to visual assessments could be implemented to better understand and detect corrosion before macroscopic failure? This research definitively proved that scribes can vary in type and dimensions, and yet are still comparable if the scribe dimensions before exposure are known. Furthermore, it demonstrated that solvents common to a variety of coating industries could become trapped within the …

Computational Modeling Of Radiation Interactions With Molecular Nitrogen, Tyler Reese

Dissertations

The ability to detect radiation through identifying secondary effects it has on its surrounding medium would extend the range at which detections could be made and would be a valuable asset to many industries. The development of such a detection instrument requires an accurate prediction of these secondary effects. This research aims to improve on existing modeling techniques and help provide a method for predicting results for an affected medium in the presence of radioactive materials. A review of radioactivity and the interactions mechanisms for emitted particles as well as a brief history of the Monte Carlo Method and its …

Influence Of Natural And Anthropogenic Environmental Variability On Larval Fish Diet, Growth, And Condition In The Northcentral Gulf Of Mexico, Angie Hoover

Master's Theses

The northern Gulf of Mexico experiences high levels of freshwater runoff annually from various sources including the Mississippi River and Mobile Bay, among other sources. Early life history stages of fishes are especially vulnerable to environmental variability created by freshwater discharge. The objectives of this study were to describe the available prey field, diet, growth and condition of larval fishes with respect to various effects of freshwater discharge in the northern Gulf. The first chapter compared these parameters in larval Gulf Menhaden (Brevoortia patronus) collected from three different water masses characterized by physical and biological parameters after the …

Late Quaternary Evolution And Stratigraphic Framework Influence On Coastal Systems Along The North-Central Gulf Of Mexico, Usa, Robert Hollis

Master's Theses

Coastal systems in the Gulf of Mexico are threatened to reduced sediment supply, storm impacts and relative sea level rise (RSLR). The geologic record can provide insights of geomorphic threshold crossings (formation, progradation, transgression, destruction) to these forcing mechanisms to predict future barrier evolution to climate change. The stratigraphic framework and antecedent topography directly influence coastal evolution over geologic timescales. This study synthesizes ~2100km of geophysical data, 700+ sediment cores, and 63 radiocarbon dates to regionally map two sequence boundaries, multiple ravinement surfaces and fourteen depositional facies. One marine isotope stage (MIS) 6 valley’s fill provided up to 300 x10 …

Holocene Formation And Evolution Of Horn Island, Mississippi, Usa, Nina Gal

Master's Theses

Horn Island, one of the most stable barriers along the Mississippi-Alabama chain, provides critical habitat, helps regulate estuarine conditions in the Mississippi Sound, and reduces wave energy and storm surge for the mainland. This study integrates 2,200 km of high-resolution geophysics, 35 sediment cores, and 15 radiocarbon ages to better understand the formation and evolution of the island in response to sea-level rise, storms, and antecedent geology. The Biloxi and Pascagoula incised valleys converge at Horn Island and have played a profound role in the evolution of the system. Within the incised valleys, numerous shallow paleochannels between 4 and 9 …

Introduction To The French Geotraces North Atlantic Transect (Ga01): Geovide Cruise, Géraldine Sarthou, Pascale Lherminier, Eric P. Achterberg, Fernando Alonso-Pérez, Eva Bucciarelli, Julia Boutorh, Vincent Bouvier, Edward A. Boyle, Pierre Branellec, Lidia I. Carracedo, Nuria Casacuberta, Maxi Castrillejo, Marie Cheize, Leonardo Contreira Pereira, Daniel Cossa, Nathalie Daniault, Emmanuel De Saint-Léger, Frank Dehairs, Feifei Deng, Floriane Desprez De Gésincourt, Jérémy Devesa, Lorna Foliot, Debany Fonseca-Batista, Morgane Gallinari, Maribel I. Garciá-Ibáñez, Arthur Gourain, Emilie Grossteffan, Michel Hamon, Lars Eric Heimbürger, Gideon M. Henderson, Catherine Jeandel, Catherine Kermabon, François Lacan

Faculty Publications

© 2018 Author(s). The GEOVIDE cruise, a collaborative project within the framework of the international GEOTRACES programme, was conducted along the French-led section in the North Atlantic Ocean (Section GA01), between 15 May and 30 June 2014. In this special issue (https://www.biogeosciences.net/special-issue900.html), results from GEOVIDE, including physical oceanography and trace element and isotope cyclings, are presented among 18 articles. Here, the scientific context, project objectives, and scientific strategy of GEOVIDE are provided, along with an overview of the main results from the articles published in the special issue.

Response To Turner 2017, Amy M. Schueller, Robert T. Leaf, Raymond M. Mroch Iii, Geneviève M. Nesslage

Faculty Publications

No abstract provided.

Receiver-Initiated Handshaking Mac Based On Traffic Estimation For Underwater Sensor Networks, Yuan Dong, Lina Pu, Yu Luo, Zheng Peng, Haining Mo, Yun Meng, Yi Zhao, Yuzhi Zhang

Faculty Publications

In underwater sensor networks (UWSNs), the unique characteristics of acoustic channels have posed great challenges for the design of medium access control (MAC) protocols. The long propagation delay problem has been widely explored in recent literature. However, the long preamble problem with acoustic modems revealed in real experiments brings new challenges to underwater MAC design. The overhead of control messages in handshaking-based protocols becomes significant due to the long preamble in underwater acoustic modems. To address this problem, we advocate the receiver-initiated handshaking method with parallel reservation to improve the handshaking efficiency. Despite some existing works along this direction, the …

The Shape Of The Orbit In Flrw Spacetimes, David Garfinkle, Lawrence R. Mead, H.I. Ringermacher

Faculty Publications

The shape of the orbit of a free particle is examined in Friedmann-Lemaître-Robertson-Walker (FLRW) cosmologies. The spatial projection of the orbit is time-independent and has a simple geometric description. We relate this description to the expression in terms of standard FLRW coordinates.

Pva/Chitosan/Silver Nanoparticles Electrospun Nanocomposites: Molecular Relaxations Investigated By Modern Broadband Dielectric Spectroscopy, Mohammad K. Hassan, Ahmed Abukmail, Alaa J. Hassiba, Kenneth A. Mauritz, Ahmed A. Elzatahry

Faculty Publications

In this study, we used broadband dielectric spectroscopy to analyze polymer nanofibers of poly(vinyl alcohol)/chitosan/silver nanoparticles. We also studied the effect of incorporating silver nanoparticles in the polymeric mat, on the chain motion dynamics and their interactions with chitosan nanofibers, and we calculated the activation energies of the sub-T_g relaxation processes. Results revealed the existence of two sub-T_g relaxations, the first gets activated at very low temperature (−90 °C) and accounts for motions of the side groups within the repeating unit such as –NH₂, –OH, and –CH₂OH in chitosan and poly(vinyl alcohol). The second …

Information-Driven Inverse Approach To Disordered Solids: Applications To Amorphous Silicon, Dil K. Limbu, Raymond Atta-Fynn, David A. Drabold, Stephen R. Elliott, Parthapratim Biswas

Faculty Publications

© Physical Review Materials

Publisher's Version

Gogo: An Improved Algorithm To Measure The Semantic Similarity Between Gene Ontology Terms, Chenguang Zhao, Zheng Wang

Student Publications

Measuring the semantic similarity between Gene Ontology (GO) terms is an essential step in functional bioinformatics research. We implemented a software named GOGO for calculating the semantic similarity between GO terms. GOGO has the advantages of both information-content-based and hybrid methods, such as Resnik’s and Wang’s methods. Moreover, GOGO is relatively fast and does not need to calculate information content (IC) from a large gene annotation corpus but still has the advantage of using IC. This is achieved by considering the number of children nodes in the GO directed acyclic graphs when calculating the semantic contribution of an ancestor node …

Unexpected Effects Of Inorganic Phosphate Glass On Crystallization And Thermo-Rheological Behavior Of Polyethylene Terephthalate, Kyoungtae Kim, Shahab Kashani Rahimi, Todd M. Alam, Eric G. Sorte, Joshua U. Otaigbe

Faculty Publications

The effects of ultra-low glass transition temperature (T_g) phosphate glass (Pglass) on the thermal, morphological, rheological, mechanical, and crystallization properties of hybrid Pglass/poly(eththylene terephthalate)(PET) were investigated. Nano- and micro-scale distribution of the Pglass in the PET polymer matrix was observed. The polydispersed Pglass in the PET matrix functioned as a nucleation agent, resulting in increasing crystallization temperature. The Pglass in the PET matrix decreased the T_g, indicating a plasticizing effect of the Pglass in the hybrids that was confirmed by the significantly decreased complex viscosity of the PET matrix. In addition, with increasing temperature, a non-terminal …

A Maximum Entropy Method For Solving The Boundary Value Problem Of Second Order Ordinary Differential Equations, Congming Jin, Jiu Ding

Faculty Publications

We propose a new method to solve the boundary value problem for a class of second order linear ordinary differential equations, which has a non-negative solution. The method applies the maximum entropy principle to approximating the solution numerically. The theoretical analysis and numerical examples show that our method is convergent.

Malware Analysis On Android Using Supervised Machine Learning Techniques, Md Shohel Rana, Andrew H. Sung

Faculty Publications

In recent years, a widespread research is conducted with the growth of malware resulted in the domain of malware analysis and detection in Android devices. Android, a mobile-based operating system currently having more than one billion active users with a high market impact that have inspired the expansion of malware by cyber criminals. Android implements a different architecture and security controls to solve the problems caused by malware, such as unique user ID (UID) for each application, system permissions, and its distribution platform Google Play. There are numerous ways to violate that fortification, and how the complexity of creating a …

Quinolines From The Cyclocondensation Of Isatoic Anhydride With Ethyl Acetoacetate: Preparation Of Ethyl 4-Hydroxy-2-Methylquinoline-3-Carboxylate And Derivatives, Nicholas Jentsch, Jared D. Hume, Emily B. Crull, Samer M. Beauti, Amy H. Pham, Julie A. Pigza, Jacques Kessl, Matthew G. Donahue

Faculty Publications

A convenient two-step synthesis of ethyl 4-hydroxy-2-methylquinoline-3-carboxylate derivatives has been developed starting from commercially available 2-aminobenzoic acids. In step 1, the anthranilic acids are smoothly converted to isatoic anhydrides using solid triphosgene in THF. In step 2, the anhydride electrophiles are reacted with the sodium enolate of ethyl acetoacetate, generated from sodium hydroxide, in warm N,N-dimethylacetamide resulting in the formation of substituted quinolines. A degradation–build-up strategy of the ethyl ester at the 3-position allowed for the construction of the α-hydroxyacetic acid residue required for the synthesis of key arylquinolines involved in an HIV integrase project.

An Extension Of The Method Of Brackets: Part 1, Ivan Gonzalez, Karen T. Kohl, Lin Jiu, Victor H. Moll

Faculty Publications

The method of brackets is an efficient method for the evaluation of a large class of definite integrals on the half-line. It is based on a small collection of rules, some of which are heuristic. The extension discussed here is based on the concepts of null and divergent series. These are formal representations of functions, whose coefficients an have meromorphic representations for n 2 C, but might vanish or blow up when n 2 N. These ideas are illustrated with the evaluation of a variety of entries from the classical table of integrals by Gradshteyn and Ryzhik.

Left Ventricular Mechanical Dyssynchrony For Cad Diagnosis: Does It Have Incremental Clinical Values?, Zhixin Jiang, Weihua Zhou

Faculty Publications

No abstract provided.

Enhancement Of Triplet-Sensitized Upconversion In Rigid Polymers Via Singlet Exciton Sink Approach, Steponas Raišys, Saulius Juršėnas, Yoan C. Simon, Christoph Weder, Karolis Kazlauskas

Faculty Publications

To increase the practical usefulness of solid-state sensitized upconversion (UC) materials as components of solar energy harvesting systems, it is important to identify and suppress loss mechanisms, and increase the UC quantum yield (Φ_UC). Here we focus on a benchmark UC system consisting of the emitter 9,10-diphenylanthracene (DPA) and the sensitizer platinum octaethylporphyrin (PtOEP) in a rigid poly(methyl methacrylate) (PMMA) matrix, and show that one of the major losses originates from Förster resonant energy transfer (FRET) from DPA back to PtOEP. Even though DPA emission lies within the PtOEP transparency window, the quantitative assessment of singlet exciton diffusion …

Reliable Delay Based Algorithm To Boost Puf Security Against Modeling Attacks, Fathi Amsaad, Mohammaed Niamat, Amer Dawoud, Selcuk Kose

Faculty Publications

Silicon Physical Unclonable Functions (sPUFs) are one of the security primitives and state-of-the-art topics in hardware-oriented security and trust research. This paper presents an efficient and dynamic ring oscillator PUFs (d-ROPUFs) technique to improve sPUFs security against modeling attacks. In addition to enhancing the Entropy of weak ROPUF design, experimental results show that the proposed d-ROPUF technique allows the generation of larger and updated challenge-response pairs (CRP space) compared with simple ROPUF. Additionally, an innovative hardware-oriented security algorithm, namely, the Optimal Time Delay Algorithm (OTDA), is proposed. It is demonstrated that the OTDA algorithm significantly improves PUF reliability under varying …

Rational Design Of Superhydrophilic/Superoleophobic Surfaces For Oil-Water Separation Via Thiol-Acrylate Photopolymerization, Li Xiong, Wei Guo, Benjamin M. Alameda, Reese Sloan, William D. Walker, Derek L. Patton

Faculty Publications

We report a simple, rapid, and scalable strategy to fabricate surfaces exhibiting in-air superoleophobic/superhydrophilic wetting via sequential spray deposition and photopolymerization of nanoparticle-laden thiol–acrylate resins comprising both hydrophilic and oleophobic chemical constituents. The combination of spray deposition with nanoparticles provides hierarchical surface morphologies with both micro- and nanoscale roughness. Mapping the wetting behavior as a function of resin composition using high- and low-surface-tension liquid probes enabled facile identification of coatings that exhibit a range of wetting behavior, including superhydrophilic/superoleophilic, superhydrophobic/superoleophobic, and in-air superhydrophilic/superoleophobic wetting. In-air superhydrophilic/superoleophobic wetting was realized by a dynamic rearrangement of the interface to expose a greater …

Role Of Stone-Wales Defects On The Interfacial Interactions Among Graphene, Carbon Nanotubes, And Nylon 6: A First-Principles Study, Sanjiv K. Jha, Michael Roth, Guido Todde, J. Paige Buchanan, Robert D. Moser, Manoj K. Shukla, Gopinath Subramanian

Faculty Publications

We investigate computationally the role of Stone-Wales (SW) defects on the interfacial interactions among graphene, carbon nanotubes (CNTs), and Nylon 6 using density functional theory (DFT) and the empirical force-field. Our first-principles DFT calculations were performed using the Quantum ESPRESSO electronic structure code with the highly accurate van der Waals functional (vdW-DF2). Both pristine and SW-defected carbon nanomaterials were investigated. The computed results show that the presence of SW defects on CNTs weakens the CNT-graphene interactions. Our result that CNT-graphene interaction is much stronger than CNT-CNT interaction indicates that graphene would be able to promote the dispersion of CNTs in …

Geotraces And Beyond: Studies Of Trace Elements In Coastal And Open Ocean Waters With An Emphasis On The Effects Of Oxygen Depletion And Hydrothermal Plumes, Peng Ho

Dissertations

We investigated various dissolved trace element (dTE) distributions in two distinct areas: the coastal northern Gulf of Mexico and the eastern tropical Pacific Ocean.

A multi-year (2007‒2011) chemical time series of eight stations in the western Mississippi Sound (MS) and northwestern Mississippi Bight (MB) was undertaken to examine the factors affecting chemical distributions in this dynamic region. Key findings include the frequent development of bottom water hypoxia in MB during late spring-summer, the likely contribution of submarine groundwater discharge (SGD) to the material flows, and observation of effects of episodic events including tropical storms and the opening of the Bonnet …

Synthetic And Theoretical Studies For Cyclization Reactions To Form C-C And C-N Bonds, Nicholas Jentsch

Dissertations

Natural product total synthesis provides an alternative method for obtaining medicinally relevant compounds in a more efficient process with higher yields than what nature can provide. Natural products pose significant synthetic challenges due to the unique heterocyclic skeletons with fused and spirocyclic ring systems. Therefore, it is paramount to develop efficient reaction methodologies targeting substructures such as cyclic ureas and spiro[4.5]decanes which are prominent among marine natural products and Lycopodium alkaloids, respectively. Presented here is a compilation of research seeking to develop synthetic methods for the construction of cyclic moieties such as those previously mentioned. The objectives that are addressed …

Adaptive Meshfree Methods For Partial Differential Equations, Jaeyoun Oh

Dissertations

There are many types of adaptive methods that have been developed with different algorithm schemes and definitions for solving Partial Differential Equations (PDE). Adaptive methods have been developed in mesh-based methods, and in recent years, they have been extended by using meshfree methods, such as the Radial Basis Function (RBF) collocation method and the Method of Fundamental Solutions (MFS). The purpose of this dissertation is to introduce an adaptive algorithm with a residual type of error estimator which has not been found in the literature for the adaptive MFS. Some modifications have been made in developing the algorithm schemes depending …

The Effect Of An Historical Geology Course On Students’ Attitudes Towards Science And Their Knowledge Of Deep Time As A Threshold To Their Knowledge Of Evolution, Allan Nolan

Dissertations

In America there exists a conflict between a small group of its citizens and the concept of evolution. Researchers have studied this conflict and the ways in which teachers might approach educational methodologies that not only address evolution in a sensitive manner, but also remain legally acceptable.

This research was designed to address teaching evolution in the context of deep time – the concept that time is vast and that geology and biology operate in a timescale of hundreds of millions to billions of years. In previous peer-reviewed works, it has been stated that deep time acts as a threshold …